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Synthesis and characterization of temperature- and pH-sensitive poly(N,N-diethylacrylamide-co-methacrylic acid)

机译:对温度和pH敏感的聚(N,N-二乙基丙烯酰胺-共-甲基丙烯酸)的合成与表征

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摘要

A series of pH- and temperature-responsive (N,N-diethylacrylamide-co-methacrylic acid) (DEAM-MAA) random copolymers were synthesized by free-radical copolymerization techniques, and their lower critical solution temperatures (LCSTs) at different pH values and their critical phase-transition pH values at different temperatures were determined by transmittance measurements, respectively. The LCSTs of DEAM-MAA copolymers depend on the MAA content in the copolymers and are significantly affected by the pH of the aqueous solution. Similarly, the critical phase-transition pH values also depend on the MAA content of the DEAM-MAA copolymers and are significantly affected by the temperature of the aqueous solution. The LCST of DEAM-MAA copolymers increases with an increase in the MAA content. The critical phase-transition pH increases with increasing MAA content in the copolymer and also increases with increasing aqueous solution temperature. (C) 2003 Wiley Periodicals, Inc. [References: 39]
机译:通过自由基共聚技术合成了一系列对pH和温度有响应的(N,N-二乙基丙烯酰胺-共-甲基丙烯酸)(DEAM-MAA)无规共聚物,以及它们在不同pH值下的较低临界溶液温度(LCST)通过透射率测定分别确定了它们在不同温度下的临界相变pH值。 DEAM-MAA共聚物的LCST取决于共聚物中的MAA含量,并受水溶液pH值的显着影响。类似地,临界相变pH值也取决于DEAM-MAA共聚物的MAA含量,并且受水溶液温度的影响很大。 DEAM-MAA共聚物的LCST随着MAA含量的增加而增加。临界相变pH随着共聚物中MAA含量的增加而增加,并且也随着水溶液温度的增加而增加。 (C)2003 Wiley Periodicals,Inc. [参考:39]

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