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NaBH_4 Pretreatment in Bioethanol Production of Corn Stalks

机译:NaBH_4在玉米秸秆生物乙醇生产中的预处理

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摘要

Corn stalks, which are an abundant agricultural waste product in Turkey, have a high carbohydrate structural content and could be a valuable raw material for bioethanol production. In this study, stalks with crystalline cellulose and complex lignin and hemicellulose distribution in their structure were first steam-exploded and then chemically treated to achieve efficient hydrolysis. The conventional chemicals sodium hydroxide (NaOH), sulfuric acid (H_2SO_4), hydrogen peroxide (H_2O_2), and an alternative chemical, sodium borohydrate (NaBH4), were utilized in the chemical treatment procedure. Results showed that the samples treated with NaOH (83.9%) and NaBH4 (82.9%) gave higher glucan conversion in enzymatic hydrolysis compared to those treated with H_2O_2 (74.5%) and H_2SO_4 (56.6%). The highest ethanol yield from untreated stalks (97.4 g/kg) was obtained when the stalks were pretreated with 4% NaBH_4 for 90 min; the theoretical ethanol yield was found to be 72.5%.
机译:玉米秸秆是土耳其丰富的农业废品,具有较高的碳水化合物结构含量,可能是生产生物乙醇的宝贵原料。在这项研究中,首先将具有结晶纤维素,复杂木质素和半纤维素分布结构的秸秆进行蒸汽爆破,然后进行化学处理以实现有效的水解。在化学处理过程中,使用了常规化学氢氧化钠(NaOH),硫酸(H_2SO_4),过氧化氢(H_2O_2)和替代化学硼氢化钠(NaBH4)。结果表明,与用H_2O_2(74.5%)和H_2SO_4(56.6%)处理的样品相比,用NaOH(83.9%)和NaBH4(82.9%)处理的样品在酶促水解中具有更高的葡聚糖转化率。当用4%NaBH_4预处理秸秆90分钟时,未处理秸秆的乙醇产量最高(97.4 g / kg);发现理论乙醇产率为72.5%。

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