Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-bound Triphenylphosphine

Tieqiao Chen; Yongbo Zhou; Cancheng Guo

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Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-bound Triphenylphosphine

机译：固定在聚苯乙烯键合的三苯基膦上的过渡金属催化的炔烃中P（O）-H键的选择性加成

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Addition of P(O)-H bonds to alkynes catalyzed by transition metals (Rh, Pd, and Ni) immobilized on polystyrene-bound triphenylphosphine proceeded efficiently to afford high yields of the addition products with high regioselectivity. The immobilized catalysts were easily recovered from the reaction mixture via simple centrifugal separation and could be reused several times without severe deactivation.

机译：通过固定在聚苯乙烯键合的三苯基膦上的过渡金属（Rh，Pd和Ni）催化，将P（O）-H键加成至炔烃上可有效进行，以高收率提供高产率的加成产物。固定的催化剂很容易通过简单的离心分离从反应混合物中回收，并且可以多次使用而不会严重失活。

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《Chemistry Letters》 |2013年第9期|共3页
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Tieqiao Chen; Yongbo Zhou; Cancheng Guo;
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1. Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-bound Triphenylphosphine [J] . Tieqiao Chen, Yongbo Zhou, Cancheng Guo Chemistry Letters . 2013,第9期

机译：固定在聚苯乙烯键合的三苯基膦上的过渡金属催化的炔烃中P（O）-H键的选择性加成
2. Transition-Metal-Catalyzed Addition of Heteroatom-Hydrogen Bonds to Alkynes [J] . Francisco Alonso, Irina P.Beletskaya, Miguel Yus Chemical Reviews . 2004,第6期

机译：过渡金属催化的杂原子-氢键与炔烃的加成反应
3. Highly selective intramolecular addition of C-N and S-N bonds to alkynes catalyzed by palladium: a practical access to two distinct functional indoles [J] . Wu Chenglin, Zhao Fei, Du Yonglei, RSC Advances . 2016,第74期

机译：高度选择性的分子内加入C-N和S-N键，催化钯催化：对两个不同功能吲哚的实际访问
4. Construction of Carbon Skeletons by Transition Metal-Catalyzed Regio- and Stereoselective Addition of Carbon-Chalcogen Bonds to Alkynes and Allenes [C] . Masashi Tovofuku, Erika Murase, Atsushi Okada Symposium on Organometallic Chemistry . 2008

机译：通过过渡金属催化的碳骨架施工碳骨架和立体选择性加入碳 - 硫醇键与炔烃和艾伦
5. Transition metal-catalyzed tandem carbon-oxygen and carbon-carbon bond forming reactions of alkynes in (1) the addition-cyclization of carboxylic acids with 1,6-diynes and in (2) the total synthesis of frondosin B. [D] . Goble, Stephen D. 2006

机译：炔烃的过渡金属催化串联碳-氧和碳-碳键形成反应在（1）羧酸与1,6-二炔的加成环化中和（2）frondosin B的总合成中。
6. Transition Metal-Catalyzed C–H Bond Addition to Carbonyls Imines and Related Polarized π-Bonds [O] . Joshua R. Hummel, Jeffrey A. Boerth, Jonathan A. Ellman -1

机译：过渡金属催化的C–H键与羰基亚胺和相关极化π键的结合
7. Transition metal catalyzed element–element′ additions to alkynes [O] . Ansell Melvyn B, Navarro Oscar, Spencer John 2017

机译：过渡金属催化的元素元素添加到炔烃中

Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-bound Triphenylphosphine

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