Se,ocpmdictor Type A Photocatalysis: Role of Substrate Adsorption and the Nature of Photoreactive Surface Sites in Zinc Sulfide Catalyzed C-C Coupling Reactions

Gerald Horner; Petra Johne; Ronald Kunneth

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Se,ocpmdictor Type A Photocatalysis: Role of Substrate Adsorption and the Nature of Photoreactive Surface Sites in Zinc Sulfide Catalyzed C-C Coupling Reactions

机译：硒，吸光子A型光催化：基质吸附的作用和硫化锌催化的C-C偶联反应中光反应性表面位点的性质

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The mechanism of the photodehydrodimerization of 2,5-dihydrofuran (2,5-DHF) by suspended zinc sulfide powders was investigated through emission, inhibition, adsorption, and quantum yield studies. Zinc and cadmium ions influenced the emission intensity only marginally but strongly inhibited the reaction, so the photoreactive surface sites were not identical with the emitting states, which had lifetimes in the 0.1-24 ns range.

机译：通过发射，抑制，吸附和量子产率研究，研究了悬浮的硫化锌粉末对2，5-二氢呋喃（2，5-DHF）进行光脱氢二聚的机理。锌和镉离子仅轻微影响发射强度，但强烈抑制了反应，因此光反应性表面位点与发射态不同，其寿命在0.1-24 ns范围内。

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《Chemistry: A European journal》 |1999年第1期|共10页
作者
Gerald Horner; Petra Johne; Ronald Kunneth;
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正文语种 eng
中图分类化学;应用化学;
关键词
ab initio calculations; c-c coupling; photochemistry; surface chemistry; zine sulfide;

机译：从头算;c-c耦合;光化学;表面化学;硫化锌;

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1. Se,ocpmdictor Type A Photocatalysis: Role of Substrate Adsorption and the Nature of Photoreactive Surface Sites in Zinc Sulfide Catalyzed C-C Coupling Reactions [J] . Gerald Horner, Petra Johne, Ronald Kunneth Chemistry: A European journal . 1999,第1期

机译：硒，吸光子A型光催化：基质吸附的作用和硫化锌催化的C-C偶联反应中光反应性表面位点的性质
2. C-C Coupling Reactions Catalyzed by Gold Nanoparticles: Evidence for Substrate-Mediated Leaching of Surface Atoms Using Localized Surface Plasmon Resonance Spectroscopy [J] . Mohammadparast Farshid, Dadgar Andishaeh P., Tirumala Ravi Teja A., The journal of physical chemistry, C. Nanomaterials and interfaces . 2019,第18期

机译：金纳米颗粒催化的C-C偶联反应：使用局部表面等离子体共振光谱法的基材介导的表面原子浸出的证据
3. Synthesis of 5-and 6-Azaindoles by Sequential Site-Selective Palladium-Catalyzed C-C and C-N Coupling Reactions [J] . Nguyen Thi Son, Tuan Anh Nguyen Tien, Ponce Marian Blanco, Synlett . 2020,第13期

机译：通过顺序位点选择性钯催化的C-C和C-N偶联反应合成5-和6-唑啉
4. Catalytic Reactions of Ionic Liquids as Substrates: Pd-Catalyzed Coupling Reaction of Imidazolium-Based Ionic Liquids with Aryl Halides [C] . Takahide Fukuyama, Taifur Rahman, Hideo Takahashi Symposium on Organometallic Chemistry . 2007

机译：离子液体作为底物的催化反应：咪唑鎓基离子液体与芳基卤化物的PD催化偶联反应
5. Palladium-catalyzed reductive cross-coupling reactions and the analysis of site-selectivity in rhodium-catalyzed C-H amination reactions. [D] . DeLuca, Ryan James. 2014

机译：钯催化的还原交叉偶联反应和铑催化的C-H胺化反应中的位点选择性分析。
6. Asymmetric Iridium Catalyzed C-C Coupling of Chiral Diols via Site-Selective Redox-Triggered Carbonyl Addition [O] . Inji Shin, Michael J. Krische -1

机译：通过位点选择性氧化还原引发羰基加成反应的不对称铱催化手性二元醇的C-C偶联
7. CC Coupling Reactions Catalyzed by Gold Nanoparticles: Evidence for Substrate-Mediated Leaching of Surface Atoms Using Localized Surface Plasmon Resonance Spectroscopy [O] . -1

机译：金纳米颗粒催化的CC偶联反应：使用局部表面等离子体共振光谱法的底物介导的表面原子浸出的证据

Se,ocpmdictor Type A Photocatalysis: Role of Substrate Adsorption and the Nature of Photoreactive Surface Sites in Zinc Sulfide Catalyzed C-C Coupling Reactions

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