CRYSTAL STRUCTURE OF MIXED CRYSTALS OF THE TETRA(N-BUTYL)AMMONIUM SALTS OF CIS-TETRAFLUOROPHTHALOCYANINATO(2)TANTALATE(V) AND CIS-TRIFLUOROPHTHALOCYANINATO(2-)TANTALATE(IV)

Schweiger K.; Homborg H.; Huckstadt H.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >CRYSTAL STRUCTURE OF MIXED CRYSTALS OF THE TETRA(N-BUTYL)AMMONIUM SALTS OF CIS-TETRAFLUOROPHTHALOCYANINATO(2)TANTALATE(V) AND CIS-TRIFLUOROPHTHALOCYANINATO(2-)TANTALATE(IV)

【24h】

CRYSTAL STRUCTURE OF MIXED CRYSTALS OF THE TETRA(N-BUTYL)AMMONIUM SALTS OF CIS-TETRAFLUOROPHTHALOCYANINATO(2)TANTALATE(V) AND CIS-TRIFLUOROPHTHALOCYANINATO(2-)TANTALATE(IV)

机译：CIS-四氟邻苯二甲醛（V）和CIS-三氟邻苯二甲醛（2-）（IV）四（N-丁基）铵盐的混合晶体的晶体结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

cis-Trichlorophthalocyaninato(2-)tantalate(V) reacts with excess tetra(n-butyl)ammonium fluoride trihydrate yielding mixed crystals of the tetra(n-butyl)ammonium salts of cis-tetrafluorophthalocyaninato(2-)tantalate(V) and cis-trifluorophthalocyaninato(2-)tantalate(IV) in the ratio five to four. These crystallize in the monoclinic space group P2(1) with cell parameters: a = 13.368(2)Angstrom, b=13.787(2)Angstrom, c = 23.069(3)Angstrom, beta = 93.35(1)degrees, Z = 4. Ta-V is octacoordinated with four F atoms and four N-iso atoms in an antiprismatic cis-arrangement. The Ta-V-F distance varies from 1.919(7) to 1.966(4)Angstrom. Ta-IV is heptacoordinated with three F atoms in a cis-arrangement. The Ta-IV-F distance varies from 1.74(1) to 1.966(4)Angstrom. The Ta atom is located out of the centre of the N-4 plane towards the F atoms by 1.234(3)Angstrom. The Ta-N distances range from 2.261(6) to 2.310(6)Angstrom. [References: 12]

机译：顺式三氯酞菁氨基（V）与过量的四（正丁基）氟化铵三水合物反应，生成顺式四氟酞菁氨基乙酸（V）和顺式的四（正丁基）铵盐的混合晶体-三氟邻苯二甲酸氰基（2-）钽酸酯（IV）的比例为五比四。这些结晶在单斜空间群P2（1）/ n中具有单元格参数：a = 13.368（2）埃，b = 13.787（2）埃，c = 23.069（3）埃，beta = 93.35（1）度，Z =4。Ta-V在反棱镜的顺式排列中由四个F原子和四个N-iso原子八配位。 Ta-V-F距离从1.919（7）到1.966（4）埃不等。 Ta-IV以三个顺式排列的F原子七配位。 Ta-IV-F距离从1.74（1）到1.966（4）埃不等。 Ta原子位于N-4平面的中心，朝F原子的距离为1.234（3）埃。 Ta-N距离范围为2.261（6）至2.310（6）埃。 [参考：12]

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第12期|共2页
作者
Schweiger K.; Homborg H.; Huckstadt H.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Phthalocyaninates; Tantalum compounds; Crystal structure; Permethyltantalocene; Derivatives; Oxo;

机译：酞菁;钽化合物;晶体结构;全甲基钽茂;衍生物;氧;

