TETRA(N-BUTYL)AMMONIUM PHTHALOCYANINATO(2-)LITHATE TETRAHYDROFURANE AND BIS(TETRA(N-BUTYL)AMMONIUM) PHTHALOCYANINATO(2-)LITHATE FLUORIDE HYDRATE - SYNTHESIS AND CRYSTAL STRUCTURE [German]

Latte B.; Homborg H.; Assmann B.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >TETRA(N-BUTYL)AMMONIUM PHTHALOCYANINATO(2-)LITHATE TETRAHYDROFURANE AND BIS(TETRA(N-BUTYL)AMMONIUM) PHTHALOCYANINATO(2-)LITHATE FLUORIDE HYDRATE - SYNTHESIS AND CRYSTAL STRUCTURE [German]

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TETRA(N-BUTYL)AMMONIUM PHTHALOCYANINATO(2-)LITHATE TETRAHYDROFURANE AND BIS(TETRA(N-BUTYL)AMMONIUM) PHTHALOCYANINATO(2-)LITHATE FLUORIDE HYDRATE - SYNTHESIS AND CRYSTAL STRUCTURE [German]

机译：四（N-丁基）邻苯二甲酰基邻氨基苯甲酸四氢呋喃和双（四（N-丁基）铵）邻苯二甲酰基氟酸盐水合物-合成和晶体结构[德国]

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Dilithiumphthalocyaninate(2-) reacts with excess tetra(n-butyl)ammonium fluoride trihydrate to yield a mixture of blue tetra(n-butyl)ammonium phthalocyaninato(2-)lithate tetrahydrofurane and bis(tetra(n-butyl)ammonium) phthalocyaninato(2-)lithate fluoride hydrate. The latter crystallizes triclinic with crystal data: a = 8.6480(1) Angstrom; b = 12.620(2) Angstrom; c = 14.866(5) Angstrom; alpha = 82.44(2)degrees; beta = 87.01(2)degrees; gamma = 75.02 degrees; space group P (1) over bar; Z = 1. Fluoride is not coordinated to lithium. On the contrary, a double-salt is formed, which consists of alternating layers of cations and anions. This arrangement opens a cavity in the centre of the unit cell which shares statistically a fluoride and a disordered fluoride hydrate. Pure tetra(n-butyl)ammonium phthalocyaninato(2-)lithate is obtained as a tetrahydrofurane solvate by the reaction of dilithiumphthalocyaninate(2-) with tetra(n-butyl)ammonium bromide in tetrahydrofurane. The solvate crystallizes monoclinic with crystal data: a = 12.455(5) Angstrom; b = 23.396(5) Angstrom; c = 16.120(5) Angstrom; beta = 94.986(5)degrees; space group P2/c1; Z = 4. [References: 25]

机译：邻苯二甲酸氰化锂（2-）与过量的四（正丁基）氟化铵三水合物反应，生成蓝色的邻苯二甲酸氰基四（正丁基）铵四氢呋喃和双（正丁基）铵酞菁双（ 2-）水合氟化锂。后者用晶体数据结晶三斜晶：a = 8.6480（1）埃; b = 12.620（2）埃; c = 14.866（5）埃; alpha = 82.44（2）度; beta = 87.01（2）度;伽玛= 75.02度; P上方的空间组P（1）; Z =1。氟化物不与锂配位。相反，形成了双盐，其由阳离子和阴离子的交替层组成。这种布置在晶胞的中心打开了一个空腔，该空腔在统计学上共享氟化物和无序的氟化物水合物。通过酞菁二酸二锂（2-）与溴化四正丁基铵在四氢呋喃中的反应获得纯的酞菁四（正丁基）铵（2-）锂盐，作为四氢呋喃溶剂化物。溶剂化物以晶体数据结晶单斜晶：a = 12.455（5）埃; b = 23.396（5）埃; c = 16.120（5）埃; beta = 94.986（5）度;空间组P2 / c1; Z =4。[参考：25]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第8期|共6页
作者
Latte B.; Homborg H.; Assmann B.;
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正文语种 ger
中图分类化学;
关键词
Phthalocyaninate(2-); Lithates; Crystal structure; Phthalocyanines; Lithium; Complexes;

机译：酞菁（2-）;锂盐;晶体结构;酞菁;锂;络合物;

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1. TETRA(N-BUTYL)AMMONIUM PHTHALOCYANINATO(2-)LITHATE TETRAHYDROFURANE AND BIS(TETRA(N-BUTYL)AMMONIUM) PHTHALOCYANINATO(2-)LITHATE FLUORIDE HYDRATE - SYNTHESIS AND CRYSTAL STRUCTURE [German] [J] . Latte B., Homborg H., Assmann B. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第8期

机译：四（N-丁基）邻苯二甲酰基邻氨基苯甲酸四氢呋喃和双（四（N-丁基）铵）邻苯二甲酰基氟酸盐水合物-合成和晶体结构[德国]
2. Syntheses and properties of (acido)(pyridine)phthalocyaninato(2-)ruthenates(II); Crystal structure of tetra(n-butyl)ammonium (cyano)(pyridine)phthalocyaninato(2-)ruthenate(II) [German] [J] . Weidemann M., Homborg H., Huckstadt H. Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第5期

机译：（酸）（吡啶）酞菁酞菁（2-）钌酸酯（II）的合成及性质四（正丁基）铵（氰基）（吡啶）邻苯二甲酸氰基萘甲酸（2-）钌酸酯（II）的晶体结构[德语]
3. PREPARATION AND PROPERTIES OF PHTHALOCYANINATO(2-)INDATES(III) WITH BIDENTATE OXO LIGANDS - CRYSTAL STRUCTURE OF TETRA(N-BUTYL)AMMONIUM CARBONATE(O,O')PHTHALOCYANINATO(2-)INDATE(III) [German] [J] . Schweiger K., Latte B., Homborg H., Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第6期

机译：二齿双氧羰基邻苯二甲酸（2-）吲哚（III）的制备及性质-四（N-丁基）碳酸铵（O，O'）邻苯二甲醛（2-）吲哚（III）的晶体结构[德国]
4. Phase Transition of Tetra n-Butyl Ammonium Fluoride Clathrate Hydrate in the Melting Process [C] . Takanari Mizushima, Takaaki Inada, Fumio Takemura, 日本伝熱シンポジウム . 2007

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5. Crystal structures of the three closely related compounds: bis(1H-tetrazol-5-yl)methylnitramide triaminoguanidinium 5-({(1H-tetrazol-5-yl)methyl(nitro)amino}methyl)tetrazol-1-ide and diammonium bis(tetrazol-1-id-5-yl)methylnitramide monohydrate [O] . Lauren A. Mitchell, Gregory H. Imler, Damon A. Parrish, 2017

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6. Crystal structure of bis(10,11-dihydro-dibenzob,f lazepin-5-yl)-2- methyl-propyl-dimethyl-ammonium tetrachlorocuprate(II), (C2OH27N2)2CUCI4 [O] . L. T. Kamel, Μ. El Essawi, R. Wartchow, 2001

机译：双层晶体结构（10,11-二氢 - 二苯脲B，F Lazepin-5-基）-2-甲基 - 丙基 - 二甲基 - 铵四氯环丙酸酯（II），（C2OH27N2）2 CUCI4

TETRA(N-BUTYL)AMMONIUM PHTHALOCYANINATO(2-)LITHATE TETRAHYDROFURANE AND BIS(TETRA(N-BUTYL)AMMONIUM) PHTHALOCYANINATO(2-)LITHATE FLUORIDE HYDRATE - SYNTHESIS AND CRYSTAL STRUCTURE [German]

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