The N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M = Cd(II) Zn(II); R = C2H5, C4H9, C6H13, C12H25); their synthesis, thermal decomposition and use to prepare of nanoparticles and nanorods of CdS

Memon AA; Afzaal M; Malik MA; Nguyen CQ; OBrien P; Raftery J

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M = Cd(II) Zn(II); R = C2H5, C4H9, C6H13, C12H25); their synthesis, thermal decomposition and use to prepare of nanoparticles and nanorods of CdS

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The N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M = Cd(II) Zn(II); R = C2H5, C4H9, C6H13, C12H25); their synthesis, thermal decomposition and use to prepare of nanoparticles and nanorods of CdS

机译：N-烷基二硫代氨基甲酸酯络合物[M（S2CNHR）（2）]（M = Cd（II）Zn（II）; R = C2H5，C4H9，C6H13，C12H25）;它们的合成，热分解以及用于制备CdS的纳米颗粒和纳米棒

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A series of N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M= Cd( II), Zn( II); R = C2H5, C4H9, C6H13, C12H25) have been synthesised and characterized. The decomposition of these complexes to sulfates has been investigated, and a mechanism proposed. The structures of [Zn(S(2)CNHHex)(2)], [Cd((SO4)(2)(NC5H5)(4))](n) and [Cd((SO4)(2)(NC5H5)(2)(H2O)(2))](n) have been determined by X-ray single crystal method. The cadmium complex [Cd(S2CNHC12H25)(2)] and zinc complex [Zn(S2CNHC6H13)(2)] were used as single-source precursors to synthesize CdS and ZnS nanoparticles, respectively. The synthesis of CdS nanoparticles was carried under various thermolysis conditions and changes in the shape of derived nanoparticles were studied by transmission electron microscope (TEM).

机译：已合成并表征了一系列N-烷基二硫代氨基甲酸酯络合物[M（S2CNHR）（2）]（M = Cd（II），Zn（II）; R = C2H5，C4H9，C6H13，C12H25）。已经研究了将这些络合物分解为硫酸盐，并提出了机理。 [Zn（S（2）CNHHex）（2）]，[Cd（（SO4）（2）（NC5H5）（4））]（n）和[Cd（（SO4）（2）（NC5H5））的结构（2）（H 2 O）（2））]（n）已通过X射线单晶法测定。镉络合物[Cd（S2CNHC12H25）（2）]和锌络合物[Zn（S2CNHC6H13）（2）]分别用作单一来源的前体，以合成CdS和ZnS纳米颗粒。 CdS纳米粒子的合成在各种热解条件下进行，并通过透射电子显微镜（TEM）研究了衍生纳米粒子的形状变化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第37期|共7页
作者
Memon AA; Afzaal M; Malik MA; Nguyen CQ; OBrien P; Raftery J;
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正文语种 eng
中图分类无机化学;
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CHEMICAL-VAPOR-DEPOSITION; ORIENTED THIN-FILMS; CADMIUM-SULFIDE; ZINC-SULFIDE; MOLECULAR-STRUCTURE; QUANTUM DOTS; PRECURSORS; CRYSTAL; NANOCRYSTALLITES; CHEMISTRY;

机译：化学气相沉积;定向薄膜;硫化镉;硫化锌;分子结构;量子点;预应力;晶体;纳米晶;化学性质;

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1. The N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M = Cd(II) Zn(II); R = C2H5, C4H9, C6H13, C12H25); their synthesis, thermal decomposition and use to prepare of nanoparticles and nanorods of CdS [J] . Memon AA, Afzaal M, Malik MA, Dalton transactions: An international journal of inorganic chemistry . 2006,第37期

机译：N-烷基二硫代氨基甲酸酯络合物[M（S2CNHR）（2）]（M = Cd（II）Zn（II）; R = C2H5，C4H9，C6H13，C12H25）;它们的合成，热分解以及用于制备CdS的纳米颗粒和纳米棒
2. Synthesis and Characterization of Pure Phase Zn(II) and Cd(II) Oxide Nanoparticles via Thermal Decomposition of Four New Zn(II) and Cd(II) Coordination Polymers [J] . Marandi Farzin, Hashemi Lida, Morsali Ali, Journal of inorganic and organometallic polymers and materials . 2016,第5期

机译：通过四种新型Zn（II）和Cd（II）配位聚合物的热分解合成纯相Zn（II）和Cd（II）氧化物纳米颗粒
3. Synthesis and Characterization of Zn(II), Cd(II) and Hg(II) Complexes of Diethyl Thiourea and 1-Ethoxylcarbonyl-1-ethylenecarbonyl-2,2-dithiolate and Their Use to Prepare Metal Sulfides Nanoparticles [J] . Jejenija Osuntokun, Peter A. Ajibade Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2015,第12期

机译：二乙基硫脲与1-乙氧基羰基-1-乙烯羰基-2,2-二硫醇盐的Zn（II），Cd（II）和Hg（II）配合物的合成，表征及其在制备金属硫化物纳米粒子中的应用
4. ZnS, CdS and Zn_xCd_(1-x)S Thin Films from Zn(II) and Cd(II) Complexes of 1,1,5,5-Tetramcthyl -2-4-dithiobiuret As Single Molecular Precursors [C] . Karthik Ramasamv, Mohammad A.Malik, Paul OBrien Materials Research Society Symposium . 2008

机译：来自Zn（II）的ZnS，Cds和Zn_XCD_（1-X）S薄膜和1,1,5,5-四羟基硫基-2-4-二硫代脲的CD（II）复合物作为单分子前体
5. Femtosecond studies of photoinduced electron dynamics in colloidal quantum-confined II-VI semiconductor nanoparticles: CdS, CdSe and CdZnS. [D] . Roberti, Trevor. 1998

机译：飞秒研究了胶体量子受限的II-VI半导体纳米颗粒（CdS，CdSe和CdZnS）中的光诱导电子动力学。
6. Synthesis, Characterization and Thermal Studies of Zn(II), Cd(II) and Hg(II) Complexes of N-Methyl-N-Phenyldithiocarbamate: The Single Crystal Structure of [(C6H5)(CH3)NCS2]4Hg2 [O] . Damian C. Onwudiwe, Peter A. Ajibade 1995

机译：N-甲基-N-苯基二硫代氨基甲酸酯的Zn（II），Cd（II）和Hg（II）配合物的合成，表征和热研究：[（C6H5）（CH3）NCS2] 4Hg2的单晶结构
7. Synthesis, Characterization and Thermal Studies of Zn(II), Cd(II) and Hg(II) Complexes of N-Methyl-N-Phenyldithiocarbamate: The Single Crystal Structure of [(C6H5)(CH3)NCS2]4Hg2 [O] . Peter A. Ajibade, Damian C. Onwudiwe 2011

机译：N-甲基-N-苯基二硫代氨基甲酸酯的Zn（II），Cd（II）和Hg（II）配合物的合成，表征和热研究：[（C6H5）（CH3）NCS2] 4Hg2的单晶结构

The N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M = Cd(II) Zn(II); R = C2H5, C4H9, C6H13, C12H25); their synthesis, thermal decomposition and use to prepare of nanoparticles and nanorods of CdS

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