The trivalent manganese hydrogenophosphate LiMn(H_2P _2O_7)_2: A chain- like structure

Baies R.; Pralong V.; Caignaert V.; Raveau B.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >The trivalent manganese hydrogenophosphate LiMn(H_2P _2O_7)_2: A chain- like structure

【24h】

The trivalent manganese hydrogenophosphate LiMn(H_2P _2O_7)_2: A chain- like structure

机译：三价磷酸氢锰锰LiMn（H_2P _2O_7）_2：链状结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new Mn3+ hydrogenophosphate LiMn(H_2P _2O_7)_2 was synthesized, using a soft chemistry method. The ab initio structure resolution of this phase shows that it consists of infinite chains [MnH_4P_4O_(14)]~∞, built up of corner-sharing MnO6 octahedra and P2O_5(OH)_2 diphosphate groups. The cohesion between the chains is ensured by Li+ cations and hydrogen bonds. This compound is paramagnetic and Mn~(3+) is in high spin (H.S.) configuration. The impedance plots show that this hydrogenophosphate is a modest ionic conductor with activation energy of 0.8 eV and a conductivity reaching 10~(-6) S·cm~(-1) at 320 °C.

机译：采用软化学方法合成了一种新的Mn3 +磷酸氢锂LiMn（H_2P_2O_7）_2。该相的从头算结构解析表明，它由无限链[MnH_4P_4O_（14）]〜∞组成，由角共享MnO6八面体和P2O_5（OH）_2二磷酸基团组成。链之间的内聚力通过Li +阳离子和氢键确保。该化合物是顺磁性的，Mn〜（3+）是高自旋（H.S.）构型。阻抗图表明，该磷酸氢根是中等离子导体，活化能为0.8 eV，在320°C时电导率达到10〜（-6）S·cm〜（-1）。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第13期|共5页
作者
Baies R.; Pralong V.; Caignaert V.; Raveau B.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Ionic conductivity; Manganese; Manganese phosphate; Phosphorus;

机译：离子电导率锰磷酸锰磷;

相似文献

外文文献
中文文献
专利

1. The trivalent manganese hydrogenophosphate LiMn(H_2P _2O_7)_2: A chain- like structure [J] . Baies R., Pralong V., Caignaert V., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第12a13期

机译：三价磷酸氢锰锰LiMn（H_2P _2O_7）_2：链状结构
2. Synthsis and structures of lithium manganese oxide spinel, LiMn_2O_4-δ (O≤δ≤0.27) [J] . Ryoji Kanno, Masao Yonemura, Tomoko Kohigashi Journal of power sources . 2001,第期

机译：锂锰氧化物尖晶石LiMn2O4≤δ≤0.27的合成与结构
3. A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature [J] . Zhao Hai-Rong, Xue Chen, Li Cui-Ping, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第17期

机译：氢磷酸锰（II）的二维无机-有机杂化固体在室温下具有高质子传导性
4. Elaboration of Structured LiMn2O4for Rechargeable Batteries from Hydrometallurgical Liquid Effluent Rich in Manganese [C] . Khalid Ouzaouit, Hakim Faqir, Abderrahman Kaddami, International Renewable and Sustainable Energy Conference . 2017

机译：富含锰的湿法冶金废液可充电电池的结构化LiMn 2 O 4 的制备
5. Comparison of the reactivity of various manganese oxides with trivalent aqueous chromium: Microscopic and spectroscopic observations of dissolution, chromium sorption and chromium and manganese redox interactions. [D] . Weaver, Robert Michael. 2001

机译：各种锰氧化物与三价铬水溶液反应性的比较：溶解，铬吸附以及铬和锰氧化还原相互作用的显微和光谱观察。
6. Comparison of the crystal structures of genetically engineered human manganese superoxide dismutase and manganese superoxide dismutase from Thermus thermophilus: differences in dimer-dimer interaction. [O] . U. G. Wagner, K. A. Pattridge, M. L. Ludwig, 1993

机译：转基因人类锰超氧化物歧化酶和嗜热栖热菌锰超氧化物歧化酶的晶体结构比较：二聚体-二聚体相互作用的差异。
7. Inhibition of Redox Behaviors in Hierarchically Structured Manganese Cobalt Phosphate Supercapacitor Performance by Surface Trivalent Cations [O] . Deviprasath Chinnadurai, Aravindha Raja Selvaraj, Rajmohan Rajendiran, 2018

机译：表面三价阳离子抑制分层结构锰钴磷酸盐超级电容器性能中的氧化还原行为
8. Complexes of Trivalent Phosphorus Derivatives Viii. Tris (Dimethylamino) Phosphine Complexes of Manganese Carbonyl. [R] . King, R. B., Korenowski, T. F. 1968

机译：三价磷衍生物的配合物Viii。羰基锰的三（二甲氨基）膦配合物。

The trivalent manganese hydrogenophosphate LiMn(H_2P _2O_7)_2: A chain- like structure

摘要

著录项

相似文献

相关主题

期刊订阅