Functional Group Compatible Palladium-Catalyzed Cross-Coupling Reactions between Aryllithium and Aryl Halide Mediated by a Five-Membered Cyclic Silyl Ether

Eun-Cheol Son; Hayato Tsuji; Tomoyuki Saeki; Kohei Tamao

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Functional Group Compatible Palladium-Catalyzed Cross-Coupling Reactions between Aryllithium and Aryl Halide Mediated by a Five-Membered Cyclic Silyl Ether

机译：五元环状硅烷基醚介导的功能基兼容钯催化的芳基锂和芳基卤化物之间的交叉偶联反应

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A functional group compatible palladium-catalyzed cross-coupling reaction between aryllithiums and aryl hal-ides mediated by a five-membered cyclic silyl ether as a precursor for an activated arylsilane has been developed.The reaction proceeds under mild conditions without the addition of a fluoride salt or a base to activate the silyl reagent.

机译：已开发出五元环状硅烷基醚作为活化芳基硅烷的前体介导的官能团相容的钯催化的芳基锂与卤代芳基之间的交叉偶联反应，该反应在温和条件下进行，无需添加氟化物盐或碱激活甲硅烷基试剂。

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《Bulletin of the Chemical Society of Japan》 |2006年第3期|共3页
作者
Eun-Cheol Son; Hayato Tsuji; Tomoyuki Saeki; Kohei Tamao;
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正文语种 eng
中图分类化学;
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1. Functional Group Compatible Palladium-Catalyzed Cross-Coupling Reactions between Aryllithium and Aryl Halide Mediated by a Five-Membered Cyclic Silyl Ether [J] . Eun-Cheol Son, Hayato Tsuji, Tomoyuki Saeki, Bulletin of the Chemical Society of Japan . 2006,第3期

机译：五元环状硅烷基醚介导的功能基兼容钯催化的芳基锂和芳基卤化物之间的交叉偶联反应
2. Effect of fluorine on palladium-catalyzed cross-coupling reactions of aryl bromides with trifluoromethyl aryl ketones via difluoroenol silyl or monotluoroenol silyl ethers [J] . Yong Guo, Jeanne M. Shreeve Chemical Communications . 2007,第34期

机译：氟对钯催化芳基溴化物与三氟甲基芳基酮经由二氟烯醇甲硅烷基或单氟烯醇甲硅烷基醚的交叉偶联反应的影响
3. Indium-mediated difunctionalization of iodoalkyl-tethered unactivated alkenesviaan intramolecular cyclization and an ensuing palladium-catalyzed cross-coupling reaction with aryl halides [J] . Song Xuan-Di, Li Xiang-Rui, Wang Ya-Wen, Organic Chemistry Frontiers . 2020,第18期

机译：铟介导的碘烷基旋转的甲基苯甲酸酯型分子化与与芳酰卤相应的钯催化的交联反应进行碘烷基
4. Palladium-Catalyzed Cross-Coupling Reaction of Triallyl(aryl)silanes with Aryl Halides [C] . Akhila K.Sahoo, Takuro Oda, Yoshiaki Nakao, Symposium on Organometallic Chemistry . 2003

机译：用芳基卤化物的三叔锭（芳基）硅烷的钯催化的交联反应
5. Silylene and germylene activation of alkane, ether and amine carbon-hydrogen bonds mediated by an aryl halide. Observation of an aryl halide kinetic isotope effect for the carbon-hydrogenactivation reaction. [D] . Walker, Randon H. 2009

机译：芳基卤化物介导的烷烃，醚和胺的碳氢键的亚甲硅烷基和亚二甲基苯活化。碳-氢活化反应的芳基卤化物动力学同位素效应的观察。
6. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction [O] . Andrew P. Cinderella, Bojan Vulovic, Donald A. Watson -1

机译：钯催化的甲硅烷基亲电试剂与烷基锌卤化物的交叉偶联：甲硅烷基-Negishi反应
7. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction [O] . -1

机译：钯催化含甲硅烷基电子药物与亚烷基苯胺的交叉偶联：甲硅烷基 - 尼糊糊反应

Functional Group Compatible Palladium-Catalyzed Cross-Coupling Reactions between Aryllithium and Aryl Halide Mediated by a Five-Membered Cyclic Silyl Ether

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