Introduction of (2-CF3)Phenyl Group via Nickel-catalyzed C-Cl Bond Activation and Arylation

Peng Zheng; Sun Hongjian; Du Aiqin; Li Xiaoyan

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Introduction of (2-CF3)Phenyl Group via Nickel-catalyzed C-Cl Bond Activation and Arylation

机译：通过镍催化的C-Cl键活化和芳基化引入（2-CF3）苯基

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A simple and mild catalytic arylation via C-CI bond activation is described. The phenyl group containing a 2-trifluoromethyl group was intmduced into the aromatic imine molecules through CC-coupling reaction between chloroarenes and the organozinc reagent. bis(2-(trifluoromethyl)phenyPzinc, with tetrakis(ttimethylphosphine)nickel(0) complex as an effective catalyst. Under catalytic conditions chlorinated henzalimines were quantitatively converted into the expected benzalimines with trilluoromethyl group(s)

机译：描述了通过C-CI键活化的简单且温和的催化芳基化。通过氯代芳烃与有机锌试剂之间的CC偶联反应，将含有2-三氟甲基的苯基引入芳族亚胺分子中。双（2-（三氟甲基）苯并Pzinc，以四（叔甲基膦）镍（0）络合物为有效催化剂在催化条件下，氯化的邻苯二甲胺被定量转化为预期的具有三氟甲基的苯丙胺

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2015年第5期|共4页
作者
Peng Zheng; Sun Hongjian; Du Aiqin; Li Xiaoyan;
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正文语种 eng
中图分类化学;
关键词
C-Cl activation; Nickel; Trifluoromethyl; Organozinc reagent; C; C-coupling; Chlorinated henzalirnine;

机译：C-Cl活化;镍;三氟甲基;有机锌试剂;C;C偶联;氯代苯丙氨酸;

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1. Introduction of (2-CF3)Phenyl Group via Nickel-catalyzed C-Cl Bond Activation and Arylation [J] . Peng Zheng, Sun Hongjian, Du Aiqin, Zeitschrift fur Anorganische und Allgemeine Chemie . 2015,第5期

机译：通过镍催化的C-Cl键活化和芳基化引入（2-CF3）苯基
2. Nickel-catalyzed intramolecular nucleophilic addition of aryl or vinyl chlorides to α-ketoamides through C-Cl bond activation [J] . Hu J.-X., Wu H., Li C.-Y., Chemistry: A European journal . 2011,第19期

机译：镍催化的分子内亲核亲核加入芳基或氯乙烯至α-酮酰胺通过C-Cl键活化
3. Nickel-Catalyzed α-Arylation of Zinc Enolates with Polyfluoroarenes via C?F Bond Activation under Neutral Conditions [J] . Daohong Yu, Chang-Sheng Wang, Cheng Yao, Organic letters . 2014,第21期

机译：在中性条件下通过C？F键活化镍催化的锌烯醇盐与多氟芳烃的α-芳基化
4. Highly Regioselective Arylation of Perylene Bisimides via C-H Bond Activation [C] . Satomi Nakazono, Hiroshi Shinokuho, Atsuhiro Osuka Symposium on Organometallic Chemistry . 2008

机译：通过C-H键活化的高度区域选择性苯并二酰胺芳基
5. Pincer complexes of diamido-pyridine based ligand as catalysts for C-Cl and C-H bond activation for cross-coupling reactions. [D] . Gartia, Yashraj. 2013

机译：基于二酰胺基-吡啶基配体的钳形配合物，可作为C-Cl和C-H键活化的催化剂进行交叉偶联反应。
6. Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations [O] . Susan L. Zultanski, Gregory C. Fu -1

机译：镍催化的碳 - 碳键形成未激活叔卤代烷的反应：铃木芳基化
7. Activation of H-H, C-H, C-C, and C-Cl bonds by Pd(0). Insight from the activation strain model [O] . Diefenbach, A., Bickelhaupt, F.M. 2004

机译：通过Pd（0）激活H-H，C-H，C-C和C-Cl键。活化应变模型的见解

Introduction of (2-CF3)Phenyl Group via Nickel-catalyzed C-Cl Bond Activation and Arylation

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