Electron transfer reactions in micellar systems: separation of the true (unimolecular) electron transfer rate constant in its components

R. Prado-Gotor; R. Jimenez; P. Perez-Tejeda; M. Lopez-Lopez; F. Sanchez

首页> 外文期刊>Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature >Electron transfer reactions in micellar systems: separation of the true (unimolecular) electron transfer rate constant in its components

【24h】

Electron transfer reactions in micellar systems: separation of the true (unimolecular) electron transfer rate constant in its components

机译：胶束系统中的电子转移反应：组分中真实（单分子）电子转移速率常数的分离

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The intramolecular electron transfer reaction within the binuclear complex [(en)_2Co~(III)(μ-2-pzCO_2)Fe~(II)(CN)_5]~- has been studied in micellar (dodecylsulphate sodium slat (SDS) and hexadecyltrimethylammonium chloride (CTACl)) solutions. The true (unimolecular) electron transfer rate constant as well as the parameters controlling this rate constant, the reorganization free energy and the reaction free energy were obtained. This has permitted us to establish that, in spite of the similar behaviour observed for k_(et) in both kinds of micellar solutions, in the case of SDS solutions the kinetics is controlled by both the driving force and the reorganization energy. In the case of CTACl, only the reorganization energy controls the k_(et) variations.

机译：在胶束（十二烷基硫酸钠钠板条（SDS））中研究了双核络合物[（en）_2Co〜（III）（μ-2-pzCO_2）Fe〜（II）（CN）_5]〜-中的分子内电子转移反应。十六烷基三甲基氯化铵（CTACl））溶液。获得了真实的（单分子）电子转移速率常数以及控制该速率常数的参数，重组自由能和反应自由能。这使我们可以确定，尽管在两种胶束溶液中都观察到了k_（et）的相似行为，但在SDS溶液中，动力学受驱动力和重组能的控制。在CTCCl的情况下，只有重组能量才能控制k_（et）的变化。

著录项

来源
《Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature》 |2001年第1期|共10页
作者
R. Prado-Gotor; R. Jimenez; P. Perez-Tejeda; M. Lopez-Lopez; F. Sanchez;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词

相似文献

外文文献
中文文献
专利

1. Electron transfer reactions in micellar systems: separation of the true (unimolecular) electron transfer rate constant in its components [J] . R. Prado-Gotor, R. Jimenez, P. Perez-Tejeda, Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature . 2001,第1期

机译：胶束系统中的电子转移反应：组分中真实（单分子）电子转移速率常数的分离
2. Estimation of electron transfer rate constant from static (optical and thermodynamic) measurements: A study of Ru(NH3)(5)pz(2+)+Fe(CN)(6)(3-)reversible arrow Ru(NH3)(5)pz(3+)+Fe(CN)(6)(4-) electron transfer reactions [J] . Sanchez F., Lopez-Lopez M., Perez-Tejeda P. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第8期

机译：从静态（光学和热力学）测量值估算电子传输速率常数：Ru（NH3）（5）pz（2 +）+ Fe（CN）（6）（3-）可逆箭头Ru（NH3）（5）的研究）pz（3 +）+ Fe（CN）（6）（4-）电子转移反应
3. Effect of laser intensity on the determination of intermolecular electron transfer rate constants - Observation of Marcus inverted region in photoinduced back electron transfer reactions [J] . Weng YX., Tzeng BC., Che CM., The Journal of Chemical Physics . 1998,第14期

机译：激光强度对分子间电子传递速率常数测定的影响-光诱导的反向电子传递反应中Marcus反向区的观察
4. Photoinduced Electron Transfer Reactions,Magnetic Field Effects on the Decay Process of Charge-Separated State,and Time-Resolved EPR Spectra in Fullerene-Donor Systems [C] . Hiroaki Yonemura, Shinya Moribe, Norihiro Kuroda, The Meeting of the Electrochemical Society . 2003

机译：光抑制电子转移反应，对富勒烯 - 供体系统中的电荷分离状态衰减过程的磁场效应，以及富勒烯 - 供体系统中的时间分辨的EPR光谱
5. STUDIES ON PHOTOCHEMICAL REACTIONS OF THREE-COMPONENT SYSTEMS INVOLVING ELECTRON TRANSFER [D] . Majima, Tetsuro 1980

机译：涉及电子转移的三组分体系的光化学反应研究
6. Quantitative electron-paramagnetic-resonance measurements of the electron-transfer components of the photosystem-I reaction centre. The reaction-centre chlorophyll (P700) the primary electron acceptor X and bound iron-sulphur centre A. [O] . P Heathcote, D L Williams-Smith, M C Evans 1978

机译：光系统-I反应中心电子转移组分的定量电子-顺磁共振测量。反应中心的叶绿素（P700）主要电子受体X和结合的铁硫中心A.
7. Effect of laser intensity on the determination of intermolecular electron transfer rate constants - Observation of Marcus inverted region in photoinduced back electron transfer reactions [O] . Che CM, Tzeng BC, Weng YX, 1998

机译：激光强度对分子间电子转移速率常数测定的影响 - 光诱导反向电子转移反应中marcus反转区的观察
8. Electron Transfer Quenching of the Luminescent Excited State of Tris(2,2'-Bipyridine)Ruthenium (II). A Flash Photolysis Relaxation Technique for Measuring the Rates of Very Rapid Electron Transfer Reactions. [R] . Bock, C. R., Meyer, T. J., Whitten, D. G. 1974

机译：三（2,2'-联吡啶）钌（II）发光激发态的电子转移猝灭。闪光光解弛豫技术测量快速电子转移反应速率。

Electron transfer reactions in micellar systems: separation of the true (unimolecular) electron transfer rate constant in its components

摘要

著录项

相似文献

相关主题

期刊订阅