Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation

Samir H.Chikkali; Jarl Ivar van der Vlugt; Joost N.H. Reek

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Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation

机译：铑催化的不对称羰基化反应中的杂二磷配体

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This review aims to illustrate recent advances in the application of hybrid diphosphorus ligands for the Rh catalysed hydroformylation of alkenes, discussing the most prevalent classes of hybrid systems, i.e. phosphine-phosphinite, phosphine-phosphonite, phosphine-phosphite, phosphite-phosphoramidite and phosphite-phosphoramidite and comparing their performance with relevant C_2 symmetric counterparts. In order to introduce the field and put the results in context, a short overview on Rh hydroformylation is provided. Available spectroscopic (in situ) data on the coordination modes of hybrid phosphorus ligands and the catalytic performance of these systems in asymmetric hydroformylation of vinyl arenes are reported. Potential avenues for future research are shortly discussed.

机译：这篇综述旨在说明杂化二磷配体在Rh催化的烯烃加氢甲酰化中的应用的最新进展，讨论了最普遍的杂化体系，即膦次膦，次膦膦，次膦膦，次膦酸酯亚磷酰胺和次膦酸酯。亚磷酰胺并将其性能与相关的C_2对称对应物进行比较。为了介绍该领域并将结果放在上下文中，提供了有关Rh加氢甲酰化的简短概述。报告了有关杂化磷配体的配位方式和这些系统在乙烯基芳烃不对称加氢甲酰化反应中的催化性能的可用光谱数据（原位）。简短讨论了未来研究的潜在途径。

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来源
《Coordination chemistry reviews》 |2014年第3期|1-15|共15页
作者
Samir H.Chikkali; Jarl Ivar van der Vlugt; Joost N.H. Reek;
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作者单位

Supramolecular & Homogeneous Catalysis, van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands ,Polymer Science and Engineering Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India;

Supramolecular & Homogeneous Catalysis, van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands;

Supramolecular & Homogeneous Catalysis, van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Rhodium; Asymmetric hydroformylation; Hybrid ligand design; In situ spectroscopy; Catalyst resting state;

机译：铑;不对称加氢甲酰化;杂配体设计;原位光谱催化剂静止状态;

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专利

1. Furanoside diphosphines derived from D-(+)-xylose and D-(+)-glucose as ligands in rhodium-catalysed asymmetric hydroformylation reactions [J] . Dieguez M., Net G., Ruiz A., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2001,第4期

机译：在铑催化的不对称加氢甲酰化反应中，以D-（+）-木糖和D-（+）-葡萄糖为配体的呋喃糖苷二膦
2. A novel dicationic phenoxaphosphino-modified Xantphos-type ligand:a ligand for highly active and selective,biphasic,rhodium catalysed hydroformylation in ionic liquids [J] . Raymond P J Bronger, Silvana M Silva, Paul C J Kamer, Dalton transactions: An international journal of inorganic chemistry . 2004,第10期

机译：一种新型的离子型苯氧磷膦修饰的Xantphos型配体：用于离子液体中高活性和选择性，双相，铑催化的加氢甲酰化的配体
3. Supported Chiral Monodentate Ligands in Rhodium-Catalysed Asymmetric Hydrogenation and Palladium-Catalysed Asymmetric Allylic Alkylation [J] . Swennenhuis BHG, Chen RF, van Leeuwen PWNM, European journal of organic chemistry . 2009,第33期

机译：铑催化的不对称加氢和钯催化的不对称烯丙基烷基化中的手性单齿配体
4. Halophosphite Ligands for the Rhodium Catalyzed Low-Pressure Hydroformylation Reaction [C] . Thomas A. Puckette Organic Reactions Catalysis Society Conference . 2007

机译：卤代磷酸盐配体用于铑催化的低压加氢甲酰化反应
5. Rhodium-Catalyzed Asymmetric Hydroformylation of Alkenes Using Diazaphospholane Ligands and Application With Wittig Olefination. [D] . Wong, Gene W. 2012

机译：使用重氮磷烷配体进行铑催化的烯烃不对称加氢甲酰化反应，并在Wittig烯烃中进行应用。
6. Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers [O] . Dr. Mehdi Elsayed Moussa, Dr. Michael Seidl, Dr. Gábor Balázs, -1

机译：带有不稳定二磷配体的预组装AgI双金属前体用于有机金属-有机杂化聚合物的程序合成
7. Supported chiral monodentate ligands in rhodium-catalysed asymmetric hydrogenation and palladium-catalysed asymmetric allylic alkylation [O] . Swennenhuis, B.H.G., Chen, R., van Leeuwen, P.W.N.M., 2009

机译：铑催化的不对称氢化和钯催化的不对称烯丙基烷基化反应中支持的手性单齿配体
8. Hydroformylation Catalyzed by cis-Chelated Rhodium Complexes. Extension to Polymer-Anchored cis-Chelated Rhodium Catalysts. [R] . pittman,charles u. jr hirao, akira 1977

机译：顺式螯合铑配合物催化加氢甲酰化。扩展到聚合物锚定的顺式螯合铑催化剂。

Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation

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