NOVEL N,N'-METHYLENE-BRIDGED METAL(II) COMPLEXES OF N,N'-METHYLENEDI(4-HYDROXY-L-PROLINE) OBTAINED FROM THE CONDENSATION OF BIS(4-HYDROXY-L-PROLINATO)METAL(II) WITH FORMALDEHYDE

Teo SB.; Ng CH.; Fun HK.; Declercq JP.; Teoh SG.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >NOVEL N,N'-METHYLENE-BRIDGED METAL(II) COMPLEXES OF N,N'-METHYLENEDI(4-HYDROXY-L-PROLINE) OBTAINED FROM THE CONDENSATION OF BIS(4-HYDROXY-L-PROLINATO)METAL(II) WITH FORMALDEHYDE

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NOVEL N,N'-METHYLENE-BRIDGED METAL(II) COMPLEXES OF N,N'-METHYLENEDI(4-HYDROXY-L-PROLINE) OBTAINED FROM THE CONDENSATION OF BIS(4-HYDROXY-L-PROLINATO)METAL(II) WITH FORMALDEHYDE

机译：新型N，N'-亚甲基桥接金属（II）的N，N'-亚甲基二（4-羟基-L-脯氨酸）的络合物是通过BIS（4-羟基-L-脯氨酸）金属（II）的缩合而得到的甲醛

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The condensation of bis(4-hydroxy-L-prolinato)metal(II) (metal = zinc, cobalt, copper, nickel) with formaldehyde led to the formation of the respective metal(II) complexes of N,N'-methylenedi(4-hydroxy-L-proline), M(II)[My(OH-Pro)(2)], each of which possesses an N,N'-methylene bridge linking the coordinated 4-hydroxy-L-proline ligands. Such linkage is without precedent in the products of the reactions of chelated amino acids with aldehydes. [References: 25]

机译：双（4-羟基-L-脯氨酰基）金属（II）（金属=锌，钴，铜，镍）与甲醛的缩合导致N，N'-亚甲基二（ 4-羟基-L-脯氨酸），M（II）[My（OH-Pro）（2）]，每个均具有连接配位的4-羟基-L-脯氨酸配体的N，N'-亚甲基桥。这种连接在螯合氨基酸与醛反应的产物中没有先例。 [参考：25]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第11期|共5页
作者
Teo SB.; Ng CH.; Fun HK.; Declercq JP.; Teoh SG.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Ray crystal-structure; Amino-acids; Copper(ii); Nickel(ii); Ammonia;

机译：射线晶体结构;氨基酸;铜（ii）;镍（ii）;氨;

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NOVEL N,N'-METHYLENE-BRIDGED METAL(II) COMPLEXES OF N,N'-METHYLENEDI(4-HYDROXY-L-PROLINE) OBTAINED FROM THE CONDENSATION OF BIS(4-HYDROXY-L-PROLINATO)METAL(II) WITH FORMALDEHYDE

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