Copper(II) and nickel(II) complexes of pyrazole derived ligands: Synthesis, characterization and coordinating properties of two substituted thiocarbamyl pyrazoles, 3,5-dimethyl-1-N-methyl/ethyl thiocarbamyl pyrazole (HL1, HL2), potential ligands for

Barik AK.; Kar SK.; Bandyopadhyay P.

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Copper(II) and nickel(II) complexes of pyrazole derived ligands: Synthesis, characterization and coordinating properties of two substituted thiocarbamyl pyrazoles, 3,5-dimethyl-1-N-methyl/ethyl thiocarbamyl pyrazole (HL1, HL2), potential ligands for

机译：吡唑衍生的配体的铜（II）和镍（II）配合物：潜在的配体，两个取代的硫代氨基甲酰基吡唑，3,5-二甲基-1-N-甲基/乙基硫代氨基甲酰基吡唑（HL1，HL2）的合成，表征和配位性能对于

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The solid complexes of Cu(II) with different counterions and Nio(II) having no counterions with 3,5-dimethyl-1-N-methyl thiocarbamylpyrazole (HL1) and 3,5-dimethyl-1-N-ethyl thiocarbamylpyrazole (HL2), the ligands having coordination function of the pyrazole ring and the thiocarbamido group, have been prepared and their geometries established on the basis of molar conductance, magnetic susceptibility, IR, UV and visible spectral data. Magnetic and spectral features indicate paramagnetic [Cu(HL1/HL2)X-2] (X = Cl, Br), [Cu(HL1/HL2)(2)] (ClO4)(2) as either planar or tetragonally distorted octahedral species with the ligands in the neutral "thione" form, while Ni(L-1/L-2)(2) as the diamagnetic square planar species with the ligands in the deprotonated "thiol" form. X-ray crystallographic studies of Ni(L-2)(2) has unambiguously proved the distorted square planar environment around the central nickel(II) ion; the ligand molecules are cis-coordinated to the nickel(II) ion. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 45]

机译：具有不同抗衡离子的Cu（II）和不具有抗衡离子的Nio（II）与3,5-二甲基-1-N-甲基硫代氨基甲酰基吡唑（HL1）和3,5-二甲基-1-N-乙基硫代氨基甲酰基吡唑（HL2）的固体配合物），已经制备了具有吡唑环和硫代氨基甲酸酯基团的配位功能的配体，并根据摩尔电导，磁化率，IR，UV和可见光谱数据确定了它们的几何形状。磁性和光谱特征表明顺磁性[Cu（HL1 / HL2）X-2]（X = Cl，Br），[Cu（HL1 / HL2）（2）]（ClO4）（2）为平面或四边形扭曲的八面体物种具有中性“硫酮”形式的配体，而Ni（L-1 / L-2）（2）作为具有反质子化“硫醇”形式的配体的反磁性方平面物质。 Ni（L-2）（2）的X射线晶体学研究清楚地证明了中心镍（II）离子周围扭曲的正方形平面环境;配体分子与镍（II）离子顺式配位。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：45]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第2期|共6页
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Barik AK.; Kar SK.; Bandyopadhyay P.;
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中图分类化学;无机化学;
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Copper(ii) and nickel(ii) complexes; Methyl/ethyl thiocarbamylpyrazole; Synthesis; Spectroscopy; X-ray crystal structure; Metal-complexes; Crystal-structure; Thiosemicarbazones; Cobalt(ii); Chemistry; 2-acetylpyridine; Antifungal;

机译：铜（ii）和镍（ii）配合物;甲基/乙基硫代氨基甲酰基吡唑;合成;光谱;X射线晶体结构;金属配合物;晶体结构;硫代氨基甲酮;钴（ii）;化学性质;2-乙酰基吡啶;抗真菌药;

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1. Copper(II) and nickel(II) complexes of pyrazole derived ligands: Synthesis, characterization and coordinating properties of two substituted thiocarbamyl pyrazoles, 3,5-dimethyl-1-N-methyl/ethyl thiocarbamyl pyrazole (HL1, HL2), potential ligands for [J] . Barik AK., Kar SK., Bandyopadhyay P. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第1a2期

机译：吡唑衍生的配体的铜（II）和镍（II）配合物：潜在的配体，两个取代的硫代氨基甲酰基吡唑，3,5-二甲基-1-N-甲基/乙基硫代氨基甲酰基吡唑（HL1，HL2）的合成，表征和配位性能对于
2. Synthesis and characterization of two tris-chelate complexes of cobalt(III) with 3,5-dimethyl-1-(N-methyl/ethyl) thiocarbamyl-pyrazole (HL1, HL2) - biologically important bidentate ligands with one ambidentate donor site [J] . Barik AK., Butcher RJ., Kar SK., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第28期

机译：钴（III）与3,5-二甲基-1-（N-甲基/乙基）硫代氨基甲酰基吡唑（HL1，HL2）的两种三螯合物的合成和表征-生物上重要的双齿配体，带有一个歧义的供体位点
3. Syntheses, characterization, X-ray crystal structures and emission properties of copper(II), zinc(II) and cadmium(II) complexes of pyridyl-pyrazole derived Schiff base ligand - Metal selective ligand binding modes [J] . Das K., Mandal T.N., Roy S., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第15期

机译：吡啶-吡唑衍生的席夫碱配体的铜（II），锌（II）和镉（II）配合物的合成，表征，X射线晶体结构和发射特性-金属选择性配体结合模式
4. Surface, morphology and X-ray diffraction studies of Co (II) complexes of pyrazole ligands [C] . A. Mishra, Garima Jain, S. Ninama International Conference on Recent Trends in Physics . 2014

机译：吡唑配体CO（II）复合物的表面，形态学和X射线衍射研究
5. Iron and copper complexes of a binucleating pyrazole ligand: Biologically relevant models for the diiron centers in metalloproteins [D] . Hahn, Carl William 1997

机译：二核吡唑配体的铁和铜配合物：金属蛋白中二铁中心的生物学相关模型
6. Synthesis characterization and potent superoxide dismutase like activity of novel bis(pyrazole) – 22′-bipyridyl mixed ligand copper(II) complexes [O] . Andrei S. Potapov, Evgenia A. Nudnova, Galina A. Domina, -1

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7. Platinum (II) and palladium (II) complexes with (N,N') and (C,N,N') ligands derived from pyrazole as anticancer and antimalarial agents: synthesis, characterization and in vitro activities [O] . Quirante Serrano Josefina, Ruiz Daniel, González Gazulla Asensio, 2014

机译：具有吡唑作为抗癌和抗疟药的（N，N'）和（C，N，N'）配体的铂（II）和钯（II）配合物：合成，表征和体外活性

Copper(II) and nickel(II) complexes of pyrazole derived ligands: Synthesis, characterization and coordinating properties of two substituted thiocarbamyl pyrazoles, 3,5-dimethyl-1-N-methyl/ethyl thiocarbamyl pyrazole (HL1, HL2), potential ligands for

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