Magnesium Bisamides as Reagents in Synthesis

Kenneth W.Henderson; William J.Kerr

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Magnesium Bisamides as Reagents in Synthesis

机译：双酰胺镁合成试剂

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摘要

As part of the continued requirement for more selective reagents in ofganic synthesis,magnesium bisamides are becoming established as a class of ofganometallic bases with considerable potential .Their relatively mild reactivity,combined with their high degree of steric congestion,leads to a distinct class of reagents with significantly different chemo-,regio-,stereo- and enantioselectivities when compared with existing species and protocols.

机译：作为对有机合成中对更多选择性试剂的持续需求的一部分，双酰胺镁已被确立为一类具有相当大潜力的纳米金属碱。它们相对温和的反应性，加上高度的空间拥堵程度，导致产生了一类独特的试剂与现有物种和实验方案相比，化学，区域，立体和对映选择性显着不同。

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《Chemistry: A European journal》 |2001年第16期|共8页
作者
Kenneth W.Henderson; William J.Kerr;
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原文格式 PDF
正文语种 eng
中图分类化学;应用化学;
关键词
aldol reaction; amination; astnnetruc synthesis; magnesium; n ligands;

机译：醛醇缩合反应;胺化;星形胶合成;镁;n配体;

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专利

1. Magnesium Bisamides as Reagents in Synthesis [J] . Kenneth W.Henderson, William J.Kerr Chemistry: A European journal . 2001,第16期

机译：双酰胺镁合成试剂
2. Synthesis of cyclopropanes via iodine-magnesium exchange between 3-iodomethyl-1-oxacyclopentanes and organomagnesium reagents [J] . Tsuji T., Nakamura T., Yorimitsu H., Tetrahedron . 2004,第4期

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3. Novel organomagnesium reagents in synthesis. Catalytic cyclomagnesiation of allenes in the synthesis of N-, O-, and Si-substituted 1Z,5Z-dienes [J] . DYakonov V.A., Makarov A.A., Makarova E.K., Tetrahedron . 2013,第39期

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4. Efficient synthesis of bridged δ-lactams from δ-bromo-2-methoxypyridine using magnesium 'ate' complexes as key reagents [C] . Jacek G. Sosnicki European Symposium on Organic Chemistry . 2009

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5. Observations in reactivity between boron-hydrogen containing compounds and organometallic reagents: synthesis of boronic acids, boronic esters, and magnesium hydrides [D] . Clary, Jacob William 2012

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6. Acyclic 12-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis [O] . Deepak Dange, Andrew R. Gair, Dafydd D. L. Jones, 2019

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7. Synthesis of Functionalized Heterocycles Using Magnesium and Zinc Reagents. Diastereoselective Addition of Allylic Aluminum Reagents to Carbonyl Compounds. Preparation and Application of Aromatic and Benzylic Manganese Reagents [O] . Peng Zhihua 2011

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Magnesium Bisamides as Reagents in Synthesis

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