Electrochemical Behavior of Indoles with Methyl, Benzyl, and Dibenzyl-4-yl Groups

I. Buder; G. Schwitzgebel; Sh. Samsoniya; E. Gogritchiani; I. Chikvaidze

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Electrochemical Behavior of Indoles with Methyl, Benzyl, and Dibenzyl-4-yl Groups

机译：具有甲基，苄基和二苄基-4-基团的吲哚的电化学行为

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2,3-Dimethylindole, N-benzyl-2-methylindole, and 2-(dibenzyl-4-yl)-7-benzylindole (DBBI) under conditions for potentiodynamic electrochemical polymerization (0.3–0.9 V vs. Ag/Ag+ in acetonitrile) underwent dimerization reactions as was shown by simulation of the potentiodynamic cycles. But DBBI alone polymerized (and only on Au), obviously because of its free N and C(3) positions. This conducting polymer could be technically interesting, because it does not show redox activities in the potential range 0.0–1.1 V vs. the Ag/AgCl electrode.

机译：2,3-二甲基吲哚，N-苄基-2-甲基吲哚和2-（二苄基-4-基）-7-苄基吲哚（DBBI）在恒动力电化学聚合条件下（相对于乙腈中的Ag / Ag +为0.3–0.9 V）进行了二聚化反应，如电位动力学循环的模拟所示。但是DBBI单独聚合（并且仅在Au上聚合），显然是由于其自由的N和C（3）位置。这种导电聚合物在技术上可能很有趣，因为与Ag / AgCl电极相比，它在0.0-1.1 V的电位范围内没有显示出氧化还原活性。

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《Chemistry of heterocyclic compounds》 |2005年第9期|共9页
作者
I. Buder; G. Schwitzgebel; Sh. Samsoniya; E. Gogritchiani; I. Chikvaidze;
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正文语种 eng
中图分类杂环化合物;
关键词
indoles; electropolymerization; cyclic voltammetry; role of substrate in polymeri-zation; simulation of CV;

机译：吲哚;电聚合;循环伏安法;聚合中底物的作用;CV模拟;

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1. Electrochemical Behavior of Indoles with Methyl, Benzyl, and Dibenzyl-4-yl Groups [J] . I. Buder, G. Schwitzgebel, Sh. Samsoniya, Chemistry of heterocyclic compounds . 2005,第9期

机译：具有甲基，苄基和二苄基-4-基团的吲哚的电化学行为
2. 5′-Benzyl--idene-1′′-methyl-4′′-phenyl-tri-spiro-[1,3-dioxolane-2,1′-cyclo-hexane-3′,3′′-pyrrolidine-2′′,3′′′-indole]-4′,2′′′-dione [J] . Kuppan Chandralekha, Deivasigamani Gavaskar, Adukamparai Rajukrishnan Sureshbabu, IUCrData . 2017,第5期

机译：5'-苄基-亚乙基-1''-甲基-4''-苯基三螺-[1,3-二氧戊环-2,1'-环己烷-3'，3''-吡咯烷-2 ′′，3′′′-吲哚] -4′，2′′′-二酮
3. Reversal of the Stereochemical Course of 1-Methyl-1H-indole Addition to Cinnamaldehyde with cis-5-Benzyl-(2-fluoromethyl)-2,3- dimethylimidazolidin-4-ones as Catalysts - a Puzzling 'Fluorine Effect' [J] . Uro? Gro?elj, ?rtomir Podlipnik, Jure Bezen?ek, Helvetica chimica acta . 2013,第10期

机译：以顺-5-苄基-（2-氟甲基）-2,3-二甲基咪唑啉丁-4-酮为催化剂，逆转1-甲基-1H-吲哚加成肉桂醛的立体化学过程-一个令人费解的“氟效应”
4. Adsorption Properties and Inhibition of Mild Steel Corrosion in 15 HCl By 3-((1H-indol-3-yl)(4-methoxyphenyl)methyl)-1H-indole: Electrochemical Study [C] . Debasis Behera, Sushil Kumar, Rajesh Ranjan Sinha, DAE Solid State Physics Symposium . 2014

机译：用3 - （（1H-吲哚-3-基）（4-甲氧基苯基）甲基）-1H-Indole中15％HCl中45％HCl中温和钢腐蚀的吸附性能和抑制作用：电化学研究
5. Part I Shorter and Improved Access to the Key Tetracyclic Core of C-19 Methyl Substituted Bioactive Sarpagine-Macroline-Ajmaline Indole Alkaloids via a New Ambidextrous Asymmetric Pictet-Spengler Reaction Beginning from Either D-(+)- or L-(-)-Tryptophan Part II the Total Synthesis of a Number of Bioactive C-19 Methyl Substituted Macroline-Sarpagine Indole Alkaloids Including Macrocarpines A-g, Talcarpine, N(4)-Methyl- N(4),21-Secotalpinine, Deoxyperaksine, Dihydroperaksine, Talpinine, O-Acetyltalpinine, as Well as N(4)-Methyltalpinine [D] . Rahman, Md Toufiqur 2018

机译：第一部分通过D-（+）-或L-（-）-开始的新的两性不对称Pictet-Spengler反应，更短和更好地利用C-19甲基取代的生物活性Sarpagine-Macroline-Ajmaline吲哚生物碱的关键四环核。色氨酸第二部分，包括大果胶Ag，塔卡品平，N（4）-甲基-N（4），21-四氢松油碱，脱氧peraksines，dihydroperaksine，Talpinine，O -乙酰基talpinine以及N（4）-甲基talpinine
6. rac-(Z)-Methyl 1-benzyl-3-(3-hydroxyquinuclidin-2-ylidene)methyl-1H-indole-6-carboxylate [O] . Narsimha Reddy Penthala, Purushotham Rao Ponugoti, Sean Parkin, 2012

机译：外消旋-（Z）-1-苄基-3-（3-羟基喹啉）-2-基亚甲基）甲基 -1H-吲哚-6-羧酸甲酯
7. rac-(Z)-Methyl 1-benzyl-3-(3-hydroxyquinuclidin-2-ylidene)methyl-1H-indole-6-carboxylate [O] . Narsimha Reddy Penthala, Purushotham Rao Ponugoti, Sean Parkin, 2012

机译：Rac-（Z） - 甲基1-苄基-3 - （3-羟基喹啉-2-百少民）甲基 -1H-吲哚-6-羧酸盐

Electrochemical Behavior of Indoles with Methyl, Benzyl, and Dibenzyl-4-yl Groups

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