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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >On the reactions of chlorodithlophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part III: Reactions with monoalkylderivatives of thiosemicarbazide
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On the reactions of chlorodithlophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles. Part III: Reactions with monoalkylderivatives of thiosemicarbazide

机译:氯二磷酸吡啶甜菜碱与多官能亲核试剂的反应。第三部分:与硫代氨基脲的单烷基衍生物的反应

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摘要

Reactions of chlorodithiophosphoric acid pyridiniumbetaine, PY center dot PS2Cl (I) with monosubstituted thiosemicarbazide derivatives RN(H)C(S)N(H)NH2, (R = methyl, ethyl), in acetonitrile media and in the presence of pyridine as an HCl acceptor were studied. New five-membered heterocyclic compounds were prepared, pyridinium salts of 4-methyl-3-sulfido-3,5-dithioxo-1,2,4,3 lambda(5)-triazaphospholidine (II) and 4-ethyl-3-sulfido-3,5-dithioxo-1,2,4,3 lambda(5)-triazaphospholidine (III). The substances II and III were completely characterized by P-31 NMR, FT-IR, Raman spectroscopies and their molecular structures were determined by the X-ray diffraction analysis. (c) 2005 Elsevier Ltd. All rights reserved.
机译:氯二硫代磷酸吡啶甜菜碱,PY中心点PS2Cl(I)与单取代的硫代氨基脲衍生物RN(H)C(S)N(H)NH2(R =甲基,乙基)在乙腈介质中和在吡啶存在下的反应研究了HCl受体。制备了新的五元杂环化合物,4-甲基-3-硫代-3,5-二硫代-1,2,4,3λ(5)-三氮杂膦(II)和4-乙基-3-硫代的吡啶鎓盐-3,5-二硫代-1,2,4,3 lambda(5)-三氮磷吡啶(III)。通过P-31 NMR,FT-IR,拉曼光谱对II和III物质进行了完全表征,并通过X射线衍射分析确定了它们的分子结构。 (c)2005 Elsevier Ltd.保留所有权利。

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