TOTAL SYNTHESIS OF (S)-(+)- AND (R)-(-)-CURCUDIOLS BASED ON 1,2-ARYL MIGRATION VIA PHENONIUM ION

Takeru Ehara; Hirofumi Yokoyama; Machiko Ono

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TOTAL SYNTHESIS OF (S)-(+)- AND (R)-(-)-CURCUDIOLS BASED ON 1,2-ARYL MIGRATION VIA PHENONIUM ION

机译：基于1,2-芳基1，离子迁移的（S）-（+）-和（R）-（-）-葫芦素的总合成

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Total synthesis of (S)-(+)- and (R)-(-)-curcudiols (2) was achieved based on the 1,2-aryl migration of the (4R,5R)- and (4S,5S)-4-aryl-5-tosyloxy-(2E)-hexenoates (9) derived from (4R,5R)- and (4S,5S)-4-epoxy-(2E)-hexenoates (3),respectively.

机译：基于（4R，5R）-和（4S，5S）-的1,2-芳基迁移，实现了（S）-（+）-和（R）-（-）-姜二醇（2）的全合成。（4R，5R）-和（4S，5S）-4-环氧-（2E）-己酸酯（3）分别衍生的4-芳基-5-甲苯磺酰氧基-（2E）-己酸酯（9）。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2007年第3期|共8页
作者
Takeru Ehara; Hirofumi Yokoyama; Machiko Ono;
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1. TOTAL SYNTHESIS OF (S)-(+)- AND (R)-(-)-CURCUDIOLS BASED ON 1,2-ARYL MIGRATION VIA PHENONIUM ION [J] . Takeru Ehara, Hirofumi Yokoyama, Machiko Ono Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007,第3期

机译：基于1,2-芳基1，离子迁移的（S）-（+）-和（R）-（-）-葫芦素的总合成
2. Formal synthesis of (-)-anisomycin based on stereoselective nucleophilic substitution along with 1,2-aryl migration [J] . Ono M, Tanikawa S, Suzuki K, Tetrahedron . 2004,第45期

机译：基于立体选择性亲核取代和1,2-芳基迁移的（-）-茴香霉素的形式合成
3. Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration [J] . Suzuki E, Komuro T, Okazaki M, Organometallics . 2009,第6期

机译：DMAP稳定化钨的芳基（亚甲硅烷基）配合物和（芳基甲硅烷基）（DMAP）配合物的合成和表征：这些配合物通过1,2-芳基迁移的相互转化机理研究
4. 1,2-Migration of Aryl Groups on Silyl Ligands:Formation and Properties of Silylenetungusten Complexes Stabilized by an External Base [C] . Eiji Suzuki, Masaaki Okazaki, Hiromi Tobita Symposium on Organometallic Chemistry . 2004

机译：在甲硅烷基配体上的1,2-芳基偏移：由外部底座稳定的Silylenetuncusten复合物的形成和性质
5. I. [1,2]-Brook rearrangement: Application of silyl glyoxylates in a novel glycolate aldol reaction and in a controlled oligomerization to complete the total synthesis of zaragozic acid C. II. Progress toward the total synthesis of pactamycin. [D] . Satterfield, Andrew Duncan. 2009

机译：I. [1,2]-布鲁克重排：甲硅烷基乙氧基化物在新型乙醇酸酯羟醛反应中和可控的低聚反应中的应用，以完成zaragozic酸C的总合成。向全合成pactamycin的进展。
6. An Expedient Formal Total Synthesis of (-)-Diazonamide A via a Powerful Stereoselective O-Aryl to C-Aryl Migration to form the C10 Quaternary Center [O] . Chi-Ming Cheung, Frederick W. Goldberg, Philip Magnus, -1

机译：通过强大的立体选择性O-芳基向C-芳基的迁移形成C10季铵化合物中心的（-）-重氮酰胺A的正式形式全合成
7. An Expedient Formal Total Synthesis of (−)-Diazonamide A via a Powerful, StereoselectiveO-Aryl toC-Aryl Migration To Form the C10 Quaternary Center [O] . Chi-Ming Cheung, Frederick W. Goldberg, Philip Magnus, 2007

机译：（ - ） - 双聚酰胺A通过强大的立体化 - 芳基TOC-芳基偏移来形成C10第四节中心的权宜之计

TOTAL SYNTHESIS OF (S)-(+)- AND (R)-(-)-CURCUDIOLS BASED ON 1,2-ARYL MIGRATION VIA PHENONIUM ION

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