The reaction of RhCp*(CH_3)_2(L)(L = pyridine,dmso)with GaCp* and AlCp*:A new type of carbon-carbon bond activation reaction

Thomas Cadenbach; Ckhristianb Germel; Rochus Schmid

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The reaction of RhCp(CH_3)_2(L)(L = pyridine,dmso)with GaCp and AlCp*:A new type of carbon-carbon bond activation reaction

机译：RhCp *（CH_3）_2（L）（L =吡啶，dmso）与GaCp *和AlCp *的反应：一种新型的碳-碳键活化反应

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Reaction of RhCp*(LXCH_3)_2(L = pyridine,dmso)with equimolar amounts of GaCp* at 60 °C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe_4GaMe_3)].[Cp*Rh(CH_3)_2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

机译：RhCp *（LXCH_3）_2（L =吡啶，dmso）与等摩尔量的GaCp *在60°C下的反应定量生成两性离子物质[Cp * Rh（CpMe_4GaMe_3）]。[Cp * Rh（CH_3）_2（GaCp *）]可以分离出来并鉴定为该反应的中间体。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第20期|共2页
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Thomas Cadenbach; Ckhristianb Germel; Rochus Schmid;
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1. The reaction of RhCp*(CH_3)_2(L)(L = pyridine,dmso)with GaCp* and AlCp*:A new type of carbon-carbon bond activation reaction [J] . Thomas Cadenbach, Ckhristianb Germel, Rochus Schmid Dalton transactions: An international journal of inorganic chemistry . 2004,第20期

机译：RhCp *（CH_3）_2（L）（L =吡啶，dmso）与GaCp *和AlCp *的反应：一种新型的碳-碳键活化反应
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The reaction of RhCp*(CH_3)_2(L)(L = pyridine,dmso)with GaCp* and AlCp*:A new type of carbon-carbon bond activation reaction

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The reaction of RhCp(CH_3)_2(L)(L = pyridine,dmso)with GaCp and AlCp*:A new type of carbon-carbon bond activation reaction