Synthesis and structures of technetium(I) and rhenium(I) tricarbonyl complexes with bis(diphenylthiophosphoryl)amide, {M(CO)(3)[(Ph2PS)(2)N](CH3CN)} (M = Tc, Re)

Abram U.; Schibli R.; Alberto R.; Dilworth JR.; Abram S.

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Synthesis and structures of technetium(I) and rhenium(I) tricarbonyl complexes with bis(diphenylthiophosphoryl)amide, {M(CO)(3)[(Ph2PS)(2)N](CH3CN)} (M = Tc, Re)

机译：carbonyl（I）和rh（I）三羰基与双（二苯基硫代磷酰基）酰胺{M（CO）（3）[（Ph2PS）（2）N]（CH3CN）}的合成和结构（M = Tc，Re）

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Complexes of the general formula {M(CO)(3)[(Ph2PS)(2)N] (CH3CN)} (M = Tc, Re) have been prepared by the reaction of (Et4N)(2)[M(CO)(3)X-3] (M = Tc, Re; X -Cl, Br) with sodium bis(diphenylthiophosphoryl)amide, Na[(Ph2PS)(2)N], in acetonitrile. The metal is six-coordinate with facially arranged carbonyl ligands. Bis(diphenylthiophosphoryl) amide is deprotonated and bonded as S,S'-chelate with Tc-S distances of 2.526(3) and 2.546(3) Angstrom. Acetonitrile occupies the sixth coordination position. The rhenium compound is isomorphous and the bonding situation in {Re(CO)(3)[(Ph2PS)(2)N](CH3CN)} is similar to that in its technetium analogue. (Et4N)[Re(CO)(3)Br-2(CH3CN)] crystallizes from a hot acetonitrile solution of (Et4N)(2)[Re(CO)(3)Br-3] despite the fact that in solution only [Re(CO)(3)(CH3CN)(3)](+) can be detected spectroscopically. It has a facial arrangement of CO groups in an octahedral co-ordination geometry. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 25]

机译：通式{M（CO）（3）[（Ph2PS）（2）N]（CH3CN）}（M = Tc，Re）的配合物是通过（Et4N）（2）[M（CO ）（3）X-3]（M = Tc，Re; X -Cl，Br）与双（二苯基硫代磷酰基）酰胺钠Na [（Ph2PS）（2）N]，在乙腈中。该金属为六配位，表面排列有羰基配体。双（二苯基硫代磷酰基）酰胺被去质子化并键合为S，S'螯合物，Tc-S距离为2.526（3）和2.546（3）埃。乙腈居第六位。 compound化合物是同构的，在{Re（CO）（3）[（Ph2PS）（2）N]（CH3CN）}中的键合情况与其tech类似物相似。尽管仅在溶液中，但（Et4N）[Re（CO）（3）Br-2（CH3CN）]从（Et4N）（2）[Re（CO）（3）Br-3]的热乙腈溶液中结晶可以用光谱法检测[Re（CO）（3）（CH3CN）（3）]（+）。它具有八面体配位几何形状的CO基团的面部排列。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：25]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第8期|共7页
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Abram U.; Schibli R.; Alberto R.; Dilworth JR.; Abram S.;
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1. Synthesis and structures of technetium(I) and rhenium(I) tricarbonyl complexes with bis(diphenylthiophosphoryl)amide, {M(CO)(3)[(Ph2PS)(2)N](CH3CN)} (M = Tc, Re) [J] . Abram U., Schibli R., Alberto R., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第8期

机译：carbonyl（I）和rh（I）三羰基与双（二苯基硫代磷酰基）酰胺{M（CO）（3）[（Ph2PS）（2）N]（CH3CN）}的合成和结构（M = Tc，Re）
2. Structural models for [M(CO)(3)(H2O)(3)](+) (M = Tc, Re): fully aqueous synthesis of technetium and rhenium tricarbonyl complexes of tripodal oxygen donor ligands [J] . Kramer DJ., Jones AG., Davison A. Inorganica Chimica Acta . 2001,第1a2期

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Synthesis and structures of technetium(I) and rhenium(I) tricarbonyl complexes with bis(diphenylthiophosphoryl)amide, {M(CO)(3)[(Ph2PS)(2)N](CH3CN)} (M = Tc, Re)

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