...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Bulletin of the Chemical Society of Japan >Millimeter-Wave Rotational Spectrum of CF3CCD in the Ground and Excited Vibrational Statesv10 = 1
【24h】

Millimeter-Wave Rotational Spectrum of CF3CCD in the Ground and Excited Vibrational Statesv10 = 1

机译：地面和激发振动状态下CF3CCD的毫米波旋转光谱v10 = 1

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Millimeter-wave rotational spectra of the symmetric top molecule CF3CCD have been measured in its ground and excited vibrational states,v10= 1.Analysis of the ground-state spectra gave the following rotational parameters:B0 = 2696.06753 MHz,D_J = 0.22759 kHz,D_(Jk)= 6.1748 kHz.H_(Jk)(16.1 mHz)and H_(kJ)(-0.243 mHz)were determined for the first time.In the v10 = 1 state,e = +-1 series have been assigned and spectroscopic parameters were obtained accurately:B1= 2701.26211 MHz,q_t+(2,2)= 3.30887 MHz,At,= 3263.93 MHz.The off diagonal parameter r_t(0.152 MHz)was determined for the first time.
机译：测量了对称顶部分子CF3CCD在基态和激发振动状态下的毫米波旋转光谱，v10 = 1。对基态光谱的分析给出了以下旋转参数：B0 = 2696.06753 MHz，D_J = 0.22759 kHz，D_ （Jk）= 6.1748 kHz。首次确定H_（Jk）（16.1 mHz）和H_（kJ）（-0.243 mHz）。在v10 = 1状态下，已分配e = + -1系列并进行了光谱分析准确获得参数：B1 = 2701.26211 MHz，q_t +（2,2）= 3.30887 MHz，At，= 3263.93 MHz。首次确定了对角线参数r_t（0.152 MHz）。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号