Sodium Acetate Catalyzed Multicomponent Cyclization of Aromatic Aldehydes, Acetone and Meldrum Acid

Lin An; Feng Yang; Rong Yao; Prof. Dr. Chaoguo Yan

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Sodium Acetate Catalyzed Multicomponent Cyclization of Aromatic Aldehydes, Acetone and Meldrum Acid

机译：乙酸钠催化芳香醛，丙酮和甲基丙烯酸的多组分环化

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摘要

The sodium acetate catalyzed three-component reaction of aromatic aldehyde, acetone and Meldrum acid or spirolactone at room temperature gave stereospecific 7,11-cis-diaryl-2,4-dioxaspiro[5,5]undecane-1,5,9-triones in a very efficient manner.

机译：乙酸钠在室温下催化芳族醛，丙酮与Meldrum酸或螺内酯的三组分反应，得到立体有择的7,11-顺-二芳基-2,4-二氧杂螺[5,5]十一烷-1,5,9-三酮以非常有效的方式

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来源
《Chinese Journal of Chemistry》 |2010年第12期|p.2451-2454|共4页
作者
Lin An; Feng Yang; Rong Yao; Prof. Dr. Chaoguo Yan;
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作者单位

College of Pharmacy, Xuzhou Medical College, Xuzhou, 221004 Jiangsu, China;

College of Chemistry &

Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China;

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原文格式 PDF
正文语种 eng
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关键词
multicomponent reactions; meldrum acid; spiro compounds; stereospecificity; Knoevenagel condensation;

机译：多组分反应;蜜氨酸;螺化合物;立体特异性;诺文;

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专利

1. Sodium Acetate Catalyzed Multicomponent Cyclization of Aromatic Aldehydes, Acetone and Meldrum Acid [J] . An Lin, Yang Feng, Yao Rong, 中国化学（英文版） . 2010,第012期
2. Unexpected stereoselective sodium acetate catalyzed multicomponent cyclization of aryl aldehydes, malononitrile and acetone into cis-4-dicyanomethylene-2,6-diarylcyclohexane-1,1-dicarbonitriles [J] . Michail N.Elinson, Anatolii N.Vereshchagin, Sergey K.Feducovich Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第38期

机译：意外的立体选择性乙酸钠催化芳基醛，丙二腈和丙酮多组分环化为顺式-4-二氰基亚甲基-2,6-二芳基环己烷-1,1-二碳腈
3. One-Pot Multicomponent Synthesis of Highly Functionalized Piperidines from Substituted β-Nitrostyrenes, Meldrum's Acid, Aromatic Aldehydes, and Ammonium Acetate [J] . Yan Li, Zhiheng Xue, Weijian Ye ACS combinatorial science . 2014,第3期

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4. Pd-Catalyzed Allylation of Aldehydes with Silyl-Substituted Allyl Acetates Proceeding through a Migration of Substituents on Silyl Group [C] . HORINO Yoshikazu, MUTSUURA Itaru, ABE Hitoshi 日本化学会春季年会講演予稿集 . 2018

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5. Iron Lewis acid-catalyzed reactions of aromatic aldehydes with diazo compounds: Synthesis of precursors for commercially important drugs from 3-hydroxy-2-arylacrylic acid ethyl esters. [D] . Mahmood, Syed J. 1999

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6. Tandem Aldol Condensation – Platinacycle-Catalyzed Addition Reactions of Aldehydes Methyl Ketones and Arylboronic Acids [O] . Yuan-Xi Liao, Qiao-Sheng Hu -1

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机译：通过芳胺，芳族醛和me的一锅多米诺骨牌多组分反应，非对映选择性合成二螺四氢喹啉-双（2,2-二甲基1,3二恶烷-4,6-二酮）衍生物的非对映选择性的新途径酸

Sodium Acetate Catalyzed Multicomponent Cyclization of Aromatic Aldehydes, Acetone and Meldrum Acid

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