SR3GDRHO6 - THE FIRST RH-III COMPOUND WITH THE K4CDCL6 STRUCTURE-TYPE - SYNTHESIS, CRYSTAL STRUCTURE, AND MAGNETIC PROPERTIES

Nunez P.; Zurloye HC.; Rzeznik MA.

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SR3GDRHO6 - THE FIRST RH-III COMPOUND WITH THE K4CDCL6 STRUCTURE-TYPE - SYNTHESIS, CRYSTAL STRUCTURE, AND MAGNETIC PROPERTIES

机译：SR3GDRHO6-具有K4CDCL6结构类型的第一种RH-III化合物-合成，晶体结构和磁性

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The compound Sr3GdRhO6 has been synthesized and structurally characterized by Rietveld refinement of powder X-ray diffraction data. (space group R (3) over bar c; Z = 6; a = 9.7840(5) Angstrom; c = 11.4196(7) Angstrom) This compound is isostructural with K4CdCl6. The structure consists of infinite one-dimensional chains of alternating face-shared RhO6 octahedra and GdO6 trigonal prisms. The strontium cations are located in a distorted square antiprismatic environment. Magnetic susceptibility data show that Sr3GdRhO6 obeys the Curie law with mu(eff) = 7.80 B.M., consistent with an oxidation state of + 3 for both rhodium and gadolinium. [References: 22]

机译：合成了化合物Sr3GdRhO6，并通过粉末X射线衍射数据的Rietveld精炼对其进行了结构表征。（R上的空间群R（3）在c上; Z = 6; a = 9.7840（5）埃; c = 11.4196（7）埃）该化合物与K4CdCl6同构。该结构由交替的面共享RhO6八面体和GdO6三角棱镜组成的无限一维链组成。锶阳离子位于扭曲的方形反棱镜环境中。磁化率数据表明，Sr3GdRhO6符合居里定律，mu（eff）= 7.80 B.M.，与铑和g的氧化态均为+3一致。 [参考：22]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第8期|共4页
作者
Nunez P.; Zurloye HC.; Rzeznik MA.;
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正文语种 eng
中图分类化学;
关键词
Sr3gdrho6; Rietveld refinement; Magnetic susceptibility;

机译：Sr3gdrho6;Rietveld细化;磁化率;

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1. SR3GDRHO6 - THE FIRST RH-III COMPOUND WITH THE K4CDCL6 STRUCTURE-TYPE - SYNTHESIS, CRYSTAL STRUCTURE, AND MAGNETIC PROPERTIES [J] . Nunez P., Zurloye HC., Rzeznik MA. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第8期

机译：SR3GDRHO6-具有K4CDCL6结构类型的第一种RH-III化合物-合成，晶体结构和磁性
2. Synthesis and characterization of new Rh(III) compounds with the K4CdCl6 structure-type: Sr3MRhO6 (M = Y, Sc, In) [J] . Layland RC., Nunez P., zur Loye HC., International Journal of Quantum Chemistry . 1998,第2期

机译：具有K4CdCl6结构类型的新Rh（III）化合物的合成和表征：Sr3MRhO6（M = Y，Sc，In）
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SR3GDRHO6 - THE FIRST RH-III COMPOUND WITH THE K4CDCL6 STRUCTURE-TYPE - SYNTHESIS, CRYSTAL STRUCTURE, AND MAGNETIC PROPERTIES

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