Water-soluble Ir~(III) N-heterocyclic carbene based catalysts for the reduction of CO_2 to formate by transfer hydrogenation and the deuteration of aryl amines in water

Azua A.; Sanz S.; Peris E.

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Water-soluble Ir~(III) N-heterocyclic carbene based catalysts for the reduction of CO_2 to formate by transfer hydrogenation and the deuteration of aryl amines in water

机译：水溶性Ir〜（III）N-杂环卡宾基催化剂，用于通过转移氢化和芳基胺的氘化将CO_2还原为甲酸

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Two new water-soluble [IrI_2(AcO)(bis-NHC)] complexes (NHC=N-heterocyclic carbene) incorporating a sulfonate functionality have been synthesized. The two complexes have been tested in the reduction of CO _2 with H_2 and iPrOH, and their activity has been compared with similar species without the sulfonate moiety. In both reactions, the complex with the two abnormally bound NHCs shows the best catalytic efficiencies, due to the higher δ-electron-donor character of the ligand. Remarkably, the activities obtained for the reduction of CO_2 under the transfer hydrogenation conditions are the best reported to date in terms of TON value (max. TON=2700). The two new complexes have also shown very good activity in the selective deuteration of arylamines, a process that is known to proceed through a chelate assisted N-directed process.

机译：合成了两种新的具有磺酸盐官能团的水溶性[IrI_2（AcO）（双-NHC）]络合物（NHC = N-杂环卡宾）。已经测试了这两种配合物在用H_2和iPrOH还原CO _2中的作用，并将它们的活性与没有磺酸盐部分的相似物质进行了比较。在这两个反应中，由于配体具有更高的δ电子给体特性，具有两个异常结合的NHC的配合物显示出最佳的催化效率。值得注意的是，就转移值而言，在转移氢化条件下获得的用于还原CO_2的活性是迄今为止报道得最好的（最大TON = 2700）。两种新的配合物在芳基胺的选择性氘代中也显示出非常好的活性，该过程已知通过螯合辅助的N定向过程进行。

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《Chemistry: A European journal》 |2011年第14期|共5页
作者
Azua A.; Sanz S.; Peris E.;
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正文语种 eng
中图分类应用化学;
关键词
deuteration; iridium; N-heterocyclic carbenes; reduction; water chemistry;

机译：氘;铱;N-杂环卡宾;还原;水化学;

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1. Water-soluble Ir~(III) N-heterocyclic carbene based catalysts for the reduction of CO_2 to formate by transfer hydrogenation and the deuteration of aryl amines in water [J] . Azua A., Sanz S., Peris E. Chemistry: A European journal . 2011,第14期

机译：水溶性Ir〜（III）N-杂环卡宾基催化剂，用于通过转移氢化和芳基胺的氘化将CO_2还原为甲酸
2. Water-soluble transition metal complexes of ruthenium(II), osmium(II), rhodium(III) and iridium(III) with chelating N-heterocyclic carbene ligands in hydrogenation and transfer hydrogenation catalysis [J] . Castanon Esther Bayon, Kaposi Marlene, Reich Robert M., Dalton transactions: An international journal of inorganic chemistry . 2018,第7期

机译：钌（II），锇（II），铑（III）和铱（III）的水溶性过渡金属配合物，其具有螯合和转移氢化催化的N-杂环碳酸丁烯配体
3. Efficient transfer hydrogenation of carbonate salts from glycerol using water-soluble iridium N-heterocyclic carbene catalysts [J] . Ainembabazi Diana, Wang Kai, Finn Matthew, Green chemistry . 2020,第18期

机译：使用水溶性铱N-杂环碳丙基催化剂高效地转移甘油盐的碳酸盐盐
4. Half-Sandwich Complexes with 4,7-Dihydroxy-l,10-phenanthroline:Water-Soluble and Highly Efficient Catalysts for Hydrogenation of CO_2 Attributable to the Electron-Donating Ability of the Oxyanion on Catalyst Ligand [C] . Yuichiro Himeda, Nobuko Onozawa-Komatsuzaki, Hideki Sugihara, Symposium on Organometallic Chemistry . 2003

机译：半三明治配合物，具有4,7-二羟基-1,10-菲咯啉：水溶性和高效催化剂，其含有氧气对催化剂配体的电子捐赠能力的CO_2
5. Part I. Asymmetric hydrosilylation of acetophenone using titanium catalysts. Part II. Synthesis of water-soluble palladacycles and their applications to the Suzuki reaction. Part III. Rhodium-catalyzed addition of aryl and alkenylboronic acids to aldehyde [D] . Huang, Rongcai. 2005

机译：第一部分：使用钛催化剂的苯乙酮不对称氢化硅烷化。第二部分水溶性palladacycles的合成及其在铃木反应中的应用。第三部分铑催化的芳基和烯基硼酸加成醛
6. Iridium N-Heterocyclic Carbene Complexes as Efficient Catalysts for Magnetization Transfer from para-Hydrogen [O] . Michael J. Cowley, Ralph W. Adams, Kevin D. Atkinson, -1

机译：铱N-杂环碳烯络合物作为从对氢磁化转移的有效催化剂
7. Water-soluble IrIII n-heterocyclic carbene based catalysts for the reduction of CO2 to formate by transfer hydrogenation and the deuteration of aryl amines in water [O] . Azua Barrios Arturo, Sanz Sergio, Peris Fajarnés Eduardo 2011

机译：水溶性IrIII n-杂环卡宾催化剂，通过转移氢化和芳基胺在水中的氘化将CO 2还原成甲酸

Water-soluble Ir~(III) N-heterocyclic carbene based catalysts for the reduction of CO_2 to formate by transfer hydrogenation and the deuteration of aryl amines in water

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