SYNTHESIS AND CHARACTERIZATION OF ME(3)GA AND ME(3)IN - ADDUCTS OF SECONDARY AMINES

Schauer SJ.; Krannich LK.; Gala RB.; Gundy EM.; Lagrone CB.; Watkins CL.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >SYNTHESIS AND CHARACTERIZATION OF ME(3)GA AND ME(3)IN - ADDUCTS OF SECONDARY AMINES

【24h】

SYNTHESIS AND CHARACTERIZATION OF ME(3)GA AND ME(3)IN - ADDUCTS OF SECONDARY AMINES

机译：仲胺诱导物中ME（3）GA和ME（3）的合成与表征

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reactions of trimethylgallium and trimethylindium with a variety of secondary amines [HNMe(2), HNEt(2), HNPr2n, HNPr2i, HNBu(2)(n), HNBu(2)(i), HNBu(2)(s), HN(CH(2)Ph)(2), HN(c-C6H11)(2), HNC4HB8 HNC5H10, HNC6H12 and HN(CH(2)CH2)(2)NMe], produce a series of room-temperature stable liquid or solid adducts. These were characterized by H-1 and C-13 NMR, IR, mass spectrometry and elemental analysis. Spectroscopic comparisons are made between these and the corresponding trimethylaluminum derivatives. H-1 and C-13 NMR data for all three series of adducts indicate a correlation between the chemical shifts of the methyl groups on the metal and the relative steric requirements of the amines. The data show a general downfield movement of these chemical shifts with increasing steric bulk. [References: 39]

机译：三甲基镓和三甲基铟与各种仲胺[HNMe（2），HNEt（2），HNPr2n，HNPr2i，HNBu（2）（n），HNBu（2）（i），HNBu（2）（s）的反应，HN（CH（2）Ph）（2），HN（c-C6H11）（2），HNC4HB8 HNC5H10，HNC6H12和HN（CH（2）CH2）（2）NMe]，产生一系列室温稳定的液体或固体加合物。这些通过H-1和C-13 NMR，IR，质谱和元素分析来表征。在这些和相应的三甲基铝衍生物之间进行光谱比较。所有三个系列加合物的H-1和C-13 NMR数据表明金属上甲基的化学位移与胺的相对空间要求之间存在相关性。数据显示，这些化学位移随空间体积的增加而在一般的低场运动。 [参考：39]

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第24期|共10页
作者
Schauer SJ.; Krannich LK.; Gala RB.; Gundy EM.; Lagrone CB.; Watkins CL.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词
Ray crystal-structures; Ligands; Complexes; Ammonia;

机译：射线晶体结构配体络合物氨;

相似文献

外文文献
中文文献
专利

1. SYNTHESIS AND CHARACTERIZATION OF ME(3)GA AND ME(3)IN - ADDUCTS OF SECONDARY AMINES [J] . Schauer SJ., Krannich LK., Gala RB., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1995,第23a24期

机译：仲胺诱导物中ME（3）GA和ME（3）的合成与表征
2. A reinvestigation into the reaction of NH4OAc with acetyl derivatives of Baylis-Hillman adducts: Formation of tertiary and secondary allyl amines instead of primart allyl amines [J] . Singh V, Pathak R, Kartojiya S, Synlett . 2005,第16期

机译：对NH4OAc与Baylis-Hillman加合物的乙酰基衍生物的反应的再研究：形成叔胺和仲烯丙基胺，而不是伯仲烯丙基胺
3. Carbene adduct of cyclopalladated ferrocenylirnine-assisted synthesis of aminopyridine derivatives by the amination of chloropyridines with primary and secondary amines [J] . Bing Mu, Jingya Li, Yangjie Wu Applied Organometallic Chemistry . 2013,第9期

机译：通过氯吡啶与伯胺和仲胺的胺化作用，环钯化的二茂铁基二烯丙氨酸辅助合成氨基吡啶衍生物的碳环加合物
4. Synthesis and characterization of polyisobutylene-amine from polyisobutylene and tetraethylenepentamine and its performance as deposit control additive in one cylinder gasoline engine [C] . Ir. Sukirno, Luki Farhandika International Tropical Renewable Energy Conference . 2020

机译：聚异丁烯与四亚乙基二胺的合成与表征，其作为一种气缸汽油发动机沉积物控制添加剂的性能及其性能
5. Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation [D] . Shin, Hyunshun 2001

机译：A部分：通过N-二苯基膦亚胺的还原/烷基化或去质子化/烷基化的非对映选择性合成保护的仲胺。 B部分：通过将有机金属试剂1,2-加成到N-二苯基膦亚胺和随后的烷基化反应来合成仲胺
6. Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand Promoted Ruthenium Catalyzed Deaminative Coupling Reaction of Primary Amines [O] . Pandula T. Kirinde Arachchige, Hanbin Lee, Chae S. Yi -1

机译：由配体促进的钌催化的伯胺的脱氨偶联反应合成对称和不对称的仲胺
7. Synthesis and Characterization of Highly Porous Borazine-Linked Polymers via Dehydrogenation/Dehydrocoupling of Borane-Amine Adducts and Their Applications to Gas Storage [O] . Jackson Karl 2011

机译：硼烷-胺加合物的脱氢/脱氢偶联反应制备高多孔性与硼嗪连接的聚合物及其在储气中的应用
8. Synthesis and Characterization of an Organothallium-Phosphorus Adduct: CrystalStructure of (Me3SiCH23 Tl-P(SiMe3))3 [R] . Baldwin, R. A., Wells, R. L., White, P. S. 1996

机译：有机磷 - 磷加合物的合成与表征：（me3siCH23 Tl-p（sime3））3的晶体结构

SYNTHESIS AND CHARACTERIZATION OF ME(3)GA AND ME(3)IN - ADDUCTS OF SECONDARY AMINES

摘要

著录项

相似文献

相关主题

期刊订阅