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首页> 外文期刊>Sensors and Actuators >Highly sensitive and selective ratiometric fluorescent metal-organic framework sensor to nitroaniline in presence of nitroaromatic compounds and VOCs
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Highly sensitive and selective ratiometric fluorescent metal-organic framework sensor to nitroaniline in presence of nitroaromatic compounds and VOCs

机译:在硝基芳香族化合物和VOC存在下对硝基苯胺具有高灵敏度和选择性的比例荧光金属有机骨架传感器

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摘要

Sensing properties of a ratiometric fluorescent metal-organic framework sensor, TMU-4S, prepared by introducing laser dye of Rhodamine В into the framework of a Zn(Ⅱ) based MOF, TMU-4, [Zn_2(oba)_2(4-bpdb)]_n -2DMF for detection of explosive nitro aromatic compounds were investigated. Azine decorated pores of TMU-4 with basicity properties show high selectivity to low concentrations of nitroaniline. Using the ratiometric fluorescent sensor with two-dimensions, signal transduction leads to greatly reduced environmental interference responses and thus it creates particular sensitivity to a certain analyte with a specific concentration.
机译:比例荧光金属有机骨架传感器TMU-4S的感测特性,通过将若丹明В的激光染料引入基于Zn(Ⅱ)的MOF,TMU-4,[Zn_2(oba)_2(4-bpdb) )] _ n -2DMF用于检测爆炸性硝基芳族化合物。具有碱性特性的TMU-4的用甲胺装饰的孔对低浓度的硝基苯胺显示出高选择性。使用二维的比例荧光传感器,信号转导可大大减少环境干扰响应,因此,它对特定浓度的特定分析物具有特别的灵敏度。

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