Synthesis and structural characterization of the helical coordination polymers [Co(phen)(oba)(H2O)2] and [Cd-3(phen)(3)(oba)(2)(Hoba)(2)(H2O)(2)] (phen=1,10-phenanthroline; oba=4,4 '-oxybis(benzoate)

Zheng YZ; Liu GF; Ye BH; Chen XM

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Synthesis and structural characterization of the helical coordination polymers [Co(phen)(oba)(H2O)2] and [Cd-3(phen)(3)(oba)(2)(Hoba)(2)(H2O)(2)] (phen=1,10-phenanthroline; oba=4,4 '-oxybis(benzoate)

机译：螺旋配位聚合物[Co（phen）（oba）（H2O）2]和[Cd-3（phen）（3）（oba）（2）（Hoba）（2）（H2O）（2）的合成和结构表征）]（phen = 1,10-phenothroline; oba = 4,4'-oxybis（benzoate）

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Two coordination polymers, [Co(phen)(oba)(H2O)(2)] (1) and [Cd-3(phen)(3)(oba)(2)(Hoba)(2)(H2O)(2)] (2) (oba = 4,4'-oxybis(benzoate), phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions. Complex 1 crystallizes in monoclinic, P2(1), a = 7.543(6), b = 33.05(2), c = 9.902(5)Angstrom, beta = 103.69(2)degrees, V = 2398(3) Angstrom(3), Z = 4; 2 in monoclinic, P2, a = 15.11(1), b = 10.069(8), c = 28.02(2)Angstrom, beta = 101.83(1)degrees, V = 4174(5) Angstrom(3), Z = 2. X-ray single-crystal diffraction investigations shows that the complexes 1 and 2 consist of helical chains, which are further assembled into layers and networks via supramolecular interactions such as pi-pi stacking interactions and hydrogen bonds, respectively. The results indicate that the coordination environment is one of the most important factors for assembly of single-stranded helical chains into double-stranded helical chains via supramolecular interactions.

机译：两种配位聚合物[Co（phen）（oba）（H2O）（2）]（1）和[Cd-3（phen）（3）（oba）（2）（Hoba）（2）（H2O）（2））]（2）（oba = 4,4'-氧双（苯甲酸酯），phen = 1,10-菲咯啉）是在水热条件下合成的。配合物1结晶为单斜晶，P2（1）/ n，a = 7.543（6），b = 33.05（2），c = 9.902（5）埃，beta = 103.69（2）度，V = 2398（3）埃（3），Z = 4; 2单斜度，P2 / n，a = 15.11（1），b = 10.069（8），c = 28.02（2）埃，beta = 101.83（1）度，V = 4174（5）埃（3），Z =2。X射线单晶衍射研究表明，络合物1和2由螺旋链组成，它们分别通过超分子相互作用（例如pi-pi堆积相互作用和氢键）进一步组装成层和网络。结果表明，配位环境是通过超分子相互作用将单链螺旋链组装成双链螺旋链的最重要因素之一。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2004年第2期|共5页
作者
Zheng YZ; Liu GF; Ye BH; Chen XM;
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正文语种 eng
中图分类化学;
关键词
coordination polymers; helicity; 4; 4 '-oxybis(benzoate); supramolecular interaction; PI-PI STACKING; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESES; COMPLEXES; ISOPHTHALATE; FRAMEWORKS; CHEMISTRY; MOLECULES; NETWORKS; LIGANDS;

机译：配位聚合物;螺旋度;4;4'-氧双（苯甲酸酯）;超分子相互作用;PI-PI堆积;晶体结构;水热合成;络合物;异邻苯二甲酸酯;骨架;化学;分子;网络;配体;

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1. Synthesis and structural characterization of the helical coordination polymers [Co(phen)(oba)(H2O)2] and [Cd-3(phen)(3)(oba)(2)(Hoba)(2)(H2O)(2)] (phen=1,10-phenanthroline; oba=4,4 '-oxybis(benzoate) [J] . Zheng YZ, Liu GF, Ye BH, Zeitschrift fur Anorganische und Allgemeine Chemie . 2004,第2期

机译：螺旋配位聚合物[Co（phen）（oba）（H2O）2]和[Cd-3（phen）（3）（oba）（2）（Hoba）（2）（H2O）（2）的合成和结构表征）]（phen = 1,10-phenothroline; oba = 4,4'-oxybis（benzoate）
2. Synthesis, crystal structure and catalytic activity for H2O2 disproportionation of the manganese(II) coordination polymer {[Mn(O2C(CF2)(8)CO2)(phen)(2)]H2O}(n) (phen=1,10-phenanthroline) [J] . Kani I, Darak C, Sahin O, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2008,第4期

机译：锰（II）配位聚合物{[Mn（O2C（CF2）（8）CO2）（phen）（2）] H2O}（n）（phen = 1,10-菲咯啉
3. Solid-state coordination chemistry: Structural influences of copper-phenanthroline subunits on oxovanadium organophosphonate phases. Hydrothermal synthesis and structural characterization of the two-dimensional materials [Cu(phen) (VO)(O3PCH2PO3)(H2O [J] . Finn RC., Greedan JE., Zubieta J., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第15期

机译：固态配位化学：铜-菲咯啉亚基对氧代钒有机膦酸酯相的结构影响。二维材料[Cu（phen）（VO）（O3PCH2PO3）（H2O）的水热合成及结构表征
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）

Synthesis and structural characterization of the helical coordination polymers [Co(phen)(oba)(H2O)2] and [Cd-3(phen)(3)(oba)(2)(Hoba)(2)(H2O)(2)] (phen=1,10-phenanthroline; oba=4,4 '-oxybis(benzoate)

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