Synthesis,characterization and reactivity of trans-[RuCl(NO)(bpydip)]~(2+) {bpydip = N,N'-bis(7-methyI-2-pyridylmethylene)-l,3-diiminopropane}:a novel nitrosyl ruthenium complex displaying high electronic delocalization

Vagner Roberto de Souza; Ana Maria da Costa Ferreira; Henrique Eisi Toma

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Synthesis,characterization and reactivity of trans-[RuCl(NO)(bpydip)]~(2+) {bpydip = N,N'-bis(7-methyI-2-pyridylmethylene)-l,3-diiminopropane}:a novel nitrosyl ruthenium complex displaying high electronic delocalization

【24h】

Synthesis,characterization and reactivity of trans-[RuCl(NO)(bpydip)]~(2+) {bpydip = N,N'-bis(7-methyI-2-pyridylmethylene)-l,3-diiminopropane}:a novel nitrosyl ruthenium complex displaying high electronic delocalization

机译：反式[RuCl（NO）（bpydip）]〜（2+）{bpydip = N，N'-双（7-甲基I-2-吡啶基亚甲基）-1,3-二亚氨基丙烷}的合成，表征和反应性亚硝酰基钌配合物显示高电子离域

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A novel trans-[RuCl(NO)(bpydip)]~(2+) species has been obtained by the reaction of nitrite ions with TRANS-[RuCl_2-(bpydip)] {bpydip=N,N'-bis(7-methyl-2-pyridylmethylene)-1,3-diiminopropane},and extensively characterized by means of elemental analysis,cyclic voltammetry,UV/Visible,FTIR,~1H NMR and EPR spectroscopy.The electrochemistry in acetonitrile solution,consists of two sets of reversible redox processes ascribed to the Ru~(III/II) (E_(1/2)=+1.92 V versus NHE) and NO~(+/.) (E_(1/2)=+0.34 V) redox couples.A relatively high v(NO) stretching frequency (1920 cm~(-1)) has been observed in the FTIR spectra,indicating a NO+ character,while the absence of EPR signals is also consistent with the Run-N0~* formulation.The reduction of the complex was monitored spectroeleclrochemically,exhibiting a shift of v(NO) to 1890 cm~(-1);and giving rise to characteristic EPR signals which evidence the NO~+ character in the product.

机译：通过亚硝酸根离子与TRANS- [RuCl_2-（bpydip）] {bpydip = N，N'-bis（7-）的反应获得了一种新型的反式[RuCl（NO）（bpydip）]〜（2+）物种。甲基-2-吡啶基亚甲基）-1,3-二亚氨基丙烷}，并通过元素分析，循环伏安，紫外/可见光，FTIR，〜1H NMR和EPR光谱进行了广泛表征。乙腈溶液中的电化学由两套归因于Ru〜（III / II）（E_（1/2）= + 1.92 V对NHE）和NO〜（+/-）（E_（1/2）= + 0.34 V）氧化还原对的可逆氧化还原过程。在FTIR光谱中观察到较高的v（NO）拉伸频率（1920 cm〜（-1）），表明NO +特性，而没有EPR信号也与Run-N0〜*公式一致。分光光度法监测复合物的还原，表现出v（NO）移至1890 cm〜（-1）;并产生特征性的EPR信号，证明产物中的NO〜+特征。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2003年第3期|共6页
作者
Vagner Roberto de Souza; Ana Maria da Costa Ferreira; Henrique Eisi Toma;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Synthesis,characterization and reactivity of trans-[RuCl(NO)(bpydip)]~(2+) {bpydip = N,N'-bis(7-methyI-2-pyridylmethylene)-l,3-diiminopropane}:a novel nitrosyl ruthenium complex displaying high electronic delocalization [J] . Vagner Roberto de Souza, Ana Maria da Costa Ferreira, Henrique Eisi Toma Dalton transactions: An international journal of inorganic chemistry . 2003,第3期

