Pd-catalyzed C-N bond formation with heteroaromatic tosylates

Mantel M.L.H.; Lindhardt A.T.; Lupp D.; Skrydstrup T.

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Pd-catalyzed C-N bond formation with heteroaromatic tosylates

机译：钯催化的杂芳族甲苯磺酸盐形成C-N键

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A protocol for the palladium(0)-catalyzed amidation of heteroaromatic tosylates was successfully developed. The methodology proved to be effective for a variety of heteroaryl tosylates including the pyridine, pyrimidine, quinoline and quinoxaline ring systems. Successful carbon-nitrogen bond formation with these heteroaryl tosylates could be performed with a wide range of primary amides, oxazolidinones, lactams, anilines and indoles, including one cyclic urea. Moreover, this C-N bond forming reaction provided products with high structural diversity. The coupling reaction was also amenable to scale up applications.

机译：成功开发了钯（0）催化杂芳族甲苯磺酸酯酰胺化的协议。该方法论证明对多种杂芳基甲苯磺酸酯有效，包括吡啶，嘧啶，喹啉和喹喔啉环系。这些杂芳基甲苯磺酸盐可成功形成碳-氮键，可使用多种伯酰胺，恶唑烷酮，内酰胺，苯胺和吲哚，包括一种环脲进行。此外，该C-N键形成反应提供了具有高结构多样性的产物。偶联反应也适合扩大规模的应用。

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《Chemistry: A European journal》 |2010年第18期|共6页
作者
Mantel M.L.H.; Lindhardt A.T.; Lupp D.; Skrydstrup T.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Aryl tosylates; C-n bond formation; Heterocycles; Heterogeneous catalysis; Palladium;

机译：芳基甲苯磺酸盐;C-n键形成;杂环;非均相催化;钯;

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1. Pd-catalyzed C-N bond formation with heteroaromatic tosylates [J] . Mantel M.L.H., Lindhardt A.T., Lupp D., Chemistry: A European journal . 2010,第18期

机译：钯催化的杂芳族甲苯磺酸盐形成C-N键
2. Monodentate Phosphines Provide Highly Active Catalysts for Pd-Catalyzed C-N Bond-Forming Reactions of Heteroaromatic Halides/Amines and (H)N-Heterocycles [J] . Kevin W.Anderson, Rachel E.Tundel, Takashi Ikawa Angewandte Chemie . 2006,第39期

机译：单齿膦为杂芳族卤化物/胺和（H）N-杂环的Pd催化C-N键形成反应提供了高活性催化剂
3. Pd-Catalyzed Sequential C-C and C-N Bond Formations for the Synthesis of N-Heterocycles: Exploiting Protecting Group-Directed C-H Activation under Modified Reaction Conditions [J] . Byung Seok Kim, Sun Young Lee, So Won Youn Chemistry, an Asian journal . 2011,第8期

机译：用于合成N-杂环的Pd催化的连续C-C和C-N键形成：在修饰的反应条件下利用保护基定向的C-H活化
4. Electronic properties study of reaction mechanism of C-N bonding formation in AC-DT-NH2 and AC-TD-NH2 peptide by ab initio computational on HF/6-31g** level [C] . Parsaoran Siahaan, Marta J Sipangkar, Siti Nur Milatus Salimah Joint Conference on Chemistry . 2019

机译：AB Initio在HF / 6-31G **水平上计算AC-DT-NH2和AC-TD-NH2肽C-N键合形成反应机理的电子性质研究
5. Catalytic C-C (C-N) Bond Formation and C-O Bond Cleavage by Pincer-Ligated Iridium Complexes [D] . Li, Bo. 2019

机译：掺杂剂铱络合物催化C-C（C-N）键合形成和C-O键切割
6. Intramolecular C-N Bond Formation via Thermal Arene C-H Bond Activation Supported by Au(III) Complexes [O] . Julianna Mruk, Agata J. Pacuła-Miszewska, Leszek Pazderski, 2021

机译：通过Au（III）配合物支持的热芳烃C-H键活化的分子内C-N键形成
7. Advances in the Stille reaction and new methods for continuous flow Pd-catalyzed C-N bond forming reactions [O] . Naber John R. (John Robert) 2010

机译：stille反应的进展和连续流动pd催化的C-N键形成反应的新方法

Pd-catalyzed C-N bond formation with heteroaromatic tosylates

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