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Polymeric Multifunctional Carboxylic Acids as Crosslinking Agents for Cotton Cellulose: Poly(itaconic acid) and In Situ Polymerization of Itaconic Acid

机译:聚合多功能羧酸作为棉纤维素的交联剂:衣康酸和衣康酸的原位聚合

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摘要

Multifunctional carboxylic acids have been used as nonformaldehyde du- rable press finishing agents for cotton. In previous research we found that maleic acid (MA) and itaconic acid (IA) polymerize in situ on cotton fabric at elevated temperatures when both potassium persulfate (K_2S_2O_8) and sodium hypophosphite (NaH_2PO_2) are present, thus imparting wrinkle resistance to the treated cotton fabric. We also found that MA and IA polymerize in aqueous solutions in the presence of ~S_20_8 and NaH_2PO_2. In this research, we compared the effectiveness of poly(itaconic acid) (PIA) applied to cotton fabric as a polymer and IA applied as a monomer and allowed to polymerize in situ for crosslinking cotton cellulose. We found that IA is more effective in esterifying cotton cellulose and imparting a high level of wrinkle resistance to the fabric as it polymerizes in situ than PIA applied as a polymer. We also found that tensile strength loss of the cotton fabric crosslinked by IA polymerizing in situ as a function of fabric wrinkle recovery angle is practically the same as that crosslinked by; PIA applied as a polymer.
机译:多功能羧酸已用作棉花的非甲醛持久性压榨整理剂。在先前的研究中,我们发现当过硫酸钾(K_2S_2O_8)和次磷酸钠(NaH_2PO_2)同时存在时,马来酸(MA)和衣康酸(IA)在高温下在棉织物上原位聚合,从而使处理过的棉具有抗皱性布。我们还发现在〜S_20_8和NaH_2PO_2存在下,MA和IA在水溶液中聚合。在这项研究中,我们比较了将聚衣康酸(PIA)应用于棉织物作为聚合物和将IA用作单体并使其原位聚合以交联棉纤维素的有效性。我们发现,IA比在原位聚合时更能有效地酯化棉纤维素,并赋予织物高水平的抗皱性,而PIA则用作聚合物。我们还发现,通过IA原位聚合而交联的棉织物的抗张强度损失与织物皱纹回复角的函数实际上与通过交联的交织物相同。 PIA用作聚合物。

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