Structural control of metalloporphyrinogens by macrocycle modification:steric blocking of the macrocyclic cavity through trans-N,N' -dimethylation

Jun Wang; Michael G. Gardiner; Evan J. Peacock; Brian W. Skelton; Allan H. White

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Structural control of metalloporphyrinogens by macrocycle modification:steric blocking of the macrocyclic cavity through trans-N,N' -dimethylation

机译：大环修饰修饰金属卟啉原的结构控制：通过反式N，N'-二甲基化对大环腔进行空间封闭

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Reactions of potassium metal with trans-N,N'-dimethyl-meso-octaethylporphyrinogen or meso-octaethyldioxa-porphyrinogen afford dipotassium complexes with one potassium cation excluded from the cavity on steric grounds in the former case,or both potassium cations bound inside the macrocyclic cavity in the latter case.

机译：在前一种情况下，钾金属与反式-N，N'-二甲基-间-八乙基卟啉原或中-八乙基二氧杂卟啉原的反应可提供双钾配合物，其中一种钾阳离子从空间上被排除在空腔之外，或者两个钾阳离子都结合在大环内在后一种情况下腔。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第2期|共2页
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Jun Wang; Michael G. Gardiner; Evan J. Peacock; Brian W. Skelton; Allan H. White;
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1. Structural control of metalloporphyrinogens by macrocycle modification:steric blocking of the macrocyclic cavity through trans-N,N' -dimethylation [J] . Jun Wang, Michael G. Gardiner, Evan J. Peacock, Dalton transactions: An international journal of inorganic chemistry . 2003,第2期

机译：大环修饰修饰金属卟啉原的结构控制：通过反式N，N'-二甲基化对大环腔进行空间封闭
2. Tuning the size of macrocyclic cavities in trianglimine macrocycles [J] . Kuhnert N, Burzlaff N, Patel C, Organic & biomolecular chemistry . 2005,第10期

机译：调整Trianglimine大环中大环腔的大小
3. X-Ray diffraction and molecular mechanics studies of 12-, 13-, and 14-membered tetraaza macrocycles containing pyridine: effect of the macrocyclic cavity size on the selectivity of the metal ion [J] . Felix V., Delgado R., Drew MGB., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001,第9期

机译：含吡啶的12元，13元和14元四氮杂大环的X射线衍射和分子力学研究：大环腔尺寸对金属离子选择性的影响
4. STRUCTURAL MODIFICATION OF A POWER PLANT'S RIVER WATER INTAKE TO MINIMIZE ICE BLOCKAGE [C] . Frank Michell, Jeffrey Stallings, Marcela Politano, ASME power conference . 2014

机译：电厂进水的结构修改以最小化结冰
5. Supramolecular structural impact on d -block metal complexes by rationally designed ligand structure modification [D] . Elgin, Jason Derek 2007

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6. Enthalpic incompatibility between two steric stabilizer blocks provides control over the vesicle size distribution during polymerization-induced self-assembly in aqueous media [O] . Deborah L. Beattie, Oleksandr O. Mykhaylyk, Steven P. Armes 2020

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7. Protonation and Zn(II) Coordination by Dipyridine-Containing Macrocycles with Different Molecular Architecture. A Case of pH-Controlled Metal Jumping OutsideInside the Macrocyclic Cavity. [O] . Carlos Lodeiro, A. Jorge Parola, Fernando Pina, 2002

机译：质子化和Zn（II）具有不同分子结构的含双吡啶的大键的配位。跳跃在宏型腔外的pH控制金属的情况。
8. Resolution of Numerical Control Machine Tool Modification Problems Using a Symbiosis of Machinery Diagnostics, Modal Analysis, Structural Dynamics Modification and Acoustic Intensity Analysis [R] . Van Hoy, B. W. , Strunk, W. D. , Morton, T. L. , 1988

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Structural control of metalloporphyrinogens by macrocycle modification:steric blocking of the macrocyclic cavity through trans-N,N' -dimethylation

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