New bulky phosphinopyridine ligands.P~N~C Tridentates in palladium complexes

Hsin-Pei Chen; Yi-Hung Liu; Shie-Ming Peng; Shiuh-Tzung Liu

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >New bulky phosphinopyridine ligands.P~N~C Tridentates in palladium complexes

【24h】

New bulky phosphinopyridine ligands.P~N~C Tridentates in palladium complexes

机译：新的庞大的膦基吡啶配体。钯络合物中的P〜N〜C三齿

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The sterically bulky pyridinyl phosphine(P~N)ligands have been prepared from the phosphinylation of 2,4-di-tert-butyl-6-methylpyridine.Due to the steric hindrance,substitution reaction of these P~N ligands with(COD)PdMeCl yields the chloro-bridged dipalladium species [(PapproxN)_2Pd_2Me_2Cl_2],in which the PapproxN ligand acts as a monodentate.Treatment of these dimeric palladium compounds with AgBF_4 in the presence of acetonitrile gives the corresponding C-H activation metal complex [(P~N~C)Pd(CH_3CN)JBF_4.Both spectral and X-ray single-crystal characterization of these palladium complexes are presented.

机译：由2,4-二叔丁基-6-甲基吡啶的膦基化反应制得大体积的吡啶基膦（P〜N）配体。由于空间位阻，这些P〜N配体与（COD）的取代反应PdMeCl产生氯桥联的二钯物种[（PapproxN）_2Pd_2Me_2Cl_2]，其中PapproxN配体充当单齿。在乙腈存在下用AgBF_4处理这些二聚钯化合物得到相应的CH活化金属络合物[[P〜N 〜C）Pd（CH_3CN）JBF_4。给出了这些钯配合物的光谱和X射线单晶表征。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2003年第7期|共6页
作者
Hsin-Pei Chen; Yi-Hung Liu; Shie-Ming Peng; Shiuh-Tzung Liu;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. New bulky phosphinopyridine ligands.P~N~C Tridentates in palladium complexes [J] . Hsin-Pei Chen, Yi-Hung Liu, Shie-Ming Peng, Dalton transactions: An international journal of inorganic chemistry . 2003,第7期

机译：新的庞大的膦基吡啶配体。钯络合物中的P〜N〜C三齿
2. Synthesis and structural characterization of novel palladium complexes chelated by bulky cobalt-containing phosphine ligands: unusual palladium-cobalt bound formation [J] . Fung-E Hong, Chin-Pei Chang, Yu-Chang Chang Dalton transactions: An international journal of inorganic chemistry . 2003,第20期

机译：庞大的含钴膦配体螯合的新型钯配合物的合成与结构表征：不常见的钯钴结合形成
3. Synthesis of a sterically bulky diphosphine synthon and Ru(II) complexes of a cooperative tridentate enamide-diphosphine ligand platform [J] . Annibale Vincent T., Ostapowicz Thomas G., Westhues Stefan, Dalton transactions: An international journal of inorganic chemistry . 2016,第40期

机译：三齿烯酰胺-二膦配体协同平台的空间庞大的二膦合成子和Ru（II）配合物的合成
4. Redox photosensitizing function of ruthenium(II) complexes with tridentate ligands [C] . Yusuke Tamaki, Osamu Ishitani 日本化学会春季年会講演予稿集 . 2018

机译：钌（II）复合物与三齿配体的氧化还原光敏功能
5. The synthesis, reactivity and characterization of highly unusual, and unsaturated ruthenium compounds supported by bulky "PNP" tridentate "pincer" ligands. [D] . Groves, Amy Nichole. 2009

机译：庞大的“ PNP”三齿“钳”配体支持的高度不寻常的不饱和钌化合物的合成，反应性和表征。
6. Asymmetric Intermolecular Boron Heck-Type Reactions via Oxidative Palladium(II) Catalysis Using Chiral Tridentate NHC-Amidate-Alkoxide Ligands [O] . Kyung Soo Yoo, Justin O’Neill, Satoshi Sakaguchi, -1

机译：通过氧化钯（II）使用手性三乙酸NHC-氨基酯 - 醇盐配体通过氧化钯（II）催化的不对称分子间硼型反应
7. Palladium complexes with tridentate PNO ligand. Synthesis of eta-1-allyl complexes and cross-coupling reactions promoted by boron compounds [O] . Crociani B, Antonaroli S, Burattini M, 2010

机译：具有三齿PNO配体的钯配合物。 η-1-烯丙基配合物的合成及硼化合物促进的交叉偶联反应

New bulky phosphinopyridine ligands.P~N~C Tridentates in palladium complexes

摘要

著录项

相似文献

相关主题

期刊订阅