Supramolecular architectures of four new transition metal complexes with 3-[4-(carboxymethoxy)phenyl]propanoic acid and N-[4-(carboxymethoxy)phenyl] iminodiacetic acid

Liu C.-B.; Wen H.-L.; Gong Y.-N.; Liu X.-M.; Tan S.-S.

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Supramolecular architectures of four new transition metal complexes with 3-[4-(carboxymethoxy)phenyl]propanoic acid and N-[4-(carboxymethoxy)phenyl] iminodiacetic acid

机译：具有3- [4-（羧基甲氧基）苯基]丙酸和N- [4-（羧基甲氧基）苯基]亚氨基二乙酸的四种新型过渡金属配合物的超分子结构

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Four new transition metal complexes: [Cu(Hcppa)_2(H_2O)_2] (1), [Co_2(cppa)_2(H_2O)_(10)] (2), [Co_3(cpia)_2(H_2O)_8]·_2H_2O (3) and [Ni_3(cpia)_2(H_2O)_(12)]·6H_2O (4) {H_2cppa = 3-(4-(carboxymethoxy)phenyl]propanoic acid; H3cpia = N-[4-(carboxymethoxy)phenyl]iminodiacetic acid} were synthesized and characterized. Complexes 1 and 2 show mononuclear structures, complexes 3 and 4 exhibit dinuclear structures. All complexes extend to 3D supramolecular networks through hydrogen bonds, of which complexes 3 and 4 display microporous structures. In complexes 2-4 the water clusters are trapped by the cooperative association of coordinate interactions as well as hydrogen bonds, forming different 1D metal-water chain structures. Thermal stabilities of complexes 1-4 were discussed.

机译：四种新的过渡金属配合物：[Cu（Hcppa）_2（H_2O）_2]（1），[Co_2（cppa）_2（H_2O）_（10）]（2），[Co_3（cpia）_2（H_2O）_8] ·_2H_2O（3）和[Ni_3（cpia）_2（H_2O）_（12）]·6H_2O（4）{H_2cppa = 3-（4-（羧基甲氧基）苯基]丙酸; H3cpia = N- [4-（羧基甲氧基）合成并表征了[苯基]亚氨基二乙酸}，配合物1和2具有单核结构，配合物3和4具有双核结构，所有配合物均通过氢键延伸至3D超分子网络，其中配合物3和4具有微孔结构。 2-4中的水团簇通过配位相互作用和氢键的协同结合被捕获，形成了不同的一维金属-水链结构，讨论了配合物1-4的热稳定性。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2011年第1期|共8页
作者
Liu C.-B.; Wen H.-L.; Gong Y.-N.; Liu X.-M.; Tan S.-S.;
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正文语种 eng
中图分类化学;
关键词
3-4-(carboxymethoxy)phenylpropanoic acid; Cobalt; Copper; N-4-(carboxymethoxy)phenyl iminodiacetic acid; Nickel; Supramolecular chemistry;

机译：3- [4-（羧基甲氧基）苯基]丙酸;钴;铜;N- [4-（羧基甲氧基）苯基]亚氨基二乙酸;镍;超分子化学;

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1. Supramolecular architectures of four new transition metal complexes with 3-[4-(carboxymethoxy)phenyl]propanoic acid and N-[4-(carboxymethoxy)phenyl] iminodiacetic acid [J] . Liu C.-B., Wen H.-L., Gong Y.-N., Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第1期

机译：具有3- [4-（羧基甲氧基）苯基]丙酸和N- [4-（羧基甲氧基）苯基]亚氨基二乙酸的四种新型过渡金属配合物的超分子结构
2. Three New Metal–Organic Polymers Based on Flexible 3-(4-(Carboxymethoxy) Phenyl) Propanoic Acid: Crystal Structures, Luminescent and Magnetic Properties [J] . Jun Ji, You Zhang, Jun-Dan Fu, Journal of Inorganic and Organometallic Polymers and Materials . 2013,第6期

机译：三种新的基于柔性3-（4-（羧基甲氧基）苯基）丙酸的金属有机聚合物：晶体结构，发光和磁性
3. Self-Assembly of Four Helical Metal-Organic Frameworks Based on 3-[4-(Carboxymethoxy) phenyl]propanoic Acid Ligands: Syntheses, Crystal Structures, and Properties [J] . Jun Ji, You Zhang, Yuan-Fa Yang, European journal of inorganic chemistry . 2013,第24期

机译：基于3- [4-（羧基甲氧基）苯基]丙酸配体的四个螺旋金属有机骨架的自组装：合成，晶体结构和性质
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5. Late Transition Metal Complexes Containing Tridentate Pincer-Type 1, 3-bis(o-(diphenylphosphino)phenyl)-N,N'-Heterocyclic Phosphenium/Carbene Ligands [D] . Pan, Baofei 2012

机译：含三齿钳型1，3-双（邻-（二苯基膦基）苯基）-N，N'-杂环磷/碳配体的晚过渡金属配合物
6. N-{4-[4-(4-Fluorophenyl)-1-(2-methoxyethyl)-2-methylsulfanyl-1H-imidazol-5-yl]-2-pyridyl}-2-methyl-3-phenylpropionamide [O] . Katharina Ziegler, Dieter Schollmeyer, Stefan Laufer 2016

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7. 3-[4-(Trifluoromethyl)phenyl]propanoic acid [O] . Jian-Ning Guan, Xiang-Jun Kong, Bin Xu, 2009

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机译：OECD 422联合重复剂量毒性研究结果与大鼠（2 - （（2-氰基-3-（4-（二乙基氨基）苯基）-1-氧代烯丙基）氧基）乙基）的生殖/发育毒性筛选试验结果（ 3-（（2-氰基-3-（4-（二乙基氨基）苯基）-1-氧代烯丙基）氧基）p

Supramolecular architectures of four new transition metal complexes with 3-[4-(carboxymethoxy)phenyl]propanoic acid and N-[4-(carboxymethoxy)phenyl] iminodiacetic acid

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