Access to well-defined isolated Fe(II) centers on silica and their use in oxidation

Roukoss C; Fiddy S; de Mallmann A; Rendon N; Basset JM; Kuntz E; Coperet C

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Access to well-defined isolated Fe(II) centers on silica and their use in oxidation

机译：获得定义明确的孤立的Fe（II）的中心是二氧化硅，及其在氧化中的用途

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Well-defined FeII isolated sites are obtained by reaction of diaryl-N,N'-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H2O2.

机译：通过使二芳基-N，N'-二氮杂二烯双（新甲硅烷基）铁（1）与二氧化硅（SiO2-（700））反应，可以获得明确的FeII分离位点。该体系可用作在H2O2存在下将环己烯催化氧化为环己烯氧化物，环己烯醇和环己烯酮的前体。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第47期|共3页
作者
Roukoss C; Fiddy S; de Mallmann A; Rendon N; Basset JM; Kuntz E; Coperet C;
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正文语种 eng
中图分类无机化学;
关键词
ALKENE EPOXIDATION; NITROGEN LIGANDS; COMPLEXES; IRON(II); CATALYSIS; MANGANESE(II); REACTIVITY; HYDROXYLATION; COBALT(II); SURFACE;

机译：烯烃环氧化;氮配体;络合物;铁（II）;催化;锰（II）;反应性;羟基化;钴（II）;表面;

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1. Access to well-defined isolated Fe(II) centers on silica and their use in oxidation [J] . Roukoss C, Fiddy S, de Mallmann A, Dalton transactions: An international journal of inorganic chemistry . 2007,第47期

机译：获得定义明确的孤立的Fe（II）的中心是二氧化硅，及其在氧化中的用途
2. Magnetic resonance studies on radiation-induced point defects in mixed oxide glasses. II. Spin centers in alkali silicate glasses [Review] [J] . Shkrob IA., Trifunac AD., Tadjikov BM. Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2000,第1a3期

机译：混合氧化物玻璃中辐射引起的点缺陷的磁共振研究。二。碱金属硅酸盐玻璃的自旋中心[评论]
3. Preparation of mesoporous titanosilicate with isolated Ti active centers for cyclohexene oxidation [J] . Gupta S., Vinod C. P., Jagadeesan D. RSC Advances . 2015,第112期

机译：具有分离的Ti活性中心的介孔钛硅酸盐的环己烯氧化制备
4. Propane dehydrogenation by heterogeneous isolated site Fe(II) on silica catalyst [C] . Bo Hu, Neil M. Schweitzer, Michael P. Lanci National Meeting Exhibition . 2013

机译：二氧化硅催化剂上的异质分离位点Fe（II）的丙烷脱氢
5. Mechanisms of electron transfer and hydrogen activation in selected triruthenium clusters with multiple bridging ligands. Part I. The attenuation of radical reactivity in triruthenium trihydrido(alkylidyne) clusters. Electrochemistry and kinetics of decomposition of the 47-electron cluster radical, via a disproportionation path. Part II. The activation of molecular hydrogen at transition metal centers via kinetics and mechanism of reversible oxidative addition of hydrogen across the metal-metal bond of (mu-hydrogen)(2)Ruthenium(3)(Carbon monoxide)(8)(mu-phosphorus(t-BU)(2))(2). [D] . Bierdeman, David John. 2000

机译：具有多个桥联配体的选定三钌簇中电子转移和氢活化的机理。第一部分。三氢三钌（亚烷基）簇中自由基反应性的减弱。通过歧化路径分解47电子簇自由基的电化学和动力学。第二部分通过（mu-hydrogen）（2）钌（3）（一氧化碳）（8）（mu-phosphorus（）的金属-金属键上氢的可逆氧化加成反应的动力学和机理激活过渡金属中心的分子氢t-BU）（2））（2）。
6. Mechanisms for Accessing Insoluble Fe(III) Oxide during Dissimilatory Fe(III) Reduction by Geothrix fermentans [O] . Kelly P. Nevin, Derek R. Lovley 2002

机译：Geothrix fermentans异化还原Fe（III）时获得不溶性Fe（III）氧化物的机制
7. Near-IR Two Photon Microscopy Imaging of Silica Nanoparticles Functionalized with Isolated Sensitized Yb(III) Centers [O] . Lapadula, Giuseppe, Bourdolle, Adrien, Allouche, Florian, 2014

机译：二氧化硅纳米粒子的近红外两光子显微镜成像，具有分离的敏化Yb（III）中心功能。

Access to well-defined isolated Fe(II) centers on silica and their use in oxidation

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