2D Ln~(III)(Nd/La)-Ag~I Heterometallic and Tm~(III) Homometallic Coordination Polymers Based on Pyridine Dicarboxylate Ligands

Ling-Zhi Zhao; Yuan-Yuan Tian; Ying-Xin Gong; Xiao-Ting Huang; Fen Zhang; Jian-Xiong Rong; Xia Cai; Wen-Tao Li; Rong-Hua Zeng; Dong-Sheng Lu

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2D Ln~(III)(Nd/La)-Ag~I Heterometallic and Tm~(III) Homometallic Coordination Polymers Based on Pyridine Dicarboxylate Ligands

机译：基于吡啶二羧酸配体的2D Ln〜（III）（Nd / La）-Ag〜I杂金属和Tm〜（III）同金属配位聚合物

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Two 2D 4d-4f heterometallic coordination polymers, [LnAg- (Py26DC)_2(H_2O)_3]·3H_2O [Ln = Nd (1), La (2); H_2Py26DC = pyridine- 2,6-dicarboxylic acid], and one 2D lanthanide homometallic coordination polymer, [Ln(Py25DC)(ox)_(0.5)(H_2O)_2] [Ln = Tm (3); H_2Py25DC = pyridine-2,5-dicarboxylic acid; ox = oxalate], were synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction analysis. Both complexes 1 and 2 are isostructural and exhibit 3-connected 2D heterometallic layer structures with the Schl?fli symbol of (8~2·10), whereas complex 3 represents an extended 2D homometallic network structure with (4,4) topology.

机译：两种2D 4d-4f杂金属配位聚合物[LnAg-（Py26DC）_2（H_2O）_3]·3H_2O [Ln = Nd（1），La（2）; H_2Py26DC =吡啶-2,6-二羧酸]和一种2D镧系元素同金属配位聚合物[Ln（Py25DC）（ox）_（0.5）（H_2O）_2] [Ln = Tm（3）; H_2Py25DC =吡啶-2,5-二羧酸;合成，并通过元素分析，红外光谱，热重分析和单晶X射线衍射分析进行表征。配合物1和2都是同构结构，并具有3个连接的2D杂金属层结构，其Schlfli符号为（8〜2·10），而配合物3表示具有（4,4）拓扑结构的扩展2D同金属网络结构。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第1期|共6页
作者
Ling-Zhi Zhao; Yuan-Yuan Tian; Ying-Xin Gong; Xiao-Ting Huang; Fen Zhang; Jian-Xiong Rong; Xia Cai; Wen-Tao Li; Rong-Hua Zeng; Dong-Sheng Lu;
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正文语种 eng
中图分类化学;
关键词
Hydrothermal synthesis; N; O ligands; Hydrogen bonds; Heterometallic coordination polymers;

机译：水热合成;N;O配体;氢键;多金属配位聚合物;

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1. 2D Ln~(III)(Nd/La)-Ag~I Heterometallic and Tm~(III) Homometallic Coordination Polymers Based on Pyridine Dicarboxylate Ligands [J] . Ling-Zhi Zhao, Yuan-Yuan Tian, Ying-Xin Gong, Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第1期

机译：基于吡啶二羧酸配体的2D Ln〜（III）（Nd / La）-Ag〜I杂金属和Tm〜（III）同金属配位聚合物
2. Syntheses, structures and properties of three new two-dimensional Cu I-LnIII heterometallic coordination polymers based on 2,2′-dipyridyl-5,5′-dicarboxylate ligands [J] . Zhao J., Cheng Y., Shang S., Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2013,第Null期

机译：基于2,2'-二吡啶基-5,5'-二羧酸酯配体的三种新型二维Cu I-LnIII杂金属配位聚合物的合成，结构和性能
3. 1-D Ln-Ag (Ln = Eu; Tb) heterometallic coordination polymers with pyridine-2,6-dicarboxylate as the single ligand: Synthesis, crystal structures, and luminescence [J] . DE-YUN MA, WEI-XIA WANG, YING-WEI LI Journal of Coordination Chemistry . 2010,第3期

机译：1-D Ln-Ag（Ln = Eu; Tb）杂金属配位聚合物，带有2,6-二羧酸吡啶作为单个配体：合成，晶体结构和发光
4. Synthesis and crystal structure of a new 2D coordination polymer Ce(3,4-pydc)_2·H_2O(3,4-pydc ＝ pyridine-3,4-dicarboxylate) [C] . Fenghua Bai, Liping Zhang, Haiquan Su, International Conference on Advanced Engineering Materials and Technology . 2011

机译：新的2D配位聚合物Ce（3,4-PYDC）_2·H_2O（3,4-PYDC =吡啶-3,4-二羧酸盐）的合成和晶体结构
5. Part A: Coordination of pyridine and pyridine-type ligands to cobalt(II)- and cobalt(III)-substituted Keggin and Dawson-type heteropolyanions. Part B: Encapsulation of various heteropolyanions in artificial phospholipid vesicles: Effects of size, charge, and polarity on encapsulation efficiency. [D] . Samonte, Joseph Laurito. 1996

机译：A部分：吡啶和吡啶型配体与钴（II）和钴（III）取代的Keggin和Dawson型杂多阴离子的配位。 B部分：在人工磷脂囊泡中包裹各种杂多阴离子：大小，电荷和极性对包裹效率的影响。
6. Tetracarbonatodiruthenium Fragments and Lanthanide(III) Ions as Building Blocks to Construct 2D Coordination Polymers [O] . Daniel Gutiérrez-Martín, Miguel Cortijo, Álvaro Martín-Humanes, 2019

机译：四碳二钌钌片段和镧系元素（III）离子作为构建2D配位聚合物的基础
7. Series of 2D heterometallic coordination polymers based on ruthenium(III) oxalate building units: synthesis, structure, and catalytic and magnetic properties [O] . Dikhtiarenko Alla, Khainakov Sergei, Pedro Imanol de, 2013

机译：基于草酸钌（III）的二维二维杂金属配位聚合物系列：合成，结构以及催化和磁性

2D Ln~(III)(Nd/La)-Ag~I Heterometallic and Tm~(III) Homometallic Coordination Polymers Based on Pyridine Dicarboxylate Ligands

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