Bridged bioxepines and bi[10]paracyclophanes - synthesis and absolute configuration of a bi[10]paracyclophane with two chiral planes and one chiral axis

Tochtermann W.; Kuckling D.; Meints C.; Kraus J.; Bringmann G.

首页> 外文期刊>Tetrahedron >Bridged bioxepines and bi[10]paracyclophanes - synthesis and absolute configuration of a bi[10]paracyclophane with two chiral planes and one chiral axis

【24h】

Bridged bioxepines and bi[10]paracyclophanes - synthesis and absolute configuration of a bi[10]paracyclophane with two chiral planes and one chiral axis

机译：架桥的生物异松油和双[10]对环环烷烃-具有两个手性平面和一个手性轴的双[10]对环烷烃的合成和绝对构型

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A preparative synthesis of novel bioxepines and bi[10]paracyclophanes with meso- and rac-configuration is described. The bi[10]paracyclophane (-)-6b with two elements of planar chirality and one chiral axis has been obtained in enantiomerically pure form. Its absolute configuration was determined by quantum chemical calculation of the circular dichroism and comparison with the experimental CID spectrum. (C) 2003 Elsevier Ltd. All rights reserved. [References: 29]

著录项

来源
《Tetrahedron》 |2003年第39期|共11页
作者
Tochtermann W.; Kuckling D.; Meints C.; Kraus J.; Bringmann G.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Oxepines; Cyclophanes; Circular dichroism; Quantum chemical cd calculations; Planar chirality; Axial chirality; Crystal-structure; Large rings; lt; c12h13o(cooch3)(2)gt; (2); Separation; Acids;

机译：Oxepines;Cyclophanes;圆二色性;量子化学cd计算;平面手性;轴向手性;晶体结构;大环;c12h13o（cooch3）（2）（2）;分离;酸;

相似文献

外文文献
中文文献
专利

1. Bridged bioxepines and bi[10]paracyclophanes - synthesis and absolute configuration of a bi[10]paracyclophane with two chiral planes and one chiral axis [J] . Tochtermann W., Kuckling D., Meints C., Tetrahedron . 2003,第39期

机译：架桥的生物异松油和双[10]对环环烷烃-具有两个手性平面和一个手性轴的双[10]对环烷烃的合成和绝对构型
2. A borderline case between meso and stable C-1: an axially chiral, yet configurationally semi-stable biphenyl with two oppositely configured [10]paracyclophane portions [J] . Bringmann G, Gulder TAM, Maksimenka K, Tetrahedron . 2005,第30期

机译：中观和稳定C-1之间的临界情况：轴向手性但构型为半稳定的联苯，具有两个相反构型的[10]对环烷部分
3. Synthesis of planar chiral [2.2]paracyclophane-based bisoxazoline ligands bearing no central chirality and application to Cu-catalyzed asymmetric O-H insertion reaction [J] . Shinji Kitagaki, Kenta Sugisaka, Chisato Mukai Organic & biomolecular chemistry . 2015,第17期

机译：不具有中心手性的平面手性[2.2]对环环烷类双恶唑啉配体的合成及其在Cu催化的不对称O-H插入反应中的应用
4. Fast bistable switching of a chiral-nematic liquid crystal cell induced by applying an in-plane electric field [C] . Seung-Won Oh, Tae-Hoon Yoon Emerging liquid crystal technologies X . 2015

机译：通过施加面内电场引起的手性向列型液晶单元的快速双稳态切换
5. Chemistry of 1,1,2,2,9,9,10,10-octafluoro-[2,2]-paracyclophane: Its synthesis and reactions. [D] . Duan, Jian-Xin. 2001

机译：1,1,2,2,9,9,10,10-八氟-[2,2]-对环环烷的化学反应：其合成和反应。
6. Planar Chiral 2.2Paracyclophane-Based Bisoxazoline Ligands and Their Applications in Cu-Mediated N–H Insertion Reaction [O] . Daniel M. Knoll, Yuling Hu, Zahid Hassan, 2019

机译：平面手性2.2环芳基的双恶唑啉配体及其在Cu介导的NH插入反应中的应用
7. Planar Chiral 2.2Paracyclophane-Based Bisoxazoline Ligands: Design, Synthesis, and Use in Cu-Catalyzed Inter- and Intramolecular Asymmetric O–H Insertion Reactions [O] . Shinji Kitagaki, Shunsuke Murata, Kisaki Asaoka, 2018

机译：平面手性2.2基于截谱的双恶唑啉配体：设计，合成，以及Cu催化和分子内不对称O-H插入反应的应用

Bridged bioxepines and bi[10]paracyclophanes - synthesis and absolute configuration of a bi[10]paracyclophane with two chiral planes and one chiral axis

摘要

著录项

相似文献

相关主题

期刊订阅