Synthesis, structure and electronic configuration of [Rh6Te8(PPh3)(6)]center dot 4C(6)H(6)

Thiele Guenther; Balmer Markus; Dehnen Stefanie

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Synthesis, structure and electronic configuration of [Rh6Te8(PPh3)(6)]center dot 4C(6)H(6)

机译：[Rh6Te8（PPh3）（6）]中心点4C（6）H（6）的合成，结构和电子构型

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[Rh6Te8(PPh3)(6)].4C(6)H(6), the first compound with a molecular Chevrel-type [Rh6Te8] cluster core has been synthesized and structurally characterized. By means of quantum chemical calculation, the close relationship of its electronic configuration to that of the lighter homologue has been demonstrated. The different crystal solvent content prevents an isostructural crystallization.

机译：[Rh6Te8（PPh3）（6）]。4C（6）H（6），是第一种具有分子Chevrel型[Rh6Te8]簇芯的化合物，并进行了结构表征。通过量子化学计算，证明了其电子构型与较轻的同系物的紧密联系。不同的晶体溶剂含量可防止同构结晶。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2016年第5期|共4页
作者
Thiele Guenther; Balmer Markus; Dehnen Stefanie;
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正文语种 eng
中图分类化学;
关键词
Chevrel; crystal structure; DFT calculation; rhodium; tellurium;

机译：人字形;晶体结构;DFT计算;铑;碲;

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1. Synthesis, structure and electronic configuration of [Rh6Te8(PPh3)(6)]center dot 4C(6)H(6) [J] . Thiele Guenther, Balmer Markus, Dehnen Stefanie Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2016,第5期

机译：[Rh6Te8（PPh3）（6）]中心点4C（6）H（6）的合成，结构和电子构型
2. Preparation and crystal structures of silver(I) mixed ligand complexes with bibenzimidazole and triphenylphosphane: [Ag(PPh3)(2)(bbimH(2))](COOCH3)center dot 2CH(2)Cl(2) and [{Ag(PPh3)(2)}(2)(mu-bbim)]center dot 4CH(2)Cl(2) [German] [J] . Lemos SD., Lang ES., Bessler KE. Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第1期

机译：银（I）与联苯并咪唑和三苯基膦的混合配体配合物的制备和晶体结构：[Ag（PPh3）（2）（bbimH（2））]（COOCH3）中心点2CH（2）Cl（2）和[{Ag（ PPh3）（2）}（2）（mu-bbim）]中心点4CH（2）Cl（2）[德语]
3. REACTIONS OF ([PD(MU-SC6F5)(MU-DPPM)PD](MU-SC64)CENTER-DOT-2O(C2H5)(2) - CRYSTAL STRUCTURES OF THE COMPLEXES [(PH3P)PD(MU-SC6F5)(MU-DPPM)PD(SC6F5)]CENTER-DOT-1.4CH(2)CL(2) AND [(PH3P)PD(MU-SC6F5)(MU-DPPM)PD(PPH3)]SO3CF3-CENTER-DOT-2CH(2)CL(2) AND AB [J] . Uson R., Sanz JF., Uson MA., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第9期

机译：（[PD（MU-SC6F5）（MU-DPPM）PD]（MU-SC64）CENTER-DOT-2O（C2H5）（2）-配合物[（PH3P）PD（MU-SC6F5）（ MU-DPPM）PD（SC6F5）] CENTER-DOT-1.4CH（2）CL（2）和[（PH3P）PD（MU-SC6F5）（MU-DPPM）PD（PPH3）] SO3CF3-CENTER-DOT-2CH （2）CL（2）和AB
4. Quantum-current transport through an array of coupled quantum-dots accounting for k center dot p electronic bandstructure [C] . M. Willatzen, B. Lassen International Conference on the Physics of Semiconductors . 2007

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Synthesis, structure and electronic configuration of [Rh6Te8(PPh3)(6)]center dot 4C(6)H(6)

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