Enantioselective Organocatalytic Conjugate Addition of FluorocarbonNucleophiles to ,-Unsaturated Aldehydes

Farman Ullah; Gui-Ling Zhao; Luca Deiana; Mingzhao Zhu; Pawel Dziedzic; IalIsmail Ibrahem; Peter Hammar; JunHang Sun; Armando Cordovelal

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Enantioselective Organocatalytic Conjugate Addition of FluorocarbonNucleophiles to ,-Unsaturated Aldehydes

机译：对映选择性有机催化共轭加氟碳亲核试剂到，-不饱和醛

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ofFBSM in non-asymmetric nucleophilic epoxide openings."Recently, Shibata and co-workers reported the enantioselec-tive addition of FBSM to chalcone derivatives using cincho-na-derived ammonium salts as catalysts.[8a1 Prakash andOlah almost simultaneously reported the addition of 1-fluoro-1-nitro(phenylsulfonyl)methane (FNSM) to chalconesemploying cinchona-based bifunctional chiral catalysts.~([8b])

机译：“最近，Shibata及其同事报道了使用cincho-na衍生的铵盐作为催化剂，向查尔酮衍生物中对映体添加FBSM的对映体。[8a1 Prakash和Olah几乎同时报道了添加1 -氟-1-硝基（苯磺酰基）甲烷（FNSM）合成金鸡纳基双功能手性催化剂的查耳酮。〜（[8b]）

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《Chemistry: A European journal》 |2009年第39期|共5页
作者
Farman Ullah; Gui-Ling Zhao; Luca Deiana; Mingzhao Zhu; Pawel Dziedzic; IalIsmail Ibrahem; Peter Hammar; JunHang Sun; Armando Cordovelal;
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正文语种 eng
中图分类应用化学;
关键词
Enantioselective; Organocatalytic; Conjugate;

机译：对映选择性;有机催化;共轭;

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1. Enantioselective Organocatalytic Conjugate Addition of FluorocarbonNucleophiles to ,-Unsaturated Aldehydes [J] . Farman Ullah, Gui-Ling Zhao, Luca Deiana, Chemistry: A European journal . 2009,第39期

机译：对映选择性有机催化共轭加氟碳亲核试剂到，-不饱和醛
2. Organocatalytic enantioselective formal conjugate addition of a hydroxymoyl anion to α,β-unsaturated aldehydes [J] . Alonso B., Reyes E., Carrillo L., Chemistry: A European journal . 2011,第22期

机译：向α，β-不饱和醛的羟基催化阴离子的有机催化对映体选择性共轭加成反应
3. Enantioselective Organocatalytic Conjugate Addition of Aldehydes to α,β-Unsaturated Thiol Esters [J] . Shaolin Zhu, You Wang, Dawei Ma Advanced synthesis & catalysis . 2009,第16期

机译：醛与α，β-不饱和硫醇酯的对映选择性有机催化共轭加成反应
4. Enantioselective Organocatalytic Michael Addition of Aldehydes to β-Nitrostyrenes [C] . Marju Laars, Kerti Ausmees, Tonis Kanger European Symposium on Organic Chemistry . 2009

机译：对β-硝化丁烯的映选择性有机催化迈克尔添加醛
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to αβ-Unsaturated Ketones Esters Weinreb Amides and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes [O] . Hao Wu, Suttipol Radomkit, Jeannette M. O’Brien, -1

机译：金属 - 催化免不对称C-B键的形成：（频哪醇）硼共轭加成到αβ不饱和酮酯酰胺的Weinreb和醛手性N-杂环卡宾推荐
7. The Enantioselective Organocatalytic 1,4-Addition of Electron-Rich Benzenes to α,β-Unsaturated Aldehydes [O] . Paras Nick A., MacMillan David W. C. 2002

机译：电子富集的苯向α，β-不饱和醛的对映选择性有机催化1,4-加成
8. Chiral Oxazaborolidines as Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes [R] . Joshi, N. N., Srebnik, M., Brown, H. C. 1989

机译：手性恶唑硼烷作为二乙基锌对醛的不对称加成催化剂

Enantioselective Organocatalytic Conjugate Addition of FluorocarbonNucleophiles to ,-Unsaturated Aldehydes

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