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Naturally-derived biopolymer nanocomposites: Interfacial design, properties and emerging applications

机译:天然来源的生物聚合物纳米复合材料:界面设计,性能和新兴应用

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摘要

Naturally derived materials with hierarchical organization are attractive candidates for high-performance and functional bionanocomposites because of their renewability, biocompatibility, biodegradability, flexibility, and the availability of multiple reactive sites for introducing novel functionalities. Complementary to these inherent properties, the synergistic combination of biological and synthetic components facilitated by strong interfacial interactions, can substantially enhance the structural performance and facilitate added functionalities of these bio-enabled nanocomposites. In this review, we discuss the current progress of naturally-derived bionanocomposites that has advanced our understanding of the biological/synthetic interfaces. In these bionanocomposites, various novel synthetic nanomaterials (e.g., graphene, carbon nanotube, mineral nanoparticles and metallic nanoparticles) are efficiently integrated with biological components to achieve novel properties such as superior electrical and thermal conductivity, controlled gas barrier properties, complex actuation, and unique optical properties. Two popular biocomponents, nanocellulose and silk, are mainly discussed in this review as representatives of classes of polysaccharides and polypeptides with some other biopolymers briefly discussed as well. The structures and morphologies, processing strategies, tailored functionalities and emerging applications of these bionanocomposites are analyzed and summarized. Finally, we present an outlook on the current trends in providing structural and interfacial enhancement as well as emerging applications which will employ new optical, sensing, structural, and actuating functionalities and properties.
机译:具有层次结构的天然衍生材料是高性能和功能性生物纳米复合材料的有吸引力的候选者,因为它们具有可更新性,生物相容性,生物降解性,柔韧性以及可用于引入新功能的多个反应位点。作为这些固有性质的补充,由强大的界面相互作用促进的生物和合成组分的协同组合,可大大增强结构性能并促进这些生物使能的纳米复合材料的附加功能。在这篇综述中,我们讨论了天然来源的仿生纳米复合材料的最新进展,该进展已加深了我们对生物/合成界面的理解。在这些生物纳米复合材料中,各种新型合成纳米材料(例如,石墨烯,碳纳米管,矿物纳米颗粒和金属纳米颗粒)与生物组分有效地整合在一起,从而获得了新颖的性能,例如优异的电导率和导热率,可控的气体阻隔性能,复杂的驱动力以及独特的性能。光学性质。在这篇综述中,主要讨论了两种流行的生物成分,即纳米纤维素和丝绸,它们是多糖和多肽类别的代表,同时也简要讨论了一些其他生物聚合物。分析和总结了这些生物纳米复合材料的结构和形态,加工策略,量身定制的功能和新兴应用。最后,我们对提供结构和界面增强以及将采用新的光学,传感,结构和驱动功能和特性的新兴应用的当前趋势进行了展望。

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