Nickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application

Sankaraperumal A.; Karthikeyan J.; Shetty A.N.; Lakshmisundaram R.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Nickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application

【24h】

Nickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application

机译：对[[N，N-双（2-氯乙基）氨基]苯甲醛-4-甲基硫代氨基脲）镍（II）配合物的合成，结构表征及生物学应用

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

New complex of Ni(II) with p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4- methyl thiosemicarbazone (CEAB-4-MTSC) have been synthesized and characterized by elemental analysis, IR, electronic, ~1H NMR spectroscopy. The crystal structure of the free ligand and complex has been determined by single crystal X-ray diffraction technique. In the complex, thiosemicarbazone ligand is coordinated to nickel through (1:2 complex) SNNS mode. The complex crystallizes in the triclinic with space group P1?. The complex has been tested for their antibacterial activity against various pathogenic bacteria. From this study, it was found out that the activity of complex reaches the effectiveness of the conventional bacteriocide Streptomycin compared to simple ligand.

机译：合成了Ni（II）与对[[N，N-双（2-氯乙基）氨基]苯甲醛-4-甲基硫代半碳zone（CEAB-4-MTSC）的新配合物，并通过元素分析，红外，电子，〜 1 H NMR光谱。游离配体和配合物的晶体结构已经通过单晶X射线衍射技术确定。在该络合物中，硫代半碳胺配体通过（1：2络合物）SNNS模式与镍配位。该配合物在三斜晶系中以空间群P1′结晶。已对该复合物针对各种病原菌的抗菌活性进行了测试。从该研究中发现，与简单配体相比，复合物的活性达到了常规杀菌剂链霉素的功效。

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2013年第1期|共6页
作者
Sankaraperumal A.; Karthikeyan J.; Shetty A.N.; Lakshmisundaram R.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Ni(II) complex; SNNS donor type complex; Square planar complex; Thiosemicarbazone;

机译：Ni（II）络合物;SNNS供体型络合物;方平面络合物;硫代氨基脲;

相似文献

外文文献
中文文献
专利

1. Nickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application [J] . Sankaraperumal A., Karthikeyan J., Shetty A.N., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第1期

机译：对[[N，N-双（2-氯乙基）氨基]苯甲醛-4-甲基硫代氨基脲）镍（II）配合物的合成，结构表征及生物学应用
2. Synthesis and characterization of nickel(II) complex of p-[N, N-bis- (2-chloroethyl)amino]benzaldehyde-4-ethyl thiosemicarbazone [J] . Anitha S, Karthikeyan J, Nityananda Shetty A Indian journal of chemistry . 2013,第1期

机译：对[[N，N-双-（2-氯乙基）氨基]苯甲醛-4-乙基硫代半乳糖苷镍（II）配合物的合成与表征
3. Analytical properties of p-[N,N-bis(2-chloroethyl)amino] benzaldehyde thiosemicarbazone: spectrophotometric determination of palladium(II) in alloys, catalysts, and complexes [J] . J. Karthikeyan, P. Parameshwara, A. Nityananda Shetty Environmental Monitoring and Assessment . 2011,第1a4期

机译：对[[N，N-双（2-氯乙基）氨基]苯甲醛硫代半碳zone的分析性质：分光光度法测定合金，催化剂和络合物中的钯（II）
4. Immobilized Cu (II)—Amino Acid Complexes asProspective Highly Efficient Catalytic Materials:Synthesis, Structural Characterization andCatalytic Activities [C] . Istvan Palinko, Adrien Ordasi, Janos T. Kiss, International Conference on Perspectives in Vibrational Spectroscopy . 2008

机译：固定化Cu（II） - 氨基酸复合物表现出高效催化材料：合成，结构表征和催化活性
5. Synthesis of symmetrical and optically active alpha-amino acids via homologation of nickel(II) complexed glycine Schiff bases. [D] . Ellis, Trevor K. 2007

机译：通过镍（II）配合的甘氨酸席夫碱的同系物合成对称和旋光的α-氨基酸。
6. Synthesis and characterization of mixed-ligand diimine-piperonal thiosemicarbazone complexes of ruthenium(II): Biophysical investigations and biological evaluation as anticancer and antibacterial agents [O] . Floyd A. Beckford, Jeffrey Thessing, Michael Shaloski Jr., -1

机译：钌（II）混合配体二嘧啶 - 哌啶硫代噻唑哌啶醇的合成与表征：生物物理研究和生物学评价作为抗癌和抗菌剂
7. Mixed-Ligand Complexes Of Nickel (II) With 2-Acetylpyridine Thiosemicarbazone And Some N/S Monodentate Ligands: Synthesis, Structural Characterization And Biological Activity [O] . GE Iniama, OE Offiong, E Nfor, 2008

机译：镍（II）的混合配体复合物用2-乙酰基吡啶硫代吡啶脱毒虫和一些N / S单齿配体：合成，结构表征和生物活性

Nickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application

摘要

著录项

相似文献

相关主题

期刊订阅