Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K_6[Re _(12)CS_(17)(OH)_6]·4H_2O and Na _(12)Re_(12)CS_(17)(SO_3)_6· 48.5H_2O

Mironov Y.V.; Kozlova S.G.; Kim S.-J.; Sheldrick W.S.; Fedorov V.E.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K_6[Re _(12)CS_(17)(OH)_6]·4H_2O and Na _(12)Re_(12)CS_(17)(SO_3)_6· 48.5H_2O

【24h】

Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K_6[Re _(12)CS_(17)(OH)_6]·4H_2O and Na _(12)Re_(12)CS_(17)(SO_3)_6· 48.5H_2O

机译：具有间隙碳原子的十二烷核cluster簇配合物：两种新化合物K_6 [Re _（12）CS_（17）（OH）_6]·4H_2O和Na _（12）Re_（12）CS_（17）的合成，结构和性质）（SO_3）_6·48.5H_2O

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re_(12)CS_(17)(OH)_6]~(6-) was obtained by the reaction of K_6[Re_(12)CS_(17)(CN) _6]·20H_2O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K_6[Re_(12)CS_(17)(OH) _6]·4H_2O and Na_2S_2O _4 in water under reflux results in the formation of the complex Na_(12)[Re_(12)CS_(17)(SO_3) _6]·48.5H_2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re_(12)CS_(17)(OH)_6] ~(6-) was also elucidated by DFT calculations.

机译：通过K_6 [Re_（12）CS_（17）（CN）_6]的反应获得具有末端羟基配体[Re_（12）CS_（17）（OH）_6]〜（6-）的十二核clear阴离子配合物。 20H_2O和300°C的熔融KOH。簇络合物从水溶液中结晶为钾盐。 K_6 [Re_（12）CS_（17）（OH）_6]·4H_2O与Na_2S_2O_4在水中回流下的反应导致形成复合物Na_（12）[Re_（12）CS_（17）（SO_3） _6]·48.5H_2O。两种新化合物均通过单晶X射线衍射，元素分析和红外光谱进行了表征。通过DFT计算也阐明了[Re_（12）CS_（17）（OH）_6]〜（6-）的电子结构。

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2010年第18期|共4页
作者
Mironov Y.V.; Kozlova S.G.; Kim S.-J.; Sheldrick W.S.; Fedorov V.E.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Crystal structure; Dodecanuclear cluster complexes; Electronic structure; Rhenium; Synthesis;

机译：晶体结构;十二核簇配合物;电子结构;hen;合成;

相似文献

外文文献
中文文献
专利

1. Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K_6[Re _(12)CS_(17)(OH)_6]·4H_2O and Na _(12)Re_(12)CS_(17)(SO_3)_6· 48.5H_2O [J] . Mironov Y.V., Kozlova S.G., Kim S.-J., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第18期

机译：具有间隙碳原子的十二烷核cluster簇配合物：两种新化合物K_6 [Re _（12）CS_（17）（OH）_6]·4H_2O和Na _（12）Re_（12）CS_（17）的合成，结构和性质）（SO_3）_6·48.5H_2O
2. Synthesis of Molecular Dodecanuclear Carbon-centered Rhenium Cluster Re_(12)CS_(17) and its Conducting Properties [J] . Vladimir Efimovich Fedorov, Svyatoslav Petrovich Gabuda, Svetlana Gennadevna Kozlova, Croatica Chemica Acta . 2012,第1期

机译：分子十二碳核为中心的Cluster团簇Re_（12）CS_（17）的合成及其导电性能
3. [Re_(12)CS_(17)(CN)_6]~(n-) (n = 6,8):A Sulfido-Cyanide Rhenium Cluster with an Interstitial Carbon Atom [J] . Yuri V.Mironov, Nikolai G.Naumov, Svetlana G.Kozlova, Angewandte Chemie . 2005,第42期

机译：[Re_（12）CS_（17）（CN）_6]〜（n-）（n = 6,8）：具有间隙碳原子的硫化氰氰R簇
4. Synthesis of molecular dodecanuclear carbon-centered rhenium cluster Re12CS17 and its conducting properties [C] . Fedorov V. E., Gabuda S. P., Kozlova S. G., 34th International Convention on Information and Communication Technology, Electronics and Microelectronics . 2011

机译：分子十二碳核为中心的cluster簇Re 12 CS 17 的合成及其导电性能
5. Novel mesostructured electrolytes: Synthesis and characterization of meso-silicon dioxide-carbon(12) E oxygen(10) hydroxyl-trifluoromethane sulfonic acid and meso-silicon dioxide-carbon(12) E oxygen(10) hydroxyl-lithium trifluoromethane sulfonate. [D] . Halla, Jamie Dustin. 2002

机译：新型介孔结构电解质：介孔二氧化硅-碳（12）E氧（10）羟基-三氟甲烷磺酸和介孔二氧化硅-碳（12）E氧（10）羟基-三氟甲烷磺酸锂的合成与表征。
6. Crystal structure determination of rac-11′-(1-acetyl-1H-indazol-3-yl)-11′11a′-dihydro-10′H17′H-spiroindene-218′-5a16bmethanotriindeno12-b:1′2′-d:2′′1′′-goxocine-1310′12′17′(10a′H)-pentaone acetonitrile 1.5-solvate [O] . Mark Baranov, Radion Vainer, Mark V. Sigalov 2018

机译：rac-11-（1-乙酰基-1H-吲唑-3-基）-1111a-二氢-10H17H-螺indene-218-5a的晶体结构测定16b methanotriindeno 12-b：12-d：21-g oxocine -13101217（10aH）-戊酮乙腈1.5溶剂化物
7. Synthesis of Molecular Dodecanuclear Carbon-centered Rhenium Cluster Re12CS17 and its Conducting Properties [O] . Fedorov, Vladimir Efimovich, Gabuda, Svyatoslav Petrovich, Kozlova, Svetlana Gennadu27evna, 2012

机译：分子十二碳核为中心的Cluster团簇Re12CS17的合成及其导电性能
8. Cluster Complex Metathesis. Synthesis, Structures, and Dynamic Behaviour of Bi- and Tri-Metallic Hexanuclear Cluster Complexes (MM'Ru4(millimicron3-H)2(CO)12(PPh3)2) (M ==M' == CU, Ag, or Au;M == CU, M' == Ag or Au; M == Ag, M' == [R] . Freeman, M. J., Green, M., Orphen, A. G., 1983

机译：簇复杂复分解。双金属和三金属六核簇合物（mm'Ru4（millimicron3-H）2（CO）12（pph3）2）（m == m'== CU，ag或au）的合成，结构和动态行为; m == CU，m'== ag或au; m == ag，m'==

Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K_6[Re _(12)CS_(17)(OH)_6]·4H_2O and Na _(12)Re_(12)CS_(17)(SO_3)_6· 48.5H_2O

摘要

著录项

相似文献

相关主题

期刊订阅