首页> 外文期刊>Journal of Applied Polymer Science >Small-angle X-ray scattering analysis of nanophase titanium dioxide, poly[N-(4-sulfophenyl)aniline], and their composite
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Small-angle X-ray scattering analysis of nanophase titanium dioxide, poly[N-(4-sulfophenyl)aniline], and their composite

机译:纳米二氧化钛,聚[N-(4-磺基苯基)苯胺]及其复合物的小角X射线散射分析

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摘要

Small-angle X-ray scattering and spectroscopic (infrared and ultraviolet-visible) techniques were used to investigate the interactions between titanium dioxide (TiO2) and the semiconductor polymer poly[N-(4-sulfophenyl)aniline] (PSA) in a poly[N-(4-sulfophenyl)aniline]/TiO2 composite (TPSA). The radius of gyration of the cross section, the radius and length of the rodlike particle, the persistence length, the surface fractal dimension, and the PSA layer thickness on TiO2 in aqueous solutions and in powder form were calculated. The results indicated that the aggregation of TiO2 particles on drying was reduced by the formation of the composite with the semiconductor poly-mer. Only the particle length of the TPSA particle (which had a rodlike shape) increased on drying, probably because of increasing void sizes and the formation of aggregation. The persistence length of the TPSA particles decreased with respect to its individual components. The PSA layer thickness on TiO2 was about 3.6 nm and decreased (to 2.6 nm) on dehydration because of the expulsions of water molecules from the TiO2/PSA composite. (C) 2003 Wiley Periodicals, Inc. [References: 26]
机译:小角度X射线散射和光谱(红外和紫外可见)技术用于研究聚二氧化钛(TiO2)与半导体聚合物聚[N-(4-硫代苯基)苯胺](PSA)之间的相互作用[N-(4-磺基苯基)苯胺] / TiO2复合材料(TPSA)。计算了在水溶液和粉末形式的TiO2上的横截面的回转半径,棒状颗粒的半径和长度,持久性长度,表面分形维数和PSA层厚度。结果表明,通过形成具有半导体聚合物的复合材料,减少了干燥时TiO2颗粒的聚集。干燥时仅TPSA颗粒(呈棒状)的颗粒长度增加,这可能是由于空隙尺寸的增加和聚集的形成。 TPSA颗粒的持久长度相对于其各个组分而言有所减少。 TiO2上的PSA层厚度约为3.6 nm,并且由于脱水而从TiO2 / PSA复合材料中排出水分子,因此在脱水时会降低(至2.6 nm)。 (C)2003 Wiley Periodicals,Inc. [参考:26]

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