Arylimido zirconium and titanium complexes: characteristic structures and application in ethylene polymerizationy

Yuan Shifang; Wang Lijing; Hua Yupeng; Zhang Jing; Sun Wen-Hua

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Arylimido zirconium and titanium complexes: characteristic structures and application in ethylene polymerizationy

机译：Arylimido锆和钛络合物：特征结构及其在乙烯聚合中的应用

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Dimeric anilidolithium (ArHNLi center dot Et2O)(2) (Ar = 2,6-'Pr2C6H3) reacted with zirconium tetrachloride in THF to give the heterometallic zirconium-lithium complex [(Et2O)(2)Li(mu-Cl)(2)(ArHN)(ArN=) Zr(mu-Cl)](2) (C1) and with titanium tetrachloride in toluene to give the titanium complex [(ArN=)TiCl2 center dot(Et2O)(2)] (C2) each in good isolated yields. Their molecular structures in the solid state were confirmed by X-ray diffraction analysis. Upon activation with methylaluminoxane, both arylimido zirconium and titanium complexes exhibited good catalytic activities toward ethylene polymerization.

机译：二聚苯胺锂（ArHNLi中心点Et2O）（2）（Ar = 2,6-'Pr2C6H3）与四氯化锆在THF中反应，得到杂金属锆-锂络合物[（Et2O）（2）Li（mu-Cl）（2））（ArHN）（ArN =）Zr（mu-Cl）]（2）（C1）并与四氯化钛在甲苯中制得钛络合物[（ArN =）TiCl2中心点（Et2O）（2）]（C2）每个都具有良好的孤立产量。通过X射线衍射分析证实了它们处于固态的分子结构。在用甲基铝氧烷活化后，芳基酰亚胺锆和钛络合物均显示出对乙烯聚合的良好催化活性。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2016年第10期|共5页
作者
Yuan Shifang; Wang Lijing; Hua Yupeng; Zhang Jing; Sun Wen-Hua;
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正文语种 eng
中图分类化学;
关键词
arylimido complex; ethylene polymerization; titanium; zirconium;

机译：芳基酰亚胺络合物;乙烯聚合;钛;锆;

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1. Arylimido zirconium and titanium complexes: characteristic structures and application in ethylene polymerizationy [J] . Yuan Shifang, Wang Lijing, Hua Yupeng, Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2016,第10期

机译：Arylimido锆和钛络合物：特征结构及其在乙烯聚合中的应用
2. Complexes of titanium and zirconium containing a tridentate linked amido-cyclopentadienyl ligand with a soft donor group: synthesis, structure, and ethylene polymerization catalysis [J] . Jun Okuda, Thomas Eberle, Thomas P. Spaniol, Journal of Organometallic Chemistry . 1999,第1a2期

机译：含三齿连接的酰胺基-环戊二烯基配体和软供体的钛和锆的配合物：合成，结构和乙烯聚合催化
3. Catalytically Active N-Acylamidine-Zirconium Complexes: Synthesis, Structures, and Application in Ethylene Polymerization [J] . Holtrichter-Roessmann Thorsten, Haeger Ina, Daniliuc Constantin-Gabriel, Organometallics . 2016,第11期

机译：催化活性的N-Acylamidine-Zr络合物：合成，结构及其在乙烯聚合中的应用
4. Polymerization of Ethylene Catalyzed by New Titanium and Zirconium Complexes with Fluorinated β-Imineenolato Ligands [C] . Sze-Man Yu, Stefan Mecking PMSE Symposia . 2008

机译：用氟化β-氨基氨酸配体的新钛和锆配合物催化乙烯的聚合
5. Structure, mechanical properties, and high temperature stability of nanolayered titanium nitride/titanium diboride and zirconium nitride/zirconium diboride thin films. [D] . Martin, Keith Joseph. 2001

机译：纳米氮化钛/二硼化钛和氮化锆/二硼化锆薄膜的结构，力学性能和高温稳定性。
6. XAS Analysis of Reactions of (Arylimido)vanadium(V)Dichloride Complexes Containing Anionic NHC That Contains a WeaklyCoordinating B(C6F5)3 Moiety (WCA-NHC)or Phenoxide Ligands with Al Alkyls: A Potential Ethylene PolymerizationCatalyst with WCA-NHC Ligands [O] . Kotohiro Nomura, Go Nagai, Itsuki Izawa, 2019

机译：（Arylimido）钒（V）反应的XAS分析含有阴离子型NHC的二氯化物络合物含量微弱协调B（C6F5）3部分（WCA-NHC）或酚醛配体与烷基铝：潜在的乙烯聚合WCA-NHC配体的催化剂
7. Titanium and Zirconium Permethylpentalene Complexes, Pn*MCpRX, as Ethylene Polymerization Catalysts [O] . Duncan A. X. Fraser, Zoë R. Turner, Jean-Charles Buffet, 2016

机译：钛和锆渗透锆烯烃络合物，PN * MCPRX，作为乙烯聚合催化剂
8. Trivalent metallocene chemistry of some uranium, titanium, and zirconium complexes [R] . Lukens, W. W. 1995

机译：一些铀，钛和锆配合物的三价茂金属化学

Arylimido zirconium and titanium complexes: characteristic structures and application in ethylene polymerizationy

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