Transition metal catalyzed element-element' additions to alkynes

Ansell Melvyn B.; Navarro Oscar; Spencer John

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Transition metal catalyzed element-element' additions to alkynes

机译：过渡金属催化的炔烃元素的添加

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The efficient and stereoselective synthesis of, or precursors to, multi-substituted alkenes has attracted substantial interest due to their existence in various industrially and biologically important compounds. One of the most atom economical routes to such alkenes is the transition metal catalyzed hetero element-element' pi-insertion into alkynes. This article provides a thorough up-to-date review on this area of chemistry, including discussions on the mechanism, range of E-E' bonds accessible and the stoichiometric/catalytic transition metal mediators employed. (C) 2017 The Authors. Published by Elsevier B.V.

机译：由于多取代烯烃存在于各种工业和生物学上重要的化合物中，因此它们的有效和立体选择性合成或其前体引起了人们的极大兴趣。通往此类烯烃的最原子经济的途径之一是过渡金属催化的杂原子元素π插入炔烃中。本文提供了有关该化学领域的最新综述，包括有关机理，E-E'键可及范围以及所用化学计量/催化过渡金属介体的讨论。（C）2017作者。由Elsevier B.V.发布

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《Coordination chemistry reviews》 |2017年第4期|54-77|共24页
作者
Ansell Melvyn B.; Navarro Oscar; Spencer John;
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作者单位

Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England;

Oregon Hlth & Sci Univ, Sch Dent, Dept Restorat Dent, Div Biomat & Biomech, 2730 SW Moody Ave, Portland, OR 97239 USA;

Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Alkynes; Alkenes; Element-element bonds; Catalysis; Transition metal;

机译：炔烃;烯烃;元素键;催化;过渡金属;

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专利

1. Element-Element Addition to Alkynes Catalyzed by the Group 10 Metals [J] . Beletskaya Lrina, Moberg Christina Chemical Reviews . 1999,第12期

机译：10族金属催化的炔烃元素-元素加成
2. Element-Element Additions to Unsaturated Carbon-Carbon Bonds Catalyzed by Transition Metal Complexes [J] . Irina Beletskaya, Christina Moberg Chemical Reviews . 2006,第6期

机译：过渡金属配合物催化不饱和碳-碳键的元素-元素加成
3. Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-bound Triphenylphosphine [J] . Tieqiao Chen, Yongbo Zhou, Cancheng Guo Chemistry Letters . 2013,第9期

机译：固定在聚苯乙烯键合的三苯基膦上的过渡金属催化的炔烃中P（O）-H键的选择性加成
4. Construction of Carbon Skeletons by Transition Metal-Catalyzed Regio- and Stereoselective Addition of Carbon-Chalcogen Bonds to Alkynes and Allenes [C] . Masashi Tovofuku, Erika Murase, Atsushi Okada Symposium on Organometallic Chemistry . 2008

机译：通过过渡金属催化的碳骨架施工碳骨架和立体选择性加入碳 - 硫醇键与炔烃和艾伦
5. Transition metal-catalyzed tandem carbon-oxygen and carbon-carbon bond forming reactions of alkynes in (1) the addition-cyclization of carboxylic acids with 1,6-diynes and in (2) the total synthesis of frondosin B. [D] . Goble, Stephen D. 2006

机译：炔烃的过渡金属催化串联碳-氧和碳-碳键形成反应在（1）羧酸与1,6-二炔的加成环化中和（2）frondosin B的总合成中。
6. Transition-Metal Catalyzed Synthesis of Aspergillide B: An Alkyne Addition Strategy [O] . Barry M. Trost, Mark J. Bartlett -1

机译：aspergillide B的过渡金属催化的合成：炔加法策略
7. Transition metal catalyzed element–element′ additions to alkynes [O] . Ansell Melvyn B, Navarro Oscar, Spencer John 2017

机译：过渡金属催化的元素元素添加到炔烃中
8. Preparation of B-σ-Metallocarboranes by Oxidative Addition:Model Intermediates for Transition Metal Catalyzed H-D Exchange in B-H Containing Species [R] . Elvin L. Hoel, M. F. Hawthorne 1974

机译：氧化加成制备B-σ-金属碳硼烷：过渡金属催化的含B-H物种H-D交换模型中间体

Transition metal catalyzed element-element' additions to alkynes

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