机译：反式[RuCl（NO）（bpydip）]〜（2+）{bpydip = N，N'-双（7-甲基I-2-吡啶基亚甲基）-1,3-二亚氨基丙烷}的合成，表征和反应性亚硝酰基钌配合物显示高电子离域
2. X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl_4(NO)(DMSO)]~- or [RuCl_4(NO)(H_2O)]~- complex anions [J] . Matiková-Ma?arová M., Novotná R., Trávní?ek Z. Journal of Molecular Structure . 2010,第1a3期

机译：涉及[RuCl_4（NO）（DMSO）]〜-或[RuCl_4（NO）（H_2O）]〜-复杂阴离子的简单钌（II）亚硝酰基配合物的X射线结构和光谱表征
3. Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes - Crystal Structures of trans-[RuCl_2{k~3-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh_2}(PPh_3)] and cis-[RuCl_2{k~4-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh)2}] [J] . Wai-Kwok Wong, Xiao-Ping Chen, Wei-Xiong Pan, European journal of inorganic chemistry . 2002,第1期

机译：钌二氨基二膦配合物的合成，化学及催化活性-反式-[RuCl_2 {k〜3-Ph_2PC_6H_4CH = NC_6H_（10）N（H）CH_2C_6H_4PPh_2}（PPh_3）]和顺式[RuCl_2 {k〜4- Ph_2PC_6H_4CH = NC_6H_（10）N（H）CH_2C_6H_4PPh）2}]
4. Macrocyclic chemistry: Part I. Synthesis, characterization and alkali metal stability constants of a new bis(phosphotriester) macrobicyclic polyether cryptand; Part II. Characterization of a new valence-averaged mixed-valence di-ruthenium complex, and of an iron beta-diimine keto macrocyclic complex. [D] . Allan, Christian Bruce. 1994

机译：大环化学：第一部分。新型双（磷酸三酯）大双环聚醚穴状配体的合成，表征和碱金属稳定性常数；第二部分表征新的价平均混合价二钌配合物和铁β-二亚胺酮大环配合物。
5. Synthesis Characterization and Solution Chemistry oftrans-Indazoliumtetrachlorobis(Indazole)Ruthenate(III) a NewAnticancer Ruthenium Complex. IR UV NMR HPLC Investigations andAntitumor Activity. Crystal Structures of trans-1-Methyl-Indazoliumtetrachlorobis-(1-Methylindazole)Ruthenate(III)and its Hydrolysis Product trans-Monoaquatrichlorobis-(1-Methylindazole)-Ruthenate(III) [O] . Kari-Georg Lipponer, Ellen Vogel, Bernhard K. Keppler 1996

机译：of的合成表征与溶液化学。一种新型的反式吲哚四氯双（吲唑）钌（III）钌抗癌复合物。 IRUVNMRHPLC研究和抗肿瘤活性。反式-1-甲基-吲唑四氯双-（1-甲基吲唑）钌的晶体结构（III）及其水解产物反-季铵三氯-（1-甲基吲唑）-钌（III）
6. Synthesis and characterization of iron(2+) and ruthenium(2+) diimino-, diamino- and diamido-diphosphine complexes X-ray crystal structure of trans-RuCl2(P2N2C2H4)center dot CHCl3 [O] . Gao J. X., Wan H. L., Wong W. K., 1996

机译：铁（2+）和钌（2+）二亚氨基，二氨基和二氨基-二膦配合物的合成与表征X-射线反式RuCl2（P2N2C2H4）中心点CHCl3的晶体结构

Synthesis,characterization and reactivity of trans-[RuCl(NO)(bpydip)]~(2+) {bpydip = N,N'-bis(7-methyI-2-pyridylmethylene)-l,3-diiminopropane}:a novel nitrosyl ruthenium complex displaying high electronic delocalization

摘要

著录项

相似文献

相关主题

期刊订阅