The organic chemistry of poly(1H-pyrazol-1-yl)methanes

Alkorta Ibon; Claramunt Rosa M.; Diez-Barra Enrique; Elguero Jose; de la Hoz Antonio; Lopez Concepcion

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The organic chemistry of poly(1H-pyrazol-1-yl)methanes

机译：聚（1H-吡唑-1-基）甲烷的有机化学

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Since their first synthesis by Huckel (1937) and the first systematic exploration by Trofimenko (1970), interest in poly(1H-pyrazol-1-yl)methanes (bis, tris and tetrakis) has increased dramatically. This review focuses on the synthesis and reactivity of these ligands and contains 541 different structures and 269 references. After a brief historical introduction, the synthesis, reactivity, and nature of the coordinated metals are described along with some properties of these compounds, particularly the complete set of X-ray molecular structures. All of the formulae are represented to show the extraordinary richness of poly(1H-pyrazol-1-yl) methanes and to promote the use of the already known poly(1H-pyrazol-1-yl) methanes in coordination chemistry and the design of new ligands with the reported procedures. (C) 2017 Elsevier B.V. All rights reserved.

机译：自从Huckel（1937）首次合成和Trofimenko（1970）首次系统探索以来，对聚（1H-吡唑-1-基）甲烷（双，三和四烷基）的兴趣急剧增加。这篇综述着重于这些配体的合成和反应性，包含541种不同的结构和269种参考。在简短的历史介绍之后，对配位金属的合成，反应性和性质以及这些化合物的某些性能，特别是完整的X射线分子结构进行了描述。所有的化学式均表示出聚（1H-吡唑-1-基）甲烷的非凡富集性，并促进了已知的聚（1H-吡唑-1-基）甲烷在配位化学中的应用以及环戊烷的设计。新的配体与报告的程序。（C）2017 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第5期|153-182|共30页
作者
Alkorta Ibon; Claramunt Rosa M.; Diez-Barra Enrique; Elguero Jose; de la Hoz Antonio; Lopez Concepcion;
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作者单位

CSIC, Inst Quim Med, Juan Cierva 3, E-28006 Madrid, Spain;

UNED, Fac Ciencias, Dept Quim Organ & Bioorgan, Paseo Senda Rey 9, E-28040 Madrid, Spain;

Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Quim Organ, Avda Camilo Jose Cela 10, E-13071 Ciudad Real, Spain;

CSIC, Inst Quim Med, Juan Cierva 3, E-28006 Madrid, Spain;

Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Quim Organ, Avda Camilo Jose Cela 10, E-13071 Ciudad Real, Spain;

UNED, Fac Ciencias, Dept Quim Organ & Bioorgan, Paseo Senda Rey 9, E-28040 Madrid, Spain;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Pyrazoles; Pyrazolylmethanes; Bis(1H-pyrazol-1-yl)methanes; Tris(1H-pyrazol-1-yl)methanes; Tetrakis(1H-pyrazol-1-yl)methanes; Metal ligands; X-ray structures;

机译：吡唑类;吡唑基甲烷;双（1H-吡唑-1-基）甲烷;三（1H-吡唑-1-基）甲烷;四（1H-吡唑-1-基）甲烷;金属配体;X射线结构;

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机译：聚（1H-吡唑-1-基）甲烷的有机化学

The organic chemistry of poly(1H-pyrazol-1-yl)methanes

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