相似文献

外文文献
中文文献
专利

1. CRYSTAL STRUCTURE OF MIXED CRYSTALS OF THE TETRA(N-BUTYL)AMMONIUM SALTS OF CIS-TETRAFLUOROPHTHALOCYANINATO(2)TANTALATE(V) AND CIS-TRIFLUOROPHTHALOCYANINATO(2-)TANTALATE(IV) [J] . Schweiger K., Homborg H., Huckstadt H. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第12期

机译：CIS-四氟邻苯二甲醛（V）和CIS-三氟邻苯二甲醛（2-）（IV）四（N-丁基）铵盐的混合晶体的晶体结构
2. Synthesis and properties of bis(tetra(n-butyl)ammonium)mu-carbido-di(halophthalocyaninato(2-)ferrates( IV)); Crystal structure of bis(tetra(n-butyl)ammonium)mu-carbido-di(fluorophthalocyaninato(2-)ferrate (IV)) trihydrate [German] [J] . Kienast A., Homborg H. Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第1期

机译：双（四（正丁基）铵）mu-carbido-di（卤代酞菁亚氨基（2-）高铁酸盐（IV））的合成及性能双（四（正丁基）铵）mu-carbido-di（fluorophthalocyaninatoto（2-）ferrate（IV））trihydrate的晶体结构[德国]
3. TETRA(N-BUTYL)AMMONIUM PHTHALOCYANINATO(2-)LITHATE TETRAHYDROFURANE AND BIS(TETRA(N-BUTYL)AMMONIUM) PHTHALOCYANINATO(2-)LITHATE FLUORIDE HYDRATE - SYNTHESIS AND CRYSTAL STRUCTURE [German] [J] . Latte B., Homborg H., Assmann B. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第8期

机译：四（N-丁基）邻苯二甲酰基邻氨基苯甲酸四氢呋喃和双（四（N-丁基）铵）邻苯二甲酰基氟酸盐水合物-合成和晶体结构[德国]
4. Lithium niobate-tantalate mixed crystals electronic and optical properties calculated from first principles [C] . Riefer A., Sanna S., Schmidt W. G. Proceedings of 2012 21st IEEE ISAF held jointly with 11th IEEE ECAPD and IEEE PFM (ISAF/ECAPD/PFM 2012) . 2012

机译：铌酸锂-钽酸混合晶体的电子和光学性质从第一原理计算得出
5. Crystal growth and structure-property relationships for ferroelectric strontium bismuth tantalate. [D] . Lu, Xinliang. 2000

机译：钽铁酸锶铋铁的晶体生长和结构-性质关系。
6. Manganese-doping enhanced local heterogeneity and piezoelectric properties in potassium tantalate niobate single crystals [O] . Yu Wang, Peng Tan, Xiangda Meng, 2021

机译：锰掺杂增强钾铌酸盐单晶钾的局部异质性和压电性能
7. Syntheses and Crystal Structures of Phenyltrimethylammonium Salts of a Mixed Hexabromoselenate/tellurate(IV), C6H5(CH3)3N2Se0.75Te0.25Br6, and a Mixed catena-poly(Di-mu-bromobis{tetrabromoselenate/tellurate(IV)})-mu-bromine, C6H5(CH3)3N2nSe1.5Te 0.5Br10.Br2n. [O] . Vitalijus Janickis, Juhani Huuskonen, Risto S. Laitinen, 1999

机译：混合六溴酸酯/碲酸盐/碲（IV），C6H5（CH3）3N 2 SE0.75TE0.25BR6的合成和晶体结构，和混合的Catena-poly （Di-Mu-Bromobis {四溴酸酯/碲化物（IV）}） - Mu-溴，C6H5（CH3）3N 2N SE1.5TE 0.5BR10.BR2 n。

CRYSTAL STRUCTURE OF MIXED CRYSTALS OF THE TETRA(N-BUTYL)AMMONIUM SALTS OF CIS-TETRAFLUOROPHTHALOCYANINATO(2)TANTALATE(V) AND CIS-TRIFLUOROPHTHALOCYANINATO(2-)TANTALATE(IV)

摘要

著录项

相似文献

相关主题

期刊订阅