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2D self-assembly of 1,3,2-dioxaborine derivatives on HOPG

机译:HOPG上1,3,2-二氧杂硼啉衍生物的2D自组装

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摘要

Two-dimensional (2D) self-assembly of two 1,3,2-dioxaborine derivatives was investigated by STM. The molecules consist of IT system and steric end groups. A droplet of toluene solution containing the molecules was deposited onto HOPG for preparing theassemblies. STM images showed that the molecular structures affect the assembly structure. The dipole-dipole interaction and steric repulsion played important roles in the formation of the self-assembled monolayers.
机译:通过STM研究了两个1,3,2-二氧杂硼啉衍生物的二维(2D)自组装。这些分子由IT系统和空间端基组成。将含有分子的甲苯溶液液滴沉积到HOPG上以制备组件。 STM图像表明分子结构影响组装结构。偶极-偶极相互作用和空间排斥在自组装单分子层的形成中起重要作用。

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