Synthesis and properties of alkynethiolate gold(I) complexes

Lardies N; Romeo I; Cerrada E; Laguna M; Skabara PJ

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Synthesis and properties of alkynethiolate gold(I) complexes

机译：炔炔硫醇盐金（I）配合物的合成与性能

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A series of alkynethiolate gold(I) derivatives have been synthesised by the cleavage of 4-monosubstituted 1,2,3-thiadiazoles in the presence of strong bases. The syntheses of the 1,2,3-thiadiazoles with p-cyanophenyl, p-tolyl, 2-thienyl, 3-thienyl and 9,9-dimethylfluoren-2-yl fragments are also described. All the complexes have been characterised by spectroscopic techniques and the complexes [Au(p-CH3-C6H4-C C-S)PPh3], [Au(3-C4H3S-C C-S) PPh3] and PPN[Au(p-CH3-C6H4-C C-S)(C6F5)] by X-ray analysis. The electrochemically polymerizable mononuclear bis(alkynethiolate) gold(I) complex PPN[Au(3-C4H3S-C C-S)(2)] is also described, including its electropolymerization and electrochemical properties.

机译：在强碱的存在下，通过裂解4-单取代的1,2,3-噻二唑合成了一系列炔硫醇金（I）衍生物。还描述了1,2,3-噻二唑与对氰基苯基，对甲苯基，2-噻吩基，3-噻吩基和9,9-二甲基芴-2-基片段的合成。所有配合物均已通过光谱技术表征，并且配合物[Au（p-CH3-C6H4-C CS）PPh3]，[Au（3-C4H3S-C CS）PPh3]和PPN [Au（p-CH3-C6H4- C CS）（C6F5）]进行X射线分析。还描述了可电化学聚合的单核双（炔硫醇盐）金（I）配合物PPN [Au（3-C4H3S-CC-S）（2）]，包括其电聚合作用和电化学性质。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第45期|共10页
作者
Lardies N; Romeo I; Cerrada E; Laguna M; Skabara PJ;
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正文语种 eng
中图分类无机化学;
关键词
X-RAY STRUCTURE; SULFUR-CONTAINING LIGANDS; METAL-COMPLEXES; CRYSTAL-STRUCTURES; PLATINUM(II) 1-ALKYNE-1-THIOLATO; CONJUGATED METALLOPOLYMERS; DITHIOLENE COMPLEXES; OXIDATIVE ADDITION; C BOND; 1; 2; 3-THIADIAZOLES;

机译：X射线结构;含硫配位体;金属络合物;晶体结构;铂（II）1-炔-1-硫醇;共轭金属聚合物;二噻吩配合物;氧化添加剂;C键;1;2;3-噻唑;

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1. Synthesis and properties of alkynethiolate gold(I) complexes [J] . Lardies N, Romeo I, Cerrada E, Dalton transactions: An international journal of inorganic chemistry . 2007,第45期

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Synthesis and properties of alkynethiolate gold(I) complexes

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