UV SPECTRUM AND DECAY KINETICS OF TRANSIENT METHYLSILENE PRODUCED IN THE 193 NM PHOTOLYSIS OF GASEOUS 1-METHYL-1-SILACYCLOBUTANE

Vatsa RK.; Naik PD.; Upadhyaya HP.; Pavanaja UB.; Saini RD. Mittal JP.; Pola J.; Kumar A.

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UV SPECTRUM AND DECAY KINETICS OF TRANSIENT METHYLSILENE PRODUCED IN THE 193 NM PHOTOLYSIS OF GASEOUS 1-METHYL-1-SILACYCLOBUTANE

机译：气态1-甲基-1-硅环戊烷在193 NM光解中产生的甲基苯乙烯的紫外光谱和衰变动力学

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193 nm photolysis of gaseous 1-methyl-1-silacyclobutane with a laser fluence of 50 mJ cm(-2) yields a H2C=Si(H)CH3 transient, which decays exclusively by dimerisation to form 1,3-dimethyl-1,3-disilacyclobutane as the stable product with an estimated rate constant of (2.4 +/- 0.5) x 10(-11) cm(3) molecule(-1) s(-1). [References: 28]

机译：气态1-甲基-1-硅环丁烷在193 nm处的光通量以50 mJ cm（-2）的激光通量产生H2C = Si（H）CH3瞬态，其仅通过二聚作用而衰减以形成1,3-二甲基-1， 3-二硅环丁烷为稳定产物，估计速率常数为（2.4 +/- 0.5）x 10（-11）cm（3）分子（-1）s（-1）。 [参考：28]

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来源
《Chemical Physics Letters》 |1996年第3期|共5页
作者
Vatsa RK.; Naik PD.; Upadhyaya HP.; Pavanaja UB.; Saini RD. Mittal JP.; Pola J.; Kumar A.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Matrix-isolated dimethylsilylene; Sila-olefins; Isomerization; Silicon; 1-methylsilene; Decomposition;

机译：基质分离的二甲基甲硅烷基;硅烯烃;异构化;硅;1-甲基硅;分解;

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1. UV SPECTRUM AND DECAY KINETICS OF TRANSIENT METHYLSILENE PRODUCED IN THE 193 NM PHOTOLYSIS OF GASEOUS 1-METHYL-1-SILACYCLOBUTANE [J] . Vatsa RK., Naik PD., Upadhyaya HP., Chemical Physics Letters . 1996,第1a3期

机译：气态1-甲基-1-硅环戊烷在193 NM光解中产生的甲基苯乙烯的紫外光谱和衰变动力学
2. UV-Absorption Spectra of the Radical Transients Generated from the 193-nm Photolysis of Allene,Propyne,and 2-Butyne [J] . Askar Fahr, Allan H.Laufer The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第11期

机译：丙二烯，丙炔和2-丁炔在193 nm光解中产生的自由基瞬态的紫外吸收光谱
3. Rotational spectrum of HCBr produced by 193-nm laser photolysis of bromoform [J] . Duan CX., Hassouna M., Walters A., Journal of Molecular Spectroscopy . 2003,第1期

机译：溴仿的193 nm激光光解产生的HCBr旋转光谱
4. Degradation kinetics of the pharmaceutical metronidazole via UV photolysis andadvanced oxidation processes [C] . Hilla Shemer, Yasemin Ka?ar Kunukcu, Karl G. Linden Water quality technology conference and exposition (2005 WQTC conference proceedings) . 2005

机译：紫外光分解和高级氧化过程降解甲硝唑的动力学
5. Time-resolved IR diode laser spectroscopy: Kinetics and product distribution determination of transient photoproducts formed by UV excimer laser photolysis of irony pentacarbonyl. [D] . Ryther, Robert James. 1991

机译：时间分辨红外二极管激光光谱法：测定五羰基铁的紫外准分子激光光解形成的瞬态光产物的动力学和产物分布。
6. Flash Photolysis of Cutinase: Identification and Decay Kinetics of Transient Intermediates Formed upon UV Excitation of Aromatic Residues [O] . Maria Teresa Neves-Petersen, Søren Klitgaard, Torbjorn Pascher, 2009

机译：角质酶的快速光解：鉴定紫外残留物后形成的瞬态中间体的衰变动力学
7. Flash Photolysis of Cutinase: Identification and Decay Kinetics of Transient Intermediates Formed upon UV Excitation of Aromatic Residues [O] . Neves-Petersen, Maria Teresa, Klitgaard, Søren, Pascher, Torbjorn, 2009

机译：角质酶的快速光解：鉴定紫外残留物后形成的瞬态中间体的衰变动力学
8. Coaxial Measurement of the Translational Distribution of CS Produced in the Laser Photolysis of CS2 at 193nm [R] . Lu, R., McCrary, V., Zakheim, D., 1983

机译：同位素测量Cs2激光光解产生的Cs在193nm处的平移分布

UV SPECTRUM AND DECAY KINETICS OF TRANSIENT METHYLSILENE PRODUCED IN THE 193 NM PHOTOLYSIS OF GASEOUS 1-METHYL-1-SILACYCLOBUTANE

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