BaAuP and BaAuAs, Synthesis via Disproportionation of Gold upon Interaction with Pnictides as Bases

Nuss J; Jansen M

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BaAuP and BaAuAs, Synthesis via Disproportionation of Gold upon Interaction with Pnictides as Bases

机译：BaAuP和BaAuAs，与肽类作为碱基相互作用时通过金的歧化来合成

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Gold disproportinates in the presence of the Zintl phases Ba3P2 or Ba3As2 forming BaAuP and BaAuAs, respectively, and BaAu2. The air and moisture sensitive ternary compounds crystallise in the ZrBeSi type of structure, an ordered variant of AlB2: BaAuP (P6(3)/mmc; a = 440.68(6) pm; c = 899.8(2) pm; R-1 = 0.0237; 183 independent reflections); BaAuAs (P6(3)/mmc; a = 453.53(5) pm; c = 902.7(1) pm; R-1 = 0.0255; 168 independent reflections). Both compounds, which are accessible as pure phases by reacting BaP or BaAs with gold, can be classified as poor metallic conductors.

机译：金在Zintl相Ba3P2或Ba3As2的存在下歧化，分别形成BaAuP和BaAuAs，以及BaAu2。空气和湿气敏感的三元化合物以ZrBeSi型结构结晶，即AlB2的有序变体：BaAuP（P6（3）/ mmc; a = 440.68（6）pm; c = 899.8（2）pm; R-1 = 0.0237; 183个独立反射）; BaAuAs（P6（3）/ mmc; a = 453.53（5）pm; c = 902.7（1）pm; R-1 = 0.0255; 168个独立反射）。可以通过使BaP或BaAs与金反应而作为纯相获得的两种化合物都可以归为不良金属导体。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第11期|共3页
作者
Nuss J; Jansen M;
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正文语种 eng
中图分类化学;
关键词
Gold; Ternary pnictides; Alkaline earth metals; Conducting materials; Crystal structures;

机译：金;三价锡;碱土金属;导电材料;晶体结构;

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BaAuP and BaAuAs, Synthesis via Disproportionation of Gold upon Interaction with Pnictides as Bases

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