Efficient synthesis of biologically interesting 3,4-diaryl-substituted succinimides and maleimides: Application of iron-catalyzed carbonylations

Prateeptongkum S.; Driller K.M.; Jackstell R.; Spannenberg A.; Beller M.

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Efficient synthesis of biologically interesting 3,4-diaryl-substituted succinimides and maleimides: Application of iron-catalyzed carbonylations

机译：有效合成生物学上有趣的3,4-二芳基取代的琥珀酰亚胺和马来酰亚胺：铁催化羰基化的应用

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A straightforward two-step synthesis of trans-3,4-disubstituted succin imides through a palladium-catalyzed Sonogashira reaction and an iron-catalyzed double carbonylation is described. In situ oxidative dehydrogenation gave the corresponding 3,4-diarylmaleimides. By starting from readily available aryl and hetgeroaryl halides, a variety of new analogues and derivatives of bioactive 3,4-bisindolylmaleimides are obtained in good yield and selectivity.

机译：描述了通过钯催化的Sonogashira反应和铁催化的双羰基化的反式3，4-二取代的琥珀酰亚胺的直接两步合成法。原位氧化脱氢得到相应的3，4-二芳基马来酰亚胺。通过从容易获得的芳基和杂芳基卤化物开始，以良好的产率和选择性获得了多种新的具有生物活性的3,4-二吲哚基马来酰亚胺的类似物和衍生物。

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《Chemistry: A European journal》 |2010年第31期|共10页
作者
Prateeptongkum S.; Driller K.M.; Jackstell R.; Spannenberg A.; Beller M.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Carbonylation; Iron; Maleimides; Reaction; Sonogashira; Succinimides;

机译：羰基化;铁;马来酰亚胺;反应;Sonogashira;琥珀酰亚胺;

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1. Efficient synthesis of biologically interesting 3,4-diaryl-substituted succinimides and maleimides: Application of iron-catalyzed carbonylations [J] . Prateeptongkum S., Driller K.M., Jackstell R., Chemistry: A European journal . 2010,第31期

机译：有效合成生物学上有趣的3,4-二芳基取代的琥珀酰亚胺和马来酰亚胺：铁催化羰基化的应用
2. Efficient synthesis of biologically interesting 3,4-diaryl-substituted succinimides and maleimides: Application of iron-catalyzed carbonylations [J] . Prateeptongkum S., Driller K.M., Jackstell R., Chemistry: A European journal . 2010,第31期

机译：有效合成生物学上有趣的3,4-二芳基取代的琥珀酰亚胺和马来酰亚胺：铁催化羰基化的应用
3. Efficient Synthesis of Biologically Interesting 3,4-Diaryl-Substituted Succinimides and Maleimides: Application of Iron-Catalyzed Carbonylations [J] . Saisuree Prateeptongkum Katrin Marie Driller Ralf Jackstell Dr. Anke Spannenberg Dr. Matthias Beller Prof. Dr. Chemistry - A European Journal . 2010,第31期

机译：有效合成生物上有趣的3,4-二芳基取代的琥珀酰亚胺和马来酰亚胺：铁催化羰基化的应用
4. CLEAN AND EFFICIENT SYNTHESIS OF N-ARYL AND N-ALKYL SUCCINIMIDES IN SUB-CRITICAL WATER [C] . Serkan Faruk Alpman, Serkan Koldas, Elife Sultan Giray International Symposium on Supercritical Fluids . 2009

机译：在亚临界水中清洁和有效地合成N-芳基和N-烷基琥珀酰亚胺
5. Ring-expanding carbonylation of epoxides: Applications in the synthesis of polyesters, pharmaceuticals, and fine chemical building blocks [D] . Tiegs, Brandon Joel. 2016

机译：环氧化物的环形羰基化：在合成聚酯，药物和精细化学积木的应用中的应用
6. Collaborative Biosynthesis of Maleimide- and Succinimide-Containing Natural Products by Fungal Polyketide Megasynthases [O] . Michio Sato, Jacob E. Dander, Chizuru Sato, -1

机译：真菌聚酮化合物大合酶协同合成含马来酰亚胺和琥珀酰亚胺的天然产物
7. Synthesis of Aromatic Carbonates by Oxidative Carbonylation: Development of Efficient Palladium Complex Catalyst Systems aud Their Application to One-step Polycarbonate Synthesis. [O] . Hirotoshi Ishii, Kazuhiko Takeuchi, Michihiko Asai, 2001

机译：氧化羰基化的合成芳烃：高效钯配合物催化剂体系的发展对一步聚碳酸酯合成的应用。

Efficient synthesis of biologically interesting 3,4-diaryl-substituted succinimides and maleimides: Application of iron-catalyzed carbonylations